Photovoltaic cells including a first group-IV subcell including an n-type emitter layer comprising a first group-IV material selected from a first group consisting of Ge, SiGe and SiGeSn, and a second layer comprising a second group-IV material, the second group-IV material being different from the first group-IV material, and the n-type emitter layer being the primary photoabsorber of the first group-IV subcell. A p-n junction of the first group-IV subcell is formed at a heterojunction of the n-type emitter layer and second layer. The photovoltaic cell also includes a tunnel junction, and a second group-IV subcell, the tunnel junction interconnecting the first group IV subcell to the second group-IV subcell, the first group IV subcell and the second group IV subcell being a lowest two subcells of the photovoltaic cell, the first group IV subcell being between the second group-IV subcell and a plurality of HI-V subcells.