Injection molded parts with a small dimension that exhibit high heat resistance are described. Thermoplastic compositions that can be utilized to form the injection molded parts are described. The thermoplastic composition includes a polyarylene sulfide and a crosslinked impact modifier. The thermoplastic composition can also include siloxane polymers, thermoplastic elastomers, or other additives that can further improve the characteristics of the injection molded parts.

Polymer-based molds and methods of manufacturing are described. The method includes depositing two or more layers of a first material having a glass transition temperature (Tg) lower than about 70 C., in order to form a first portion of the mold and then depositing two or more layers of a second material having a Tg higher than about 80 C. to form a second portion of the mold. The method may further include depositing two or more layers of a material having a Tg lower than about 70 C. forming a third portion of the mold to cover the second portion.

The disclosure provides a thermally stable melt processable thermoset polymer composition including at least one melt processable thermoset polymer, such as an epoxy, and at least one reinforcing filler, such as carbon nanotubes. Such compositions when 3D printed, exhibit improved Z-layer adhesion and modulus at melt temperature, a common related additive manufacturing problem, as compared to thermoset polymers without reinforcing filler and more conventional thermoplastic resin systems. Subsequent actinic cure of such compositions irreversibly and permanently cures the material thereby making it no longer melt processable.

The present invention aims to provide a supporting material for supporting the shape of a photofabrication model on photofabrication in ink-jet three dimensional printing method in which the photocured product is excellent in solubility in water and is easy to remove after photofabrication, and the like. A modeling material for forming a photofabrication model in ink-jet three dimensional printing method containing a curable resin component with a weighted average of SP value of 9.0 to 10.3; and a supporting material for supporting the shape of a photofabrication model on photofabrication in ink-jet three dimensional printing method containing a water-soluble monofunctional ethylenically unsaturated monomer (F), polyoxypropylene glycol with a number average molecular weight of 100 to 5,000 and/or water (G), and a photopolymerization initiator (D).

The present invention aims to provide a supporting material for supporting the shape of a photofabrication model on photofabrication in ink-jet three dimensional printing method in which the photocured product is excellent in solubility in water and is easy to remove after photofabrication, and the like. A modeling material for forming a photofabrication model in ink-jet three dimensional printing method containing a curable resin component with a weighted average of SP value of 9.0 to 10.3; and a supporting material for supporting the shape of a photofabrication model on photofabrication in ink-jet three dimensional printing method containing a water-soluble monofunctional ethylenically unsaturated monomer (F), polyoxypropylene glycol with a number average molecular weight of 100 to 5,000 and/or water (G), and a photopolymerization initiator (D).

The invention relates to the use of compounds of formulae (I) and/or (II) as colorless IR absorbers wherein M is Ni, Pd, Pt, Au, Ir, Fe, Zn, W, Cu, Mo, In, Mn, Co, Mg, V, Cr or Ti, X.sub.1, X.sub.2 and X.sub.3 are each independently of the others sulfur or oxygen, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 are each independently of the others hydrogen, NR.sub.7R.sub.8, unsubstituted or substituted C.sub.1-C.sub.18alkyl, C.sub.1-C.sub.18 alkyl wherein the alkylene chain is interrupted with oxygen, unsubstituted or substituted C.sub.1-C.sub.18alkenyl, unsubstituted or substituted aryl, unsubstituted or substituted arylalkyl or unsubstituted or substituted heteroarylalkyl, R.sub.2 and R.sub.8, each independently of the other, being unsubstituted or substituted C.sub.1-C.sub.18alkyl, unsubstituted or substituted aryl, unsubstituted or substituted arylalkyl or unsubstituted or substituted heteroarylalkyl, a further IR absorber optionally being added to the compounds of formulae (I) and (II). The invention relates also to novel dithiolene compounds of formulae (I) and (II) wherein X.sub.1 is oxygen and X.sub.2 and X.sub.3 are oxygen or sulfur. The invention relates furthermore to novel dithiolene compounds of formulae (I) and (II) wherein R.sub.1 to R.sub.6 arc NR.sub.7R.sub.8.

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A polarizing plate protective film containing an acrylic resin, in which the acrylic resin includes a methyl methacrylate unit a, a mass fraction of an alkyl (meth)acrylate unit b other than methyl methacrylate is less than 5 mass %, a weight average molecular weight is 250,000 to 4,000,000, and a weight decreasing amount at the time of being heated at 140 C. for 1 hour is less than or equal to 0.5%, has excellent heat resistance and an excellent surface shape; a dope composition; a method for manufacturing a polarizing plate protective film; a polarizing plate; and a liquid crystal display device.

In the method for manufacturing conglomerate stone slabs using the Bretonstone technology, in the variant where the starting mixture is enclosed between two paper sheets, the improvement consists in replacing each paper sheet with a containment element consisting of a paper sheet, one surface of which has, applied thereon, a film of plastic material which is impermeable to organic vapours, impermeable to the liquids and in particular to the liquid resin constituting the binder of said mixture, resistant to the catalysis temperatures of the said resin and resistant to hot solvents and chemical vapours. Preferably, said plastic material is water-soluble, in particular polyvinyl alcohol.

Described herein are photopolymerizable compositions for use in 3D printing. The compositions contain highly crosslinkable acrylate monomers, oligomers comprising a polyether acrylate oligomer, a polyester oligomer, an unsaturated polyester oligomer, or a combination thereof and a photoinitiator. The compositions, after photopolymerization, have a high heat deflection temperature, while maintaining strong mechanical properties. Also described are methods for fabricating three dimensional objects utilizing these compositions, and three dimensional objects made from these compositions.

A method for producing an extruded polystyrene foam in which when a foamable melted product, obtained by heat-melting a styrene resin composition and adding a foaming agent thereto in an extruder provided with a die slit section having an opening a (mm) in the thickness direction, is extrusion-foamed through the die slit section into a low pressure zone to form a plate-shaped foam, thereby obtaining an extruded polystyrene foam having a density of 20 kg/m.sup.3 or more and 45 kg/m.sup.3 or less, a closed cell ratio of 90% or more, and a thickness A (mm) of 10 mm or more and 150 mm or less, a foaming agent containing hydrofluoroolefin and other organic foaming agent is used, a thickness extension ratio A/a of an opening a in the thickness direction of the die slit section and a thickness A of the extruded polystyrene foam is adjusted to 18 or less, and a foamable melted product, just before the extrusion from the die slit section, is pressurized to 4.5 MPa or more and 10.0 MPa or less.