Provided is a transparent, non-elastomeric optical article prepared by (1) combining to form a reaction mixture (a) a polyisocyanate component; and (b) an active hydrogen component including (b1) a first component free of amino groups including at least one first polyol; and (b2) a second component containing (i) a second polyol and/or a polythiol and (ii) a compound containing both amine and hydroxyl functional groups; (2) introducing the reaction mixture to a mold at a temperature and for a time sufficient to form a thermoset polymerizate; and (3) releasing the polymerizate from the mold to yield a transparent, non-elastomeric optical article. Also provided is a method for preparing a transparent optical film. Optical films and articles prepared by the methods also are provided.

Disclosed herein is an injection molding method for making optical thermoplastic lenses using 3Dprinted functional wafers. The method employs a variable injection molding cavity temperature that is heated to at least wafer Tg10 C.

A method for preparing eye-tracking glasses, comprising the following steps: providing a substrate assembly, the substrate assembly comprising a functional film, the functional film being arranged on a surface of the substrate assembly, and electronic components being arranged on the surface of the functional film. Pressing an injection mold against the substrate assembly to form an injection cavity, and making the surface of the functional film with the electronic components face an interior of the injection cavity. Injecting and molding an optical adhesive in the injection cavity to form a lens, with the electronic components embedded in the lens. Demolding the injection mold from the lens, separating the functional film from the substrate assembly to obtain the eye-tracking glasses.

The invention provides a method for producing embedded contact lenses involving steps of use of a set of 3 mold halves in two-curing steps. One of the 3 mold halves have been used twice, the first time for molding an insert and the second time for molding the embedded hydrogel contact lens. The twice-used mold half has been treated with a corona plasma or a vacuum UV in a central circular area of its molding surface having a diameter equal to or smaller than the diameter of the insert to ensure that the molded insert consistently adhered to the twice-used mold half. The method also comprises a step of forming a reactive polysiloxane coating that is covalently attached onto the back or front surface of a molded insert adhered on the twice-used mold half before molding the embedded contact lens in the 2.sup.nd curing step.

The invention provides a method for producing embedded diffractive contact lenses involving use of a mold set in two-curing steps. The mold set consists of three mold halves, one of which is used twice, the first time for molding a diffractive insert and the second time for an embedded contact lens with the molded diffractive insert embedded therein. The twice-used mold half has been treated with a corona plasma or a vacuum UV in a central circular area having a diameter equal to or smaller than the diameter of the insert to ensure that the molded insert consistently adheres to the twice-used mold half, even though the other mating insert mold half for molding the diffractive insert has a great tendency to bind strongly the molded insert due to the diffractive structure on its molding surface.

The invention provides a method for producing embedded contact lenses involving a mold set in a two-curing-step process and a fast-curing SiHy lens formulation. The mold set consists of three mold halves, one of which is used twice, the first time for molding an insert from an insert-forming composition and the second time for an embedded contact lens with the molded insert embedded therein from the fast curing SiHy lens formulation that comprises a N,N-dialkylacrylamide, a hydrophilic (meth)acrylamido monomer, and a polysiloxane vinylic crosslinker and being free of any siloxane-containing vinylic monomer.

The invention provides a method for producing delamination-resistant embedded contact lenses involving use of a mold set in two-curing steps and a special lens-forming composition for forming a bulk hydrogel material for embedding a crosslinked polymeric insert. The mold set consists of three mold halves, one of which is used twice, the first time for molding an insert from an insert-forming composition and the second time for an embedded contact lens with the molded insert embedded therein from the special lens-forming composition that a vinylic crosslinking agent and or organic solvent both of which independent of each other can swell an insert by a moderate swelling degree. The resultant embedded hydrogel contact lenses can be free of deformation and delamination.

Provided is a transparent, non-elastomeric optical article prepared by (1) combining to form a reaction mixture (a) a polyisocyanate component; and (b) an active hydrogen component including (b1) a first component free of amino groups including at least one first polyol; and (b2) a second component containing (i) a second polyol and/or a polythiol and (ii) a compound containing both amine and hydroxyl functional groups; (2) introducing the reaction mixture to a mold at a temperature and for a time sufficient to form a thermoset polymerizate; and (3) releasing the polymerizate from the mold to yield a transparent, non-elastomeric optical article. Also provided is a method for preparing a transparent optical film. Optical films and articles prepared by the methods also are provided.

A filament for use as a feedstock in three-dimensional printing of an optical device has a strand-like structure for continuous feeding into a printing nozzle of a three-dimensional printer. The strand-like structure includes one or more of elongated side-by-side core/cladding sections each having an optically transmissive inner core surrounded by a lower-index optically transmissive outer cladding for corresponding light guiding in the optical device. In embodiments, the core may be a solid material or an air core, and in the case of solid material may include scintillation material or other enhancements. Other variations and specifics are disclosed.

There is provided a method of making an optical polymer waveguide having an arbitrary refractive index profile, the method including: a) providing a first input optical beam having a first beam intensity profile and a second input optical beam having a second beam intensity profile; b) combining the first and second input optical beams to form an output optical beam having an output beam intensity profile; and c) forming the optical waveguide on a substrate by: exposing the optical materials of the waveguide to the output optical beam; and curing the optical materials using said output optical beam.