Provided is a melt processible fluororesin composition for injection molding of articles that has melt flow that facilitates injection molding, that can enhance strength of a fluororesin weld line area in an injection molded article, and that achieves excellent release from a mold. The fluororesin composition includes two or more types of melt processible fluororesins having different melt flow rates; one of the melt processible fluororesins being a high melt flow rate melt processible fluororesin having a melt flow rate of 35 g/10 min or greater, and another being a low melt flow rate melt processible fluororesin having a melt flow rate of 10 g/10 min or greater but less than 35 g/10 min; and wherein the ratio of the melt flow rate (MFRa) of the high MFR melt processible fluororesin to the melt flow rate (MFRb) of the low MFR melt processible fluororesin (MFRa/MFRb) is from 1 to 10.

Disclosed are compositions, methods and uses for thin multi-layered films that may include a metallizable skin layer that include polyethylene polymer(s), wherein the metallizable skin layer may be treated one or more times. The multi-layered films include a core layer and a sealant layer, wherein each of these layers includes metallocene-catalyzed, linear, low-density polyethylene. The core layer is located between the metallizable skin layer and the sealant layer. These films may include one or more additives in any of the layers and/or include one or more tie layers. The multi-layered films may be biaxially oriented, have a haze equal to or below 5%, and have an elastic modulus equal to or below 350 N/mm.sup.2. The multi-layered films may also include a metallized layer on the metallizable skin layer, a coated layer on the metallizable skin layer, and/or be laminated to a polyethylene-based polymer, such as polyethylene terephthalate.

A surrogate multilayered material and manufacturing method thereof includes a first fiber reinforced layer, the first reinforced layer including a crosslinked polymer and fibers, and a second fiber reinforced layer, the second reinforced layer including the crosslinked polymer and the fibers. A foam layer is disposed between the first and second fiber reinforced layers. Opposite faces of the foam layer are in direct contact with the first fiber reinforced layer and the second fiber reinforced layer. The foam layer has a compressive strength of about 3.5 to about 4.5 MPa, when measured as per ASTM-D-1621-73, and a shear strength of 1.50 to about 2.15 MPa, when measured as per ASTM-C-273.

A die and method for impregnating at least one fiber roving with a polymer resin are disclosed. In one embodiment, the die includes an impregnation section including an impregnation zone configured to impregnate the roving with the resin, the impregnation zone including a plurality of contact surfaces. The die further includes a perturbation positioned on at least one of the plurality of contact surfaces, the perturbation configured to interact with the roving. In one embodiment, the method includes coating a fiber roving with a polymer resin. The method further includes traversing the coated roving through an impregnation zone to impregnate the roving with the resin. The impregnation zone includes a plurality of contact surfaces. The method further includes interacting the coated roving with a perturbation positioned on at least one of the plurality of contact surfaces.

A roller for a vacuum cleaner comprises: an interior roller body which comprises a resiliently deformable region; and an exterior abrasion-resistant skin which surrounds the interior roller body.

Self-supporting uniaxially expanded polytetrafluoroethylene (ePTFE) membranes that have high intrinsic strength, a high matrix modulus, and a high crystallinity index are provided. In some embodiments, the ePTFE membrane is stretched in the machine direction. Uniaxially oriented ePTFE membranes have a matrix tensile strength at least about 1000 MPa in the machine direction, a matrix modulus at least about 100 GPa ambient temperature (i.e., about 20° C.), and a crystallinity index of at least about 94%. In some embodiments, the ePTFE membrane has a tenacity greater than or equal to about 5 gf/d and a denier less than or equal to about 750 g/9000 m. In addition, the uniaxially oriented ePTFE membranes have a <P2> orientation of at least about 0.98. Also, the fibrils in the ePTFE membranes have a nearly perfect parallel alignment. The ePTFE membrane may be used to form composites, laminates, fibers, tapes, sheets, tubes, or other three-dimensional objects.

A resin powder for solid freeform fabrication contains pillar-like form particles having an average circularity of 0.83 or greater in a particle diameter range of from 0.5 to 200 μm.

The present invention relates to photocurable compositions, comprising (A1) a N-vinyloxazolidinone of formula (I), wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently of each other a hydrogen atom or an organic group having not more than 10 carbon atoms, (A2) optionally one, or more second reactive diluents, (B) one, or more oligomers, and (C) a photoinitiator (C), wherein the amount of component (A1) is 5 to 70% by weight based on the amount of components (A1), (A2) and (B), wherein the viscosity of said photocurable composition is in the range 10 to 3000 mPa.Math.s, preferably 10 to 1500 mPa.Math.s at 30° C. The compositions, from which cured three-dimensional shaped articles having balanced mechanical properties combining stiffness with high toughness can be made, are particularly suitable for the production of three-dimensional articles by stereolithography and photopolymer jetting.

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The present disclosure provides methods and compositions for directed to synthetic block copolymer proteins, expression constructs for their secretion, recombinant microorganisms for their production, and synthetic fibers (including advantageously, microfibers) comprising these proteins that recapitulate many properties of natural silk. The recombinant microorganisms can be used for the commercial production of silk-like fibers.

The disclosure generally relates to 3D printed articles prepared from filaments comprising an ionomer (A) prepared from a base resin (B); wherein: base resin (B) is prepared from ethylene and at least one C.sub.3 to C.sub.8 α,β ethylenically unsaturated carboxylic acid monomer; the carboxylic acid moieties of base resin (B) are 10 to 99.5 percent neutralized by zinc or lithium; the at least one C.sub.3 to C.sub.8 α,β ethylenically unsaturated carboxylic acid is present from about 2 weight percent to about 30 weight percent, based on the weight of base resin (B).