Microbiological cleaning formulations may include an aqueous solution of a microbial component comprising at least one sporogenous microbial species. The microbiological cleaning formulation may also include a nonionic surfactant. The microbiological cleaning formulations may further include additives, solvents, preservatives, stabilizers, and fragrance agents. The microbiological formulations are such that they may removes organic carcinogens from a surface of a material contaminated during firefighting-related activities or from exposure to organic carcinogens. Corresponding methods for removing organic carcinogens from a surface of a firefighting material may include applying the microbiological cleaning formulation on the surface of the firefighting material. Corresponding cleaning kits may include the microbiological cleaning formulation and an optional scrubbing element.

An ozone cleaning system includes a first chamber, a second chamber coupled to the first chamber, and a utility assembly disposed within the second chamber. The utility assembly includes an ozone generator configured to provide ozone to the first chamber, a humidifying unit configured to provide water vapor to the first chamber, and a blower configured to at least one of (i) reduce air pressure within the first chamber or (ii) draw the ozone from the first chamber following a decontamination process.

An ozone cleaning system includes a decontamination chamber, a utility chamber coupled to the decontamination chamber, and a utility assembly disposed within the utility chamber. The utility assembly is configured to decontaminate at least one of contaminated gear and contaminated equipment positioned in the decontamination chamber by treating organic carcinogens. The utility assembly includes an ozone generator configured to provide ozone to the decontamination chamber, a humidifying unit configured to provide humidity to the decontamination chamber, and a vacuum blower configured to at least one of (i) generate a vacuum within the decontamination chamber and (ii) pull the ozone from the decontamination chamber following a decontamination process.

Decontamination compositions are described. The decontamination composition comprises an aqueous solution of a water soluble cerium salt or a dispersion of cerium oxide in water. The decontamination composition may optionally include at least one of an oxidizer, a surfactant, a co-solvent, a chelating agent, and a polymer. Methods of decontaminating clothing are also described.

A polymer-based material includes a polymeric binder and one or more porous active materials that adsorb, chemisorb, decompose, or a combination thereof, a hazardous chemical. The polymeric binder and the one or more porous active materials are combined to form a composite bead. The polymeric binder may include a polyurethane or a styrene-based block copolymer. The porous active materials may comprise metal-organic frameworks, metal oxides, metal hydroxides, and metal hydrates. The one or more porous active materials may be between 1 and 99 wt % of a total composite mass of the composite bead. Alternatively, the one or more porous active materials may be between 80 and 95 wt % of a total composite mass of the composite bead. The hazardous chemical may include a chemical warfare agent, a simulant of chemical warfare agents, and toxic industrial chemicals.

According to one embodiment, a treatment method may include making a byproduct come into contact with a treatment solution, wherein the byproduct is a solid or liquid byproduct formed by polymerizing components contained in an exhaust gas discharged by synthesizing a silicon-containing material using a gas which includes silicon and halogen. The treatment solution may include at least one of an inorganic base or an organic base, and is basic.

A method for treatment of ash from incineration plants includes: collecting ash from an incinerator; feeding the collected ash and additional feed material to a gasification/vitrification reactor; vitrifying the ash and additional feed material in the gasification/vitrification reactor, to form a slag of molten material; allowing the slag to flow from the gasification/vitrification reactor and solidify outside the gasification/vitrification reactor; gasifying volatile components in the ash and the additional feed material; combusting syngas generated in the gasification/vitrification reactor in a secondary combustion zone in the gasification/vitrification reactor; and supplying products of the syngas combustion to the incinerator to augment the thermal environments of the incinerator. An apparatus used to practice the method is also provided.

A treatment method for coal fly ash, and in particular sodic fly ash, comprises 1) contacting the coal fly ash with anhydrite, and 2) contacting the coal fly ash in the presence of water with at least one additive. The material obtained from the contacting steps (1) and (2) may be dried. The steps (1) and (2) may be carried simultaneously or sequentially. The additive may comprise at least one component selected from the group consisting of strontium-containing compounds, barium-containing compounds, dolomite, a dolomite derivative such as calcined or hydrated dolomite, water-soluble sources of silicate such as sodium or potassium silicate, iron-containing compounds, and any combinations thereof. A particularly preferred additive comprises sodium silicate. The method may be effective in reducing the sodium content in the fly ash (Na.sub.2O), reducing the alkalinity of the fly ash, and/or stabilizing at least one heavy metal such as selenium and/or arsenic to reduce their leachability.

One method of treating incinerated waste comprises: size separating at least some of the incinerated waste into a first undersize fraction comprising particles smaller than the first separation size and into a first oversize fraction comprising particles larger than the first separation size; size reducing at least some of the first oversize fraction; size separating at least some of the size-reduced first oversize fraction into a second undersize fraction comprising particles smaller than the second separation size and into a second oversize fraction comprising particles larger than the second separation size; combining at least some of the first undersize fraction and at least some of the second undersize fraction into a fine fraction; and extracting metal from at least some of the fine fraction. Another method of treating incinerated waste comprises extracting metal by froth flotation from at least some of the incinerated waste. Systems are also disclosed.

A treatment method for stabilizing at least a portion of at least one heavy metal contained in a sodic fly ash to reduce leachability, wherein the sodic fly ash is provided by a process whereby a sodium-based sorbent is injected in a combustion flue gas to remove pollutants therefrom. The treatment method comprises contacting the sodic fly ash with at least one water-soluble source of silicate and at least one additive comprising calcium and/or magnesium. The material obtained from the contacting step is preferably dried. The additive may be selected from the group consisting of lime kiln dust, fine limestone, quicklime, hydrated lime, dolomitic lime, dolomite, selectively calcined dolomite, hydrated dolomite, magnesium hydroxide, magnesium carbonate, magnesium oxide, and any mixture thereof. A particularly preferred additive comprises lime kiln dust and/or dolomitic lime. The heavy metal to be stabilized in the sodic fly ash may comprise selenium and/or arsenic.