Described herein is a curable composition comprising an amorphous fluoropolymer having an iodine, bromine and/or nitrile cure site; a peroxide cure system comprising a peroxide and a Type II coagent; and a photoinitiator, wherein the curable composition is substantially free of a binder material. Also described herein, are methods of curing the curable composition using actinic radiation and articles thereof.

A multiple axis robotic additive manufacturing system includes a robotic arm movable in six degrees of freedom. The system includes a build platform movable in at least two degrees of freedom and independent of the movement of the robotic arm to position the part being built to counteract effects of gravity based upon part geometry. The system includes an extruder mounted at an end of the robotic arm. The extruder is configured to extrude at least part material with a plurality of flow rates, wherein movement of the robotic arm and the build platform are synchronized with the flow rate of the extruded material to build the 3D part.

A plasticizing apparatus, includes: a drive motor; a rotor that is rotated around a rotation axis by the drive motor and that has a groove forming surface on which a groove is formed; a barrel that has a facing surface facing the groove forming surface and that includes a communication hole in the facing surface; a heating portion that heats a material supplied to between the groove and the barrel; and a controller that controls the drive motor and the heating portion to plasticize the material supplied to between the groove and the barrel and discharge the material from the communication hole, the facing surface includes a first region and a second region that is closer to the communication hole than is the first region, the controller controls the heating portion to set a temperature of the second region to be higher than a temperature of the first region, and the controller controls the heating portion to reduce a temperature difference between the first region and the second region when the material includes a crystalline resin as compared with a case where the material includes an amorphous resin.

The invention relates to a multilayer biaxially oriented polyester film comprising a base layer B, an amorphous outer layer A and a further outer layer C, where this polyester film is suitable for lamination with metal sheets. The invention in particular relates to a polyester film which comprises (based on the mass of polyester) from 2 to 15% by weight of isophthalate-derived units in the base layer and which comprises more than 19% by weight of isophthalate-derived units in the amorphous layer A, and which has a silane-based coating on the outer layer A. The invention further relates to a process for the production of these films.

The present disclosure relates to crystallizable shrinkable films and thermoformable sheets comprising amorphous polyester compositions which comprise residues of terephthalic acid, neopentyl glycol (NRG), 1,4-cyclohexanedimethanol (CHDM), ethylene glycol (EG), and diethylene glycol (DEG), in certain compositional ranges having certain advantages and improved properties including recyclability.

A multiple axis robotic additive manufacturing system includes a robotic arm movable in six degrees of freedom. The system includes a build platform movable in at least two degrees of freedom and independent of the movement of the robotic arm to position the part being built to counteract effects of gravity based upon part geometry. The system includes an extruder mounted at an end of the robotic arm. The extruder is configured to extrude at least part material with a plurality of flow rates, wherein movement of the robotic arm and the build platform are synchronized with the flow rate of the extruded material to build the 3D part.

A resin molded body, includes: a polyolefin element including a crystalline region and an amorphous region; and a hydrophilic polymer contained in a region from a surface of the polyolefin element to part of the amorphous region located below the surface. Or, a method for producing a resin molded body, includes: preparing a polyolefin element including a crystalline region and an amorphous region; forming a coating of a hydrophilic polymer on a surface of the polyolefin element; and applying heat treatment to the polyolefin element on which the coating of the hydrophilic polymer is formed, wherein by applying the heat treatment, the coating of the hydrophilic polymer is immersed in a region from the surface to part of the amorphous region located below the surface.

An object of the present invention is to provide a stretchable polyester having shape followability and flexibility by elastic response and being able to suppress deterioration over time due to secondary crystallization. The present invention provides a stretchable polyester which is an aliphatic copolymer polyester containing two or more types of monomer units, wherein the stretchable polyester contains an α-form and an amorphous structure, and a degree of orientation determined by X-ray of the α-form is 50% or greater.

The present invention relates to a process for producing a three-dimensional component by means of selective laser sintering (SLS), wherein a processing temperature T.sub.x is established in a build chamber, and a powder layer consisting of a thermoplastic polymer powder is provided in the build chamber. The thermoplastic polymer powder comprises a blend of a semicrystalline polymer, an amorphous polymer and a polymeric compatibilizer. The polymer powder is then melted in a spatially resolved manner by means of a directed beam of electromagnetic radiation, wherein binding of the regions of the melted and resolidified polymer layer by layer in multiple steps affords a three-dimensional component. In the process of the invention, the temperature in the build chamber during the performance of the individual steps varies by not more than +/−10% from the processing temperature T.sub.x set. In addition, the processing temperature T.sub.x differs by not more than +/−20 K from the processing temperature T.sub.x(A) of a polymer powder comprising the corresponding semicrystalline polymer as the sole polymeric component.

A transparent multilayer coextruded heat shrinkable barrier film is useful for high-value packaging applications such as food and medical device packaging. The transparent multilayer coextruded heat shrinkable barrier film includes first and second outer layers formed using a transparent polyester or polyester copolymer; an inner nanolayer sequence including a plurality of nanolayers a) including ethylene vinyl alcohol, alternating with nanolayers b) including at least one of ethylene ethyl acrylate, low density polyethylene and linear low density polyethylene, each of the nanolayers b) having a degree of crystallinity less than about 45%; and adhesive layers between each of the two outer layers and the inner nanolayer sequence. The film has a light transmittance of at least about 80% and a heat shrunk of at least about ten percent in at least one direction.