A transparent multilayer coextruded heat shrinkable barrier film is useful for high-value packaging applications such as food and medical device packaging. The transparent multilayer coextruded heat shrinkable barrier film includes first and second outer layers formed using a transparent polyester or polyester copolymer; an inner nanolayer sequence including a plurality of nanolayers a) including ethylene vinyl alcohol, alternating with nanolayers b) including at least one of ethylene ethyl acrylate, low density polyethylene and linear low density polyethylene, each of the nanolayers b) having a degree of crystallinity less than about 45%; and adhesive layers between each of the two outer layers and the inner nanolayer sequence. The film has a light transmittance of at least about 80% and a heat shrunk of at least about ten percent in at least one direction.

A transparent thermoformed high barrier plastic bottle is provided for use in storing food and beverages, personal care products, health care products, and other applications that require excellent transparency and barrier properties. The transparent thermoformed high barrier plastic bottle includes first and second outer layers formed using a transparent polyester or polyester copolymer; an inner nanolayer sequence including a plurality of nanolayers a) including ethylene vinyl alcohol, alternating with nanolayers b) including at least one of ethylene ethyl acrylate, low density polyethylene and linear low density polyethylene, each of the nanolayers b) having a degree of crystallinity less than about 45%; and adhesive layers between each of the two outer layers and the inner nanolayer sequence. A method for producing a transparent thermoformed high barrier plastic bottle is also provided.

A multi-layer film having excellent surface hardness and transparency, a small heat shrinkage factor and such high brittleness that it is easily trimmed after decorative molding. The multi-layer film comprises a layer (layer A) which contains a polycarbonate resin having a viscosity average molecular weight of 13,000 or more to less than 20,000 and layers (layer B-1 and layer B-2) which contain an acrylic resin and are formed on both sides of the layer A, respectively, wherein the total thickness of the multi-layer film is 50 to 200 μm, and the thickness of the layer A accounts for 5 to 30 $ of the total thickness.

A laminate film manufacturing method is capable of preventing thickness unevenness of a cured layer and preventing wrinkling of the entire laminate film. A laminate film is manufactured by applying a coating solution including an active radiation curable resin to a surface of a first film that is continuously transported in an application part to form a coated film in a lamination part, laminating a second film that is continuously transported on the coated film to sandwich the coated film between the first film and the second film, and in a state in which the coated film is sandwiched between the first film and the second film, winding the first film around a backup roller and irradiating the coated film with infrared rays from an ultraviolet irradiation device while continuously transporting the first film to cure the coated film in a curing part so as to form a cured layer.

A laminate film manufacturing method is capable of preventing thickness unevenness of a cured layer and preventing wrinkling of the entire laminate film. A laminate film is manufactured by applying a coating solution including an active radiation curable resin to a surface of a first film that is continuously transported in an application part to form a coated film in a lamination part, laminating a second film that is continuously transported on the coated film to sandwich the coated film between the first film and the second film, and in a state in which the coated film is sandwiched between the first film and the second film, winding the first film around a backup roller and irradiating the coated film with infrared rays from an ultraviolet irradiation device while continuously transporting the first film to cure the coated film in a curing part so as to form a cured layer.

A method or apparatus for three-dimensionally printing. The method may comprise causing a phase change in a region of the first material by applying focused energy to the region using a focused energy source, and displacing the first material with a second material. The apparatus may comprise a container configured to hold a first material, a focused energy source configured to cause a phase change in a region of the first material by applying focused energy to the region, and an injector configured to displace the first material with a second material. The first material may comprise a yield stress material, which is a material exhibiting Herschel-Bulkley behavior. The yield stress material may comprise a soft granular gel. The second material may comprise one or more cells.

In one embodiment, an orthodontic article is described comprising the reaction product of a polymerizable composition comprising: a) 30-70 parts by weight of monofunctional (meth)acrylate monomer, wherein a cured homopolymer of at least one monofunctional (meth)acrylate monomer has a Tg of at least 30, 35, 40, 45, 50, 55, or 60° C.; and b) urethane (meth)acrylate polymer comprising polymerized units of an aliphatic polyester diol. Also described are polymerizable compositions, as well as methods and systems for making an article utilizing 3D printing.

A synthetic resin laminated sheet, in which whitening, cracking, and foaming do not occur when thermoforming is carried out, in particular when deep-draw molding is carried out, and defects do not occur during lamination of a hard coating layer; and a molded article obtained by molding the laminated sheet. A synthetic resin laminated sheet has a coating layer, which includes an acrylic resin, laminated on one surface of a substrate layer including a polycarbonate resin in which a monohydric phenol represented by general formula (1) is used as a chain terminator and is obtained by reacting the monohydric phenol with a dihydric phenol and a carbonate binding agent and has a viscosity average molecular weight of 18000-35000. (In the formula, R1 represents a C8-36 alkyl group or a C8-36 alkenyl group. R2-R5 each represent hydrogen, halogen, or an optionally substituted C1-20 alkyl group or C6-12 aryl group).

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A three-dimensional shaping composition of this invention is a three-dimensional shaping composition which is used for producing a three-dimensionally shaped article by laminating layers and contains particles having a hydrophilic surface and water-soluble monomers having a hydroxyl group. The water-soluble monomer is preferably at least one selected from the group consisting of 4-hydroxybutyl acrylate, 2-hydroxybutyl acrylate, 2-hydroxypropyl acrylate, 2-hydroxyethyl methacrylate, 2-hydroxypropyl methacrylate, and phenol epoxy acrylate.

The present disclosure relates to methods by which a warped workpiece is reconfigured in a pre-determined manner to reduce a separation between the warped workpiece and a joining workpiece. The warped workpiece is reformed/reshaped, prior to joining, by softening material of the warped workpiece through application of a predetermined amount of energy at or near warping and using a directional force applied to a first surface of the warped workpiece, thus reducing a separation space at a joining interface of the warped workpiece and joining workpiece.