A recording medium comprises an oleophilic substrate and, thereover, a topmost oleophobic layer comprising a cured polymeric silicone matrix that consists essentially of the addition-cure reaction product of a vinyl-functional polydialkylsiloxane and a silane cross-linking agent. The vinyl-functional polydialkylsiloxane has a molecular weight ranging from 30,000 to 75,000 or 110,000 to 130,000. If the molecular weight of the vinyl-functional polydialkylsiloxane is within the range of 30,000 to 75,000, the molar ratio of silane groups to vinyl groups is within the range of about 11:1 to about 25:1; and if the molecular weight of the vinyl-functional polydialkylsiloxane is within the range of 110,000 to 130,000, the molar ratio of silane groups to vinyl groups is from about 5:1 to about 27:1. The recording medium may be used as a lithographic printing plate.

A nanoimprint lithography template, a system for using the template and a method of using the template. The template may comprise a body having a front side with a shaping surface. The back side may have a central core-out that is located opposite the shaping surface. A first peripheral region may be bounded by: the central core-out; a first edge of the template; and a first set of two parallel perimeter lines orthogonal to the first edge and extending from the first edge to the central core-out. A first peripheral core-out may be positioned in the first peripheral region.

A nanoimprint lithography template, a system for using the template and a method of using the template. The template may comprise a body having a front side with a shaping surface. The back side may have a central core-out that is located opposite the shaping surface. A first peripheral region may be bounded by: the central core-out; a first edge of the template; and a first set of two parallel perimeter lines orthogonal to the first edge and extending from the first edge to the central core-out. A first peripheral core-out may be positioned in the first peripheral region.

Negative-working, IR-sensitive printing plates utilize a radiation-sensitive composition having a component polymerizable by a free-radical mechanism, at least part of which comprises or consists essentially of a non-particulate, aliphatic urethane acrylic oligomer that is infinitely water-dilutable but not water-soluble.

Negative-working, IR-sensitive printing plates utilize a radiation-sensitive composition having a component polymerizable by a free-radical mechanism, at least part of which comprises or consists essentially of a non-particulate, aliphatic urethane acrylic oligomer that is infinitely water-dilutable but not water-soluble.

A highlight microdot mask element includes: at least one imaged region having at least one imaged block and being optically transmissive; at least one opaque island formed by at least one non-imaged block, wherein an arrangement of the plurality of imaged regions and the at least one opaque island defines the highlight microdot print surface pattern; and an opaque void region surrounds the highlight microdot pattern. A flexographic plate highlight microdot printhead includes: at least one elevated region, each elevated region having at least one elevated block forming a print surface; at least one internal recess formed by at least one recessed block, wherein an arrangement of the plurality of elevated regions and the at least one recess define a the highlight microdot print surface pattern of a highlight microdot structure; and an recess void region surrounding the highlight microdot structure.

A highlight microdot mask element includes: at least one imaged region having at least one imaged block and being optically transmissive; at least one opaque island formed by at least one non-imaged block, wherein an arrangement of the plurality of imaged regions and the at least one opaque island defines the highlight microdot print surface pattern; and an opaque void region surrounds the highlight microdot pattern. A flexographic plate highlight microdot printhead includes: at least one elevated region, each elevated region having at least one elevated block forming a print surface; at least one internal recess formed by at least one recessed block, wherein an arrangement of the plurality of elevated regions and the at least one recess define a the highlight microdot print surface pattern of a highlight microdot structure; and an recess void region surrounding the highlight microdot structure.

Provided are an on-press development type lithographic printing plate precursor having a support and an image-recording layer on the support in which the image-recording layer contains a coloring compound capable of having a coloring reaction with a decomposition product generated by exposure of the image-recording layer, and an on-press development type lithographic printing plate precursor having a support and an image-recording layer on the support in which the image-recording layer contains a compound represented by Formula 1C or Formula 2C and an electron-donating polymerization initiator. In Formula 1C and Formula 2C, R.sup.1C to R.sup.4C each independently represent a monovalent organic group, L.sup.1C and L.sup.2C each independently represent a divalent organic group, A.sup.C represents OH or NR.sup.5CR.sup.6C, and R.sup.5C and R.sup.6C each independently represent a monovalent organic group

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Provided are an on-press development type lithographic printing plate precursor having a support and an image-recording layer on the support in which the image-recording layer contains a coloring compound capable of having a coloring reaction with a decomposition product generated by exposure of the image-recording layer, and an on-press development type lithographic printing plate precursor having a support and an image-recording layer on the support in which the image-recording layer contains a compound represented by Formula 1C or Formula 2C and an electron-donating polymerization initiator. In Formula 1C and Formula 2C, R.sup.1C to R.sup.4C each independently represent a monovalent organic group, L.sup.1C and L.sup.2C each independently represent a divalent organic group, A.sup.C represents OH or NR.sup.5CR.sup.6C, and R.sup.5C and R.sup.6C each independently represent a monovalent organic group

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