A method of additive manufacturing of a three-dimensional object includes sequentially dispensing and solidifying a plurality of layers. The plurality of layers may be formed with a plurality of different colored model materials, a flexible material arranged in a configured pattern to form a sacrificial structure at least partially encompassing the object, and a soft material. The soft material is arranged in a configured pattern to provide separation between the model material and the sacrificial structure. The plurality of different colored model materials is arranged in a configured pattern corresponding to the shape and color definition of the object.

A laminate shaping support material is provided which includes one of: a resin composition containing a polyvinyl alcohol resin having a primary hydroxyl group at its side chain, and having a heat of fusion of 10 to 30 J/g at its melting point (Embodiment (X)); and a resin composition containing a polyvinyl alcohol resin, and a block copolymer including a polymer block of an aromatic vinyl compound, at least one of a polymer block of a conjugated diene compound and a block of a hydrogenated conjugated diene compound, and a functional group reactive with a hydroxyl group (Embodiment (Y)). Therefore, the laminate shaping support material according to Embodiment (X), for example, is excellent in shape stability and adhesiveness to a model material. The laminate shaping support material according to Embodiment (Y) is excellent in peelability and forming stability.

An object of the present invention is to provide a method for forming an antiglare hard coat layer having a concavo-convex shape that exhibits a good antiglare property and being superior in scratch resistance.

A oil gel composition, consisting essentially of: 65-80 wt. % of a mineral oil, 15-25 wt. % of a hydrogenated styrenic block copolymer (HSBC), 1 to 15 wt. % of glass spheres having an average particle size of at least 15 microns, 1 at least 50 wt. % of a plasticizer selected from mineral oil, a paraffinic oil, an oil-enriched in paraffin, and mixtures thereof, and 0.25-5 wt. % of a tack reducing component selected from the group of steric acid, metal stearates, long chain fatty acids, fatty acid salts, fatty acid esters, amide waxes, ethylene-bis-stearamides, erucamide, polyester modified siloxanes, and mixtures thereof. The oil gel composition has an average peel strength of less than 0.3 lbf/in measured according to ASTM D 1876. Articles formed from the oil gel composition are characterized as being tack-free.

A multilayer composite structure is disclosed. The multilayer composite structure has at least one polymer-based cap layer containing, for example, an acrylic, styrenic or acrylonitrile polymer and at least one polyester-based inner or substrate layer. Also disclosed are methods of forming the multilayer composite structure to improve and control the level of adhesion between the layers. Optional tie layers can be used to improve and control the level of adhesion between the layers. An optional exterior layer over the cap layer can contain polyvinylidene fluoride (PVDF) polymers. The multilayer composite structure combines the attributes of both polymersthe high UV stability, scratch resistance, and excellent appearance of the polymer-based outer cap layer and the strength and impact resistance of the polyester-based interior layer.

A composite structure that includes a multi-layer laminate including a plurality of layers of material, and at least one crack barrier layer extending within the plurality of layers of material. The multi-layer laminate is folded to define a first web region and a second web region in a face-to-face relationship, and a folded tip region defined between the first web region and the second web region. The at least one crack barrier layer is configured to restrict crack propagation from spreading through the plurality of layers of material in the folded tip region.

The present invention provides methods of preparing peelable seal layers, methods of preparing multilayer films, peelable seal layers made therefrom, and multilayer films made therefrom. In one aspect, a method of preparing a peelable seal layer comprises (a) providing a first blend comprising (i) from 5 to 98 percent by weight of a reactor grade propylene based plastomer or elastomer having a molecular weight distribution of less than 3.5 and a density of less than 0.89 g/cc and (ii) from 2 to 95 percent by weight of a second polymer selected from the group consisting of polyethylene, polybutylene, and styrenic polymer and mixtures thereof; (b) providing at least one linear low density polyethylene; (c) blending the first blend with the at least one linear low density polyethylene to obtain a second blend; and (d) extruding the second blend to form a peelable seal layer, wherein the peelable seal layer has a heat seal initiation temperature less than 120 C. when sealed at a bar pressure of 40 psi with a dwell time of 0.5 seconds.

A method of manufacturing an in-mold decorative molded product including a transfer layer formed on a surface of an injection-molded product, the method including: inserting in a first mold for injection molding an in-mold transfer film including the transfer layer disposed on a base film; forming a molding injection space by mold clamping of the first mold and a second mold including a structure for injecting a resin into the molding injection space and a structure for holding a molded product; and forming a molded product by filling the molding injection space with a molding resin and then opening the second mold and the first mold, wherein when the base film is separated from the in-mold decorative molded product integrated with and the transfer layer by opening the molds, a peeling weight varies depending on a portion in an end part of the in-mold decorative molded product so that a peeling starting point is generated from a position with a light peeling weight in the in-mold transfer film to peel the in-mold decorative molded product from the in-mold transfer film.

A laminate shaping support material is provided which includes one of: a resin composition containing a polyvinyl alcohol resin having a primary hydroxyl group at its side chain, and having a heat of fusion of 10 to 30 J/g at its melting point (Embodiment (X)); and a resin composition containing a polyvinyl alcohol resin, and a block copolymer including a polymer block of an aromatic vinyl compound, at least one of a polymer block of a conjugated diene compound and a block of a hydrogenated conjugated diene compound, and a functional group reactive with a hydroxyl group (Embodiment (Y)). Therefore, the laminate shaping support material according to Embodiment (X), for example, is excellent in shape stability and adhesiveness to a model material. The laminate shaping support material according to Embodiment (Y) is excellent in peelability and forming stability.

The present invention is a soluble material for three-dimensional modeling that is used as a material of a support material for supporting a three-dimensional object when the three-dimensional object is manufactured by a 3D printer of a fused deposition modeling system and that contains a thermoplastic resin having a hydrophilic group and an organic salt compound represented by a general formula (I) below: (R.sup.1-SO.sub.3.sup.).sub.nX.sup.n+ (I). According to the present invention, it is possible to provide a soluble material for three-dimensional modeling that is used for a support material and that is capable of suppressing the degradation of the modeling accuracy of a three-dimensional object when the three-dimensional object is manufactured by a 3D printer of a fused deposition modeling system, and has a high rate of dissolution to neutral water to be removable speedily from a precursor of the three-dimensional object without use of a strong alkaline aqueous solution.