The present invention relates to a flexible polymer-based microtube having an inner diameter of about 4 ?m to about 1000 ?m and a variable outer diameter, wherein the cross-sectional shape of the microtube can be, for instance, circular, rectangular, square, triangular, elliptical, star or irregular. The present invention also relates to a method of making the flexible microtube and devices incorporating the flexible microtube.

Disclosed are bioprinters for rapidly fabricating biological tubes comprising extruding a bio-ink filament onto a rotating mandrel. Also disclosed are methods of rapidly fabricating biological tubes comprising extruding a bio-ink filament onto a rotating mandrel, maturing the deposited bio-ink filament, and removing the biological tube from the mandrel. Also disclosed are methods of fabricating a multilayered biological tube. Also disclosed are engineered biological tubes prepared using the disclosed methods.

This disclosure provides methods and systems for the additive manufacturing of three-dimensional workpieces using a support fluid build. In one aspect, a method is provided for forming a three-dimensional workpiece, the method comprising dispensing a resin in a liquid state into a container, irradiating at least a portion of the resin layer at the fluid interface with light to polymerize an irradiated portion of the resin layer as a current build layer of the three-dimensional workpiece at the fluid interface, wherein a portion of the three-dimensional workpiece is affixed to a build platform immersed in the support fluid; and advancing the build platform to a next position in the support fluid to submerge the current build layer within the support fluid. The process is repeated to successively build the workpiece in the support fluid.

This invention generally relates to polyethylene or ethylene/?-olefin copolymer based co-extruded, multi-layer films or sheetsrigid or flexiblefor thermoforming into shaped containers such as packaging containers. Inter alia, the rigid films have improved barrier properties, toughness, and snapability. Particularly, the films of the present invention comprise one or more stacks of polypropylene layers. In one embodiment, the polypropylene layers in the stack are provided such that any two adjacent layers have different microstructures that provide a interface or interphase between the two layers with likely different microstructures and/or crystallinity. The overall polypropylene stack structure assists in disrupting the transport of oxygen, thereby providing a laminate or structure, for example a rigid film or sheet, with enhanced oxygen-barrier properties. The invention also relates a process for preparing shaped articles such as containers from such films, and to such shaped articles-rigid or flexible-both filled and unfilled.

A method of forming a three-dimensional object, is carried out by (a) providing a carrier and a build plate, the build plate comprising a semipermeable member, the semipermeable member comprising a build surface with the build surface and the carrier defining a build region therebetween, and with the build surface in fluid communication by way of the semipermeable member with a source of polymerization inhibitor; (b) filling the build region with a polymerizable liquid, the polymerizable liquid contacting the build surface; (c) irradiating the build region through the build plate to produce a solid polymerized region in the build region, while forming or maintaining a liquid film release layer comprised of the polymerizable liquid formed between the solid polymerized region and the build surface, the polymerization of which liquid film is inhibited by the polymerization inhibitor; and (d) advancing the carrier with the polymerized region adhered thereto away from the build surface on the build plate to create a subsequent build region between the polymerized region and the build surface; (e) wherein the carrier has at least one channel formed therein, and the filling step is carried out by passing or forcing the polymerizable liquid into the build region through the at least one channel. Apparatus for carrying out the method is also described.

A positive electrode (10) for an air cell of the present invention includes: a catalyst layer (11) composed of a porous layer containing electrical conductive carbon (1), a binder (2), and a catalyst component (3); and a fluid-tight gas-permeable layer (12) composed of a porous layer containing an electrical conductive carbon (1a) and a binder (2). The fluid-tight gas-permeable layer is stacked on the catalyst layer. This configuration can facilitate series connection of the air cells while preventing electrolysis solution from leaking out of a positive electrode. It is therefore possible to enhance the manufacturing efficiency and handleability of the air cells.

A method of forming a three-dimensional object, comprises providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; filling the build region with a polymerizable liquid; irradiating the build region through the optically transparent member to form a solid polymer from the polymerizable liquid while concurrently advancing the carrier away from the build surface to form the three-dimensional object from the solid polymer, while also concurrently: (i) continuously maintaining a dead zone of polymerizable liquid in contact with the build surface, and (ii) continuously maintaining a gradient of polymerization zone between the dead zone and the solid polymer and in contact with each thereof, the gradient of polymerization zone comprising the polymerizable liquid in partially cured form. Apparatus for carrying out the method is also described.

A diffuser membrane and a method for manufacturing the same are provided. In the method for manufacturing, a first material is heated and extruded to form a base layer and a second material is heated and extruded to form a coating layer. The base layer and coating layer may be extruded substantially simultaneously in a coextrusion process. Accordingly, the coating may be applied to the base layer in a manner that optimizes the bonding between the two layers and provides the ability to control the thickness of the coating layer. Alternatively, the base layer is formed initially and the coating layer is subsequently formed thereover. The first and second materials have differing properties. The first material may comprise polyurethane and the second material may comprise polyurethane and PTFE.

Polymeric layers (50) comprising an array of blind openings (56) extending into the first major surface (52, 10111, 11211), but not through the second major surfaces (54, 10112, 11212). The blind openings each have a series of areas through the openings from the first major surface towards the second major surfaces ranging from minimum to maximum areas, where for at least a majority of the blind openings the minimum area is not at the first major surface. At least a portion of the first major surface comprises a first material and extends up to, but not into the second major surface. At least a portion of the second major surface comprises a second, different material. Methods for making the polymeric layers are also disclosed. Polymeric layers are useful, for example, as components in personal care garments such as diapers and feminine hygiene products. They can also be useful for filtering (including liquid filtering) and acoustic applications.

A method of forming a three-dimensional object, is carried out by (a) providing a carrier and a build plate, the build plate comprising a semipermeable member, the semipermeable member comprising a build surface with the build surface and the carrier defining a build region therebetween, and with the build surface in fluid communication by way of the semipermeable member with a source of polymerization inhibitor; (b) filling the build region with a polymerizable liquid, the polymerizable liquid contacting the build surface, (c) irradiating the build region through the build plate to produce a solid polymerized region in the build region, while forming or maintaining a liquid film release layer comprised of the polymerizable liquid formed between the solid polymerized region and the build surface, wherein the polymerization of which liquid film is inhibited by the polymerization inhibitor; and (d) advancing the carrier with the polymerized region adhered thereto away from the build surface on the build plate to create a subsequent build region between the polymerized region and the build surface while concurrently filling the subsequent build region with polymerizable liquid as in step (b). Apparatus for carrying out the method is also described.