A method of preparing a printing form precursor for printing, or a printed circuit board precursor or a semiconductor precursor, the method comprising the step of applying electromagnetic radiation having a pulse duration of not greater than 110.sup.6 seconds, in an imagewise manner, to an imagable surface of the precursor. The imaging process may cause ablation of the coating of the precursor or permit its development in a developer. In each case the imaging radiation needs not be tuned to imaging chemistry (if any) present in the coating. Alternatively the imaging process may induce a change of hydrophilicity or hydrophobicity, or other change of state, of an uncoated substrate.

An apparatus and method of manufacturing a fluorosilicone composite for a variable data lithography imaging member surface layer. Examples of the fluorosilicone composite include a first part and a second part, the first part having fluorosilicone, carbon black, silica and butyl acetate, the second part having a platinum catalyst, a crosslinker, butyl acetate and an inhibitor. The first part may also include a dispersant (e.g., a polyoxyalkylene amine derivative) that removes a need for shaking the dispersion by paint shaker and instead allows a more manufacture friendly roll ball milling process. The dispersant will also help in stabilizing the fluorosilicone composite for scaled up production.

An ink-based digital printing system for variable data lithographic printing includes an imaging member having a surface configured to absorb dampening fluid. A dampening fluid patterning system jets dampening fluid onto the imaging member surface according to image data to form a dampening fluid pattern. The system includes a transfer member that receives the jetted dampening fluid pattern from the imaging member at a dampening fluid loading nip for subsequent inking of the dampening fluid pattern to form an ink pattern. The ink pattern is transferred to a substrate from the transfer member at an ink pattern transfer nip.

A method of preparing a printing form precursor for printing, or a printed circuit board precursor or a semiconductor precursor, the method comprising the step of applying electromagnetic radiation having a pulse duration of not greater than 110.sup.6 seconds, in an imagewise manner, to an imagable surface of the precursor. The imaging process may cause ablation of the coating of the precursor or permit its development in a developer. In each case the imaging radiation needs not be tuned to imaging chemistry (if any) present in the coating. Alternatively the imaging process may induce a change of hydrophilicity or hydrophobicity, or other change of state, of an uncoated substrate.

The invention pertains to a printing form precursor, a method of preparing a printing form from the precursor, and a process of preparing the precursor. The printing form precursor includes a photopolymerizable layer, an elastomeric layer having at least an elastomeric binder and particulate, and an actinic radiation opaque material on, adjacent, or disposed above the elastomeric layer opposite the photopolymerizable layer. The particulate is selected from specific material particles having an average diameter from 1 to 10 micron and a refractive index that is within 0.04 units of an index of refraction of the composition forming the elastomeric layer.

An ink-based digital printing system for variable data lithographic printing includes an imaging member having a surface configured to absorb dampening fluid. A dampening fluid patterning system jets dampening fluid onto the imaging member surface according to image data to form a dampening fluid pattern. The system includes a transfer member that receives the jetted dampening fluid pattern from the imaging member at a dampening fluid loading nip for subsequent inking of the dampening fluid pattern to form an ink pattern. The ink pattern is transferred to a substrate from the transfer member at an ink pattern transfer nip.

This disclosure is directed to a material composition that may be usable as a surface component in a plate design for use in variable data digital lithographic image forming devices. The disclosed material composition incorporates infra-red (IR) absorbing filler materials, including carbon black filler material particles in a fluorosilicone polymer or elastomer. The inclusion of the disclosed carbon black material compositions promotes precise heating in a patterning step for a layer of dampening fluid while minimizing harmful byproduct emissions including emissions of trifluoropropionaldehyde (TFPA) resulting from localized heating of a principally fluorosilicone imaging layer. The disclosed homogeneously-dispersed carbon black particles are particularly usable for improving operational characteristics of fluorosilocone-based reimageable surface layers of imaging members employed in the variable data digital lithographic image forming devices.

This disclosure is directed to a plate design for use in variable data digital lithographic image forming devices. The disclosed plate design incorporates surface passivated carbon black filler material particles in a fluorosilicone polymer. The disclosed functionalized carbon black material compositions include hydrophobic carbon black particles passivated with polymerized pentafluorostyrene. The disclosed surface passivated carbon black particles have a diameter in a range of 50 nanometers to 1 micron, and enable enhances dispersion in fluorinated polymers, and fine dispersion in solvent. The disclosed surface passivated carbon black particles are particularly usable for improving operational characteristics of fluorosilocone-based reimageable surface layers of imaging members employed in the variable data digital lithographic image forming devices.

An ink-based digital printing system for variable data lithographic printing includes an imaging member having a surface configured to absorb dampening fluid. A dampening fluid patterning system jets dampening fluid onto the imaging member surface according to image data to form a dampening fluid pattern. The system includes a transfer member that receives the jetted dampening fluid pattern from the imaging member at a dampening fluid loading nip for subsequent inking of the dampening fluid pattern to form an ink pattern. The ink pattern is transferred to a substrate from the transfer member at an ink pattern transfer nip.

Lithographic printing plates are formed by imagewise exposing a single-layer or dual-layer positive-working lithographic printing plate precursor. The precursor has an outermost ink receptive layer containing a phenolic resin. The exposed precursor can be processed using a silicate-free developer composition having a pH of at least 12.5. This composition also includes an alkali metal hydroxide; a coating protecting agent that is a quaternary ammonium salt or phosphonium salt, or a mixture thereof, and a moderator for the coating protecting agent that is represented by the following general formula (I):

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wherein m is at an integer of at least 1 and up to and including 10 and M represents one or more counterions sufficient to balance the negatively-charged sulfonate groups.