An efficient photocatalyst nanocomposite comprising reduced graphene oxide, noble metal, and a metal oxide prepared by a one-step method that utilizes date seed extract as a reducing and nanoparticle determining size agent. The photocatalyst of the invention is a more effective sunlight photocatalyst than that prepared by traditional method in the photo decomposition of organic compounds in contaminated water.

The present invention concerns a multifunctional catalyst for the conversion of CO.sub.2 into useful products, such as CO via the reverse water gas shift reaction. The catalyst according to the invention efficiently combined a water sorption functionality with at least one catalytic functionality into a single particle, by having a solid water sorbent impregnated with at least one metal capable of converting CO.sub.2 from a gaseous mixture comprising H.sub.2 and CO.sub.2. The catalyst according to the invention allows for higher selectivity in the conversion of CO.sub.2, at more lenient conditions in terms of temperature and pressure, and improved stability of the catalyst itself. The invention also concerns a process for converting CO.sub.2, utilizing the catalyst and the use of the catalyst in the conversion of CO.sub.2.

The present invention relates to a mixed oxide of aluminium, of zirconium, of cerium, of lanthanum and optionally of at least one rare-earth metal other than cerium and lanthanum that makes it possible to repair a catalyst that retains, after severe ageing, a good thermal stability and a good catalytic activity. The invention also relates to the process for preparing this mixed oxide and also to a process for treating exhaust gases from internal combustion engines using a catalyst prepared from this mixed oxide.

A process for preparing C2 to C3 hydrocarbons may include introducing a feed stream including hydrogen gas and a carbon-containing gas comprising carbon monoxide, carbon dioxide, and mixtures thereof into a reaction zone of a reactor, and converting the feed stream into a product stream comprising C2 to C3 hydrocarbons in the reaction zone in the presence of a hybrid catalyst. The hybrid catalyst may include a metal oxide catalