Provided is a lithographic printing plate precursor having an aluminum support, an image-recording layer, and a water-soluble overcoat layer in this order, in which the image-recording layer contains an infrared-absorbing polymethine colorant having HOMO of −5.2 eV or less, a polymerization initiator, a polymerizable compound, and a polymer, and the polymer has a constitutional unit formed of an aromatic vinyl compound and a constitutional unit formed of an acrylonitrile compound. Also provided are a method for preparing a lithographic printing plate using the lithographic printing plate precursor.

The present invention provides a printing plate precursor including a layer which includes a polymer and is provided on a printing surface side of an aluminum support, and a layer which includes particles and is provided on a side opposite to the printing surface side, in which a modulus of elasticity of the particles is 0.1 GPa or more, and in a case where a Bekk smoothness of an outermost layer surface on the side opposite to the printing surface side is denoted by b second, a specific expression (1) is satisfied; a printing plate precursor laminate; a method for making a printing plate; and a printing method.

Lithographic printing plate precursors are prepared with a unique aluminum-containing substrate and one or more radiation-sensitive imageable layers. The aluminum-containing substrate is prepared by three separate and sequential anodizing processes to provide an inner aluminum oxide layer having an average dry thickness (T.sub.i) of 500-1,500 nm and a multiplicity of inner pores having an average inner pore diameter (D.sub.i) larger than 0 and <15 nm. A formed middle aluminum oxide layer has a dry thickness (T.sub.m) of 60-300 nm and a multiplicity of middle pores of average middle pore diameter (D.sub.m) of 15-60 nm, arranged over the inner aluminum oxide layer. A formed outer aluminum oxide layer comprises a multiplicity of outer pores having an average outer pore diameter (D.sub.o) of 5-35 nm and an average dry thickness (T.sub.o) of 30-150 nm, arranged over the middle aluminum oxide layer. D.sub.m is larger than D.sub.o that is larger than D.sub.i.

Lithographic printing plate precursors are prepared with a unique aluminum-containing substrate and one or more radiation-sensitive imageable layers. The aluminum-containing substrate is prepared by three separate and sequential anodizing processes to provide an inner aluminum oxide layer having an average dry thickness (T.sub.i) of 500-1,500 nm and a multiplicity of inner pores having an average inner pore diameter (D.sub.i) larger than 0 and <15 nm. A formed middle aluminum oxide layer has a dry thickness (T.sub.m) of 60-300 nm and a multiplicity of middle pores of average middle pore diameter (D.sub.m) of 15-60 nm, arranged over the inner aluminum oxide layer. A formed outer aluminum oxide layer comprises a multiplicity of outer pores having an average outer pore diameter (D.sub.o) of 5-35 nm and an average dry thickness (T.sub.o) of 30-150 nm, arranged over the middle aluminum oxide layer. D.sub.m is larger than D.sub.o that is larger than D.sub.i.

Lithographic printing plate precursors are prepared with a unique substrate using two separate anodizing processes to provide an inner aluminum oxide layer of average dry thickness (T.sub.i) of 650-3,000 nm and a multiplicity of inner micropores of average inner micropore diameter (D.sub.i) of 15 nm. An outer aluminum oxide layer comprises a multiplicity of outer micropores of average outer micropore diameter (D.sub.o) of 15-30 nm; dry thickness (T.sub.o) of 130-650 nm; and a micropore density (C.sub.o) of 500-3,000 micropores/m.sup.2. The ratio of D.sub.o to D.sub.i is greater than 1.1:1. A hydrophilic layer disposed on the outer aluminum oxide layer has a copolymer composed of (a) recurring units and (b) recurring units, wherein the (a) recurring units have an amide group, and the (b) recurring units have at least a phosphonic acid, a phosphoric acid, a salt of a phosphonic acid, or a salt of a phosphoric acid group.

