The present disclosure provides a novel method of 3D printing using frontal polymerization chemistry. This method enables the printing of tough, high quality thermosets in a short time with the option of adding fiber reinforcement. As such, it facilitates fabrication of mechanically robust 3D-printed devices and structures.

The present invention provides a method for 3D inkjet printing, which comprises: a preheating step: an external heating source is used to heat a main body layer composed of a first composition to a first temperature, wherein the main body layer has a thickness of 10 m to 500 m and a unit density of 0.1 to 1.0 g/cm.sup.3, and the first temperature is less than the melting point of the first composition; a heating step: a second composition is applied to the surface of the first composition at the first temperature of the composite to proceed an exothermic cross-linking polymerization, so that the main body layer is heated to a second temperature to become a molten state; and a cooling step: the main body layer in the molten state is cooled down and solidified to form.

An apparatus and method for making molded products for marine, automotive, recreational, and other applications. The apparatus and method for making the molded products generally includes a closed mold and an inline mixer for adding a catalyst to a filled resin. The method may include adding a fiber material to a resin to create the filled resin, adding a catalyst to the filled resin, and mixing the catalyst and the filled resin to create an uncured catalyzed, filled resin. The method may also include adding the uncured catalyzed, filled resin to a mold and allowing the uncured catalyzed, filled resin to harden in the mold.

The disclosure provides a circuit substrate and a method for manufacturing the same. The circuit substrate includes a wiring and a substrate having a base region and a circuit region. The base region having a first pattern is constituted by a first thermoplastic material. The circuit region having a second pattern is constituted by a second thermoplastic material. The first pattern has a portion opposite to the second pattern. The wiring is formed on the circuit region along the second pattern. The first thermoplastic material is different from the second thermoplastic material, and the second thermoplastic material includes a catalyst particle.

The invention relates to a device assembly and methods useful for producing molded silicone rubber products from liquid silicone rubber compositions (LSR) via injection molding. The methods provide a flexible process to produce faster cured silicone rubber products from LSR and allow for use of low curing temperature in the molding cavities without drastically lowering cure speed of the LSR and the physical properties of the produced molded silicone rubber material, therefore allowing liquid silicone rubber overmolding on or over heat sensitive substrates. The device assembly of the invention allows a faster cycle and the use of precise dosing and mixing units thus creating a flexible process to produce cured silicone rubber products faster from liquid silicone rubber (LSR).

The present invention relates to vacuum forming process for moulding a thermoset material and a start-up process for moulding a thermoset material. The present invention also relates to articles produced by the vacuum forming process.

The present invention provides a process for recycling propylene-ethylene copolymers to obtain polymers having good optical and mechanical properties, as well as good processability. The invention further provides propylene-ethylene copolymer pellets obtained from the process, articles comprising or consisting of such pellets and the use of the propylene-ethylene copolymer pellets for injection molding applications. The process comprising the steps of (a) polymerizing propylene and ethylene in the presence of a single site catalyst in a continuous polymerization reactor under dynamic conditions, (b) collecting the resulting propylene-ethylene copolymer powders from step (a) to obtain a mixture (M) of propylene-ethylene copolymer powders having a MFR.sub.2 (ISO 1133, 230 C., 2.16 kg) in a raffle of from 1.5 to 80.0 g/ 10 min and an ethylene content in a range of from 1.0 to 4.0 wt. % based on the total weight of the mixture (M), (c) compounding said mixture (M) in an extruder in the presence of a radical initiator, and a clarifying agent in an amount of from 0.01 to 1.0 wt. %, based on the total weight of the mixture of propylene-ethylene copolymer powders, and (d) extruding the above mixture into pellets; wherein, in step a), the dynamic conditions are such that the ethylene content and the melt flow rate (MFR.sub.2) of the resulting copolymer gradually changes from a first predetermined ethylene content, E1, to a second predetermined ethylene content, E2, and from a first predetermined melt flow rate, MFR.sub.2-1, to a second predetermined melt flow rate, MFR.sub.2-2; wherein collecting the copolymer powders in step b) is started when the polymer produced in step a) has a first ethylene content, E1, and a melt flow rate MFR.sub.2-1, and collecting the copolymer powders in step b) is stopped when the polymer produced in step a) has a second ethylene content, E2, and a melt flow rate MFR.sub.2-2; and wherein said pellets obtained in step d) have (i) a MFR.sub.2 (ISO 1133, 230 C., 2.16 kg) in the range of from 20 to 120 g/10 in, (ii) a ratio of MFR.sub.2 pellets/MFR.sub.2 powder>1, (iii) an ethylene content in a range of from 1.0 to 4.0 wt %, (iv) a crystallization temperature Tc, determined by DSC according to ISO 11357-3:1999 in the range of from 100 to 125 C., and (v) a flexural modulus, determined in a 3-point-bending according to ISO 178 on injection molded specimens of 80104 mm, prepared in accordance with EN ISO 1873-2, of 850 MPa or more.

Disclosed herein is an oxygen scavenging composition for containers. The oxygen scavenging composition for containers may comprise at least one polyester component, a transition metal catalyst, an oxygen scavenger, and a vegetable oil. The vegetable oil preferably comprises at least one molecule having a double allylic structure. The polyester component preferably comprises at least one acid unit and at least one diol unit. The concentration of double allylic structures of the vegetable oil in the composition may be greater than 5.0 meq/kg of all of the polyester components. The oxygen scavenger is preferably present in the composition at a level less than 1.0% by weight of the total composition. The vegetable oil is preferably present in the composition at a level greater than 0.3% by weight relative to the total weight of the polyester components, the transition metal catalyst and the vegetable oil.

Manufacture of 3D object by a printing method that enables the use several reactive materials sequentially. A laser-enhanced jetting-based 3D printer forms successive layers of reactive compositions on one another and the first and subsequent layers are allowed to crosslink between the printings to ultimately form the 3D object. Additional reactive compositions may be printed prior to the crosslinking. The crosslinking may be effected by heating, with or without a catalyst, and post printing curing may be employed after the 3D object is formed.

A foam molded article mold includes a lower mold with a cavity space; an upper mold formed with an upper mold face portion facing a lower mold face portion of the cavity space when the upper mold has been brought together with the lower mold; a partitioning wall that projects out from the upper mold face portion, and that configures a first parting line between the partitioning wall and the lower mold face portion in a state in which the upper mold has been brought together with the lower mold; and a partition that projects out from the lower mold face portion, and that, in a state in which the upper mold has been brought together with the lower mold, partitions the cavity space together with the partitioning wall to form plural cavities, and that configures a second parting line between the partition and the partitioning wall.