An object of the present invention is to provide a composition for forming an undercoat layer capable of forming an undercoat layer that does not easily peel off from the substrate, an undercoat layer formed by the composition, as well as an exhaust gas purification catalyst and an exhaust gas purification apparatus each including the undercoat layer, and, to achieve the object, the present invention provides a composition for forming an undercoat layer, the composition containing tin oxide microparticles and tin oxide nanoparticles, wherein a content of the tin oxide nanoparticles is 8% by mass or more and 30% by mass or less, with respect to a total content of the tin oxide microparticles and the tin oxide nanoparticles, an undercoat layer formed by the composition, as well as an exhaust gas purification catalyst and an exhaust gas purification apparatus each including the undercoat layer.

The present disclosure provides an improved shaped catalyst containing catalytic material comprised of mixed oxides of vanadium and phosphorus and using such shaped catalysts for the production of maleic anhydride.

Water purification particles have porous particles and photocatalyst particles formed of titanium-based compound particles that are supported on the porous particles, have absorption at a wavelength of 500 nm in a visible absorption spectrum, and have an absorption peak at 2,700 cm.sup.−1 to 3,000 cm.sup.−1 in an infrared absorption spectrum, and a metal compound having a metal atom and a hydrocarbon group is bonded to the surface of each of the titanium-based compound particles through an oxygen atom.

Disclosed herein is a method of treating an aqueous solution containing impurities including a perfluoroalkyl substance and/or a polyfluoroalkyl substance, comprising introducing the aqueous solution into a batch or semi-batch photocatalytic reactor with a microparticulate catalyst configured to reduce chain length of the perfluoroalkyl substance and/or polyfluoroalkyl substance, forming a treated aqueous stream, the reactor including a catalyst flow controller configured to automatically increase the catalyst concentration in the reactor while agitating the catalyst-containing solution during reaction, and removing catalyst particles from the treated aqueous stream to form a purified aqueous stream. In some cases, the feed to the reactor is atomized. Corresponding systems also are disclosed.

The present invention relates to a process for preparing a cobalt-containing Fischer-Tropsch synthesis catalyst with good physical properties and high cobalt loading. In one aspect, the present invention provides a process for preparing a supported cobalt-containing Fischer-Tropsch synthesis catalyst, said process comprising the following steps of: (a) impregnating a support powder or granulate with a cobalt-containing compound; (b) calcining the impregnated support powder or granulate and extruding to form an extrudate; or extruding the impregnated support powder or granulate to form an extrudate and calcining the extrudate; and (c) impregnating the calcined product with a cobalt-containing compound; or forming a powder or granulate of the calcined product, impregnating with a cobalt-containing compound and extruding to form an extrudate.

Metal oxide nanoarrays, such as titanium oxide nanoarrays, having a platinum group metal dispersed thereon and methods of making such nanoarrays are described. The platinum group metal can be dispersed on the metal oxide nanoarray as single atoms. The nanoarrays can be used to catalyze oxidation of combustion exhaust.

A selective catalytic reduction catalyst for the treatment of an exhaust gas stream of a passive ignition engine, the catalyst comprising a porous wall-flow filter substrate comprising an inlet end, an outlet end, a substrate axial length (w) extending between the inlet end and the outlet end, and a plurality of passages defined by porous internal walls of the porous wall flow filter substrate; wherein the catalyst further comprises a first coating, said first coating extending over x % of the substrate axial length from the inlet end toward the outlet end of the substrate, x being in the range of from 10 to 100, wherein the first coating comprises copper and an 8-membered ring pore zeolitic material; wherein the catalyst further comprises a second coating, the second coating extending over y % of the substrate axial length from the outlet end toward the inlet end of the substrate, y being in the range of from 20 to 90, wherein the second coating comprises copper, and optionally an 8-membered ring pore zeolitic material; wherein the catalyst optionally further comprises a third coating; wherein x+y is at least 90; wherein y % of w from the outlet end toward the inlet end of the substrate define the outlet zone of the coated substrate and (100−y) % of w from the inlet end toward the outlet end of the substrate define the inlet zone of the coated substrate; wherein the ratio of the loading of copper in the inlet zone, Cu(in), calculated as CuO, relative to the loading of copper in the outlet zone, Cu(out), calculated as CuO, Cu(in):Cu(out), is less than 1:1.

Disclosed are a catalyst for carbonylation of dimethyl ether that has high catalyst activity and can be regenerated using a fluidized bed reactor, and a method for preparing the same. The catalyst for carbonylation of dimethyl ether includes a support having a first density; and ferrierite zeolite catalyst particles bound to a surface of the support via a polymer binder and having a second density smaller than the first density.

A catalyst for non-oxidative dehydrogenation of alkanes and a method for making and using the same is disclosed. The catalyst can include vanadium oxide derived from vanadyl oxalate. More particularly the catalyst is prepared by a method comprising the steps of: (a) contacting a transition alumina support with an aqueous solution comprising a vanadium carboxylate material solubilized therein; (b) heating the contacted alumina support to remove the water and produce a catalyst precursor material in solid form; and (c) heating the solid catalyst precursor material in the presence of an oxidizing source at a temperature of 500 to 800° C. to produce an alumina supported catalytic material comprising vanadium oxide. The catalyst can be further modified with an alkali metal oxide like potassium oxide, the precursor thereof being introduced with the impregnation solution.

A process for preparing a powder support containing alumina and silica or their derivatives for a catalyst of a Fischer-Tropsch type reaction, including stage (a) of preparing a first reactant containing an alumina compound or precursor including a reaction for peptization of an alumina compound or precursor in the presence of an acid, to form solid particles in suspension, stage (b) of preparing a second reactant based on silicic acid and/or on a compound or precursor of silicic acid, including a controlled aging treatment of the silicic acid targeted at its polymerization up to a degree of conversion of the silicic acid of at most 70%, stage (c) of mixing the two reactants in a mixer, and the pH of the first reactant is adjusted to a value not exceeding a given maximum pH threshold.