Provided are a planographic printing plate precursor and a method of producing a planographic printing plate precursor, in which an image forming region during printing on newspaper page is ensured and edge stains are eliminated. Provided are a planographic printing plate precursor (10b) including an aluminum support (12) which has an anodized film (14), and an image recording layer (16) on the aluminum support (12), in which an end portion of the planographic printing plate precursor (10b) has a sagging shape having a sagging amount (X) of 25 m to 150 m and a sagging width (Y) of 70 m to 300 m, the image recording layer (16) contains an infrared absorbing agent, and a part or an entire side surface of two sides of the aluminum support (12), the two sides having the sagging shape and opposing each other contains an ink repellent agent (44); and a method of producing the planographic printing plate precursor (10b).

Lithographic printing plate precursors are prepared with a unique substrate and one or more radiation-sensitive imageable layers. The substrate is prepared by two separate anodizing processes to provide an inner aluminum oxide layer having an average dry thickness (T.sub.i) of 650-3,000 nm and a multiplicity of inner micropores having an average inner micropore diameter (D.sub.i) of 15 nm. A formed outer aluminum oxide layer comprises a multiplicity of outer micropores having an average outer micropore diameter (D.sub.o) of 15-30 nm; an average dry thickness (T.sub.o) of 130-650 nm; and a micropore density (C.sub.o) of 500-3,000 micropores/m.sup.2. The ratio of D.sub.o to D.sub.i is greater than 1.1:1, and D.sub.o in nanometers and the outer aluminum oxide layer micropore density (C.sub.o) in micropores/m.sup.2, are further defined by the outer aluminum oxide layer porosity (P.sub.o) according to the following equation:
0.3P.sub.o0.8
where P.sub.o is 3.14(C.sub.o)(D.sub.o.sup.2)/4,000,000.

Provided are a lithographic printing plate precursor including a hydrophilized aluminum support, and a water-soluble or water-dispersible negative type image recording layer provided on the aluminum support, in which an arithmetic average height Sa of a surface of an outermost layer on a side where the image recording layer is provided is in a range of 0.3 m to 20 m or in which Expression (1) and Expression (2) are satisfied in a case where a Bekk smoothness of a surface of an outermost layer on a side where the image recording layer is provided is set as a seconds and a Bekk smoothness of a surface of an outermost layer on a side opposite to a side where the image recording layer is provided is set as b seconds; a method of producing the same; a lithographic printing plate precursor laminate formed of the lithographic printing plate precursor; a plate-making method for a lithographic printing plate; and a lithographic printing method.

a1000, b1000(1)

1/a+1/b0.002(2)

The present invention provides a printing plate precursor, a method of producing a printing plate, and a printing method with excellent stain resistance and deinking capability after being left to stand at the time of obtaining a printing plate. The printing plate precursor of the present invention is a printing plate precursor including an aluminum support, and a functional layer which is disposed on the aluminum support, in which the aluminum support includes an aluminum plate and an aluminum anodized film disposed on the aluminum plate, the anodized film is positioned closer to the functional layer than the aluminum plate is, the anodized film has micropores extending in a depth direction from a surface of the functional layer side, and an average diameter of the micropores in the surface of the anodized film is in a range of 13 nm to 100 nm, the printing plate precursor contains a hydrophilizing agent in a region on a plate surface of the functional layer side which extends to a distance of 5 mm inward from two facing end portions of the printing plate precursor, and a content of the hydrophilizing agent per unit area in the region is greater than a content of the hydrophilizing agent per unit area in a region other than the region by 10 mg/m.sup.2 or greater.

A lithographic printing plate precursor including a hydrophilized aluminum support, and a water-soluble or water-dispersible negative type image recording layer provided on the aluminum support, in which an arithmetic average height Sa of a surface of an outermost layer on a side where the image recording layer is provided is in a range of 0.3 m to 20 m; a method of producing a lithographic printing plate precursor; a lithographic printing plate precursor laminate formed of the lithographic printing plate precursor; a plate-making method for a lithographic printing plate; and a lithographic printing method.