[Problem] To provide: a resin-coated metallic plate which cannot undergo the occurrence of a retort brushing phenomenon (the formation of white spots) or the delamination of a film under retort sterilization treatment conditions; and others. [Solution] A resin-coated metallic plate having a resin layer (A) and a resin layer (B) is characterized in that the resin layer (A) contains 50 to 80 wt % of a polyethylene terephthalate-based resin (I) and 20 to 50 wt % of a polybutylene terephthalate-based resin (II), wherein the resin layer (B) contains 50 to 80 wt % of a polyethylene terephthalate-based resin (III) and 20 to 50 wt % of a polybutylene terephthalate-based resin (II), the polyethylene terephthalate-based resin (I) has a melting point of 210 to 230 C. inclusive, the polybutylene terephthalate-based resin (II) has a melting point of 215 to 225 C. inclusive, and the polyethylene terephthalate-based resin (III) has a melting point of higher than 230 C. and 205 C. or lower.

[Problem] To provide a polyester resin-coated metal sheet which has excellent coating material adhesion capable of withstanding severe forming processing while retaining high decorative property and photoluminescence property and a container using the same. [Solution] The polyester resin-coated metal sheet of the present invention includes a metal sheet, and a non-oriented polyester resin formed of a plurality of layers provided on at least one surface of the metal sheet. A surface layer and an adjacent layer in contact with the surface layer, of the plurality of layers, have a difference therebetween in melting temperature of not less than 10 C., and a difference in tensile stress at an elongation of 250% under an environmental temperature of 70 C. of less than 3 MPa in tensile tests in a single-layer film state corresponding to each layer, and the surface layer contains fine particles.

The invention provides a heat-shrinkable polyester film which has sufficient heat shrinkage properties in a main shrinkage direction that is in the longitudinal direction, has low heat shrinkage in the width direction orthogonal to the main shrinkage direction, does not have excessively high shrinkage stress in the main shrinkage direction, and has small attenuation of the shrinkage stress, whereby the followability to a container which is an object to be packaged is high, and slack is less likely to be generated.

A resin film for laminating on metal sheet is provided which is composed of a polyester resin having such a mechanical property that a true stress at which a true strain of 1.0 as measured at 45 C. is obtained is 13 to 40 MPa. In addition, a resin film for laminating on metal sheet is provided in which the polyester resin is a material obtained by blending of a polytrimethylene terephthalate resin and a polybutylene terephthalate resin (PTT resin content: 20 to 80 mass %) or a two-layer resin film of a polyester resin and a polyethylene terephthalate resin, wherein the thickness of the polyester resin layer is not less than one half the total resin layer thickness.

A method for producing high strength three piece steel can body and cans produced therewith.

This invention relates to clear, semicrystalline, strain induced crystallized polyester films heat laminated onto metal substrates. The films contain at least one polyester which comprises at least of one or more monomers selected from 1,4-cyclohexanedimethanol or 2,2,4,4-tetramethyl-1,3-cyclobutanediol. The articles of the present invention exhibit enhanced mechanical properties useful for the fabrication of thin metal articles such as metal cans.

Embodiments of the invention provide a hard coat film, including a film base material and a hard coat arranged on at least one surface of the film base material, wherein the hard coat is comprised of an active energy ray-curable resin composition. The active energy ray-curable resin composition includes 100 parts by mass of (P) a urethane (meth)acrylate compound, 0.02 to 5 parts by mass of (Q) organic fine particles having an average particle size of 10 to 300 nm, and 0.0002 to 2 parts by mass of (R) an acrylic silicon leveling agent. The (R) acrylic silicon leveling agent is loaded in the active energy ray-curable resin composition in an amount of 1 part by mass or more based on 100 parts by mass of the (Q) organic fine particles.

A three-piece resealable can for acidic liquid includes, a cylindrical can body member that includes a screw portion at one end; and a can bottom member that contacts the can body member so as to close an opening portion of the other end of the can body member. The can body member includes a cylindrical first steel sheet, Ni plating that is formed on an inner circumferential surface of the first steel sheet, a polyester film that is formed so as to be disposed on the outermost surface of the inner circumference of the can body member, and a Zr-containing film that is formed between the first steel sheet and the polyester film. The can bottom member includes a second steel sheet, and Sn plating that is formed on the can body member side of the can bottom member. The Zr-containing film contains Zr compounds.

A resin-coated metal sheet for containers that has excellent content releasability is provided. The resin-coated metal sheet includes a resin layer (A) and a resin layer (B). The resin layer (A) has a multilayer structure and is disposed on a side which, after the metal sheet is formed into a container, becomes the inner side of the container. The resin layer (B) is disposed on a side that becomes the outer side of the container. The resin layer (A) contains polyester as a main component and includes an uppermost resin layer (a1). A Raman band intensity ratio (I.sub.2968/I.sub.3085) on the surface of the resin layer (a1) is 0.6 to 0.9. The resin layer (B) includes polyester (I) composed mainly of polyethylene terephthalate and a polyester (II) composed mainly of polybutylene terephthalate. A Raman band intensity ratio on the surface of the resin layer (B) is 0.8 to 1.0.

It is provided that a polyester-based film for laminating a metal plate having corrosion resistance, being capable of being adhered to a metal plate at a relatively low temperature, having excellent can-making properties, and easily repairing a joint part after can making. A polyester-based film for laminating a metal plate constituted by two layers of Layer A and Layer B, wherein a resin constituting Layer A is a polyester-based resin having a total content of ethylene terephthalate units and diethylene terephthalate units of not less than 95% by mol and not more than 98% by mol, in 100% by mol of total constituent units of the polyester, and a resin constituting Layer B comprises 80 to 100% by mass of a polyester-based resin (B1) mainly including ethylene terephthalate and 0 to 20% by mass of a polyester-based resin (B2) having composition different from composition of the polyester-based resin (B1).