A method for preparing a sacrificial support material for use in printing a three-dimensional (3D) article includes providing a water-soluble thermoplastic polymer composite including a water-soluble thermoplastic polyethylene oxide graft polymer having a polyethylene oxide polymer backbone, and from about 0.05% to about 10% by weight of the polyethylene oxide polymer backbone of at least one polar vinyl monomer grafted to the polyethylene oxide polymer backbone. One or more nanoscopic particulate processing aids may be uniformly dispersed in the graft polymer in an amount of from about 0.05% to about 10% by weight of the water-soluble thermoplastic polymer composite. The water-soluble thermoplastic polymer composite may have a viscosity in the range of about 100 to about 10,000 Pa-sec. The method may also include forming the water-soluble thermoplastic polymer composite into the 3D printable sacrificial support material.

Over an outer peripheral surface of a sleeve, a primer layer is formed that is a thermoplastic resin-based adhesive thermally melted at a temperature lower than a melting point of a thermoplastic resin formed into a resin member to exhibit adhesiveness. With the sleeve preheated, a thermoplastic resin to be formed into the resin member is annularly injection-molded over an outer periphery of the sleeve.

The present disclosure is directed to systems and methods for synthesizing a spidroin. In some embodiments, the methods comprise synthesizing a monomer in vivo in a heterologous host, the monomer comprising an N-terminus IntC domain and a C-terminus IntN domain, and post-translationally polymerizing the synthesized monomer via in vitro split-intein mediated polymerization.

Provided is a thermoplastic resin composition having high flame resistance, high fluidity during injection molding, and improved impact resistance in a molded article. To provide a method for producing a thermoplastic resin composition, the method including a step (1) of obtaining a polyester resin mixture by melt-kneading a crystalline terephthalate-based polyester resin, and a polyester resin A including at least one kind selected from the group consisting of isophthalic acid, orthophthalic acid, naphthalenedicarboxylic acid, anthracene dicarboxylic acid and pyridine dicarboxylic acid as an aromatic dicarboxylic acid component with an extruder, and a step (2) of mixing the polyester resin mixture, a polycarbonate resin, a flame retardant and a toughening agent.

An optical waveguide includes a textured light-diffracting layer. The optical waveguide is made from a poly(aliphatic ester)-polycarbonate copolymer having very high flow properties and good impact properties. A method of manufacturing the waveguide by injection molding, a method of incorporating a microprism structure and a method of scattering light by directing light through a light-scattering layer thereby produced on the waveguide are also disclosed.

A reinforcing article (10, 100, 200) includes a porous substrate layer (105, 205) and a plurality of parallel first continuous fiber elements (12, 114, 212) spaced apart from each other and extending along a first direction and fixed to the porous substrate (105, 205). Each first continuous fiber element (12, 114, 212) includes a plurality of parallel and co-extending continuous fibers (22, 122, 222) embedded in a thermoplastic resin (24, 124, 224).

A method of bioprinting a bioink printed structure and a bioprinted composition resulting from this method is provided. Biological cells are mixed with biomaterial inks. These biomaterial inks have a biopolymer backbone with grafted thereto a first bio-orthogonal chemical group. The mixed biological cells and biomaterial inks are extruded into a support bath. The next step is diffusing crosslinking molecules which have a second (complementary to the first) bio-orthogonal chemical group, in the support bath, whereby the diffusing crosslinking molecules react via bioorthogonal click-chemistry between the first and second bio-orthogonal chemical groups resulting in covalently crosslinking the biomaterial ink into a printed structure. Embodiments of this invention can be directed towards personalized medicine and printed tissue engineering constructs, as well as drug discovery by printing complex tissue mimics or printing model vasculature for studying cardiovascular disease.

Disclosed herein are ethylene-based polymers having low densities and narrow molecular weight distributions, but high melt strengths for blown film processing. Such polymers can be produced by peroxide-treating a metallocene-catalyzed resin.

The present invention is a thermoplastic polymer composition which contains 10-120 parts by mass of a polar group-containing polypropylene resin (B) per 100 parts by mass of a thermoplastic elastomer (A) that is a block copolymer having a polymer block containing an aromatic vinyl compound unit and a polymer block composed of a conjugated diene unit having 40% by mole or more of 1,2-bonds and 3,4-bonds in total, or a hydrogenated product of the block copolymer (provided that a thermoplastic polymer composition containing 1 part by mass or more of a polyvinyl acetal resin is excluded). This thermoplastic polymer composition is able to be bonded with a ceramic, a metal or a synthetic resin without requiring a primer treatment, and has excellent flexibility, mechanical characteristics, moldability, heat resistance and storage stability.

A method for fabricating an embodiment of a medical device comprising the steps of: preparing a biodegradable polymeric structure; coating the biodegradable polymeric structure with a polymeric coat including a pharmacological or biological agent; cutting the structure into patterns configured to allow for crimping of the cut structure and expansion of the cut structure after crimping into a deployed configuration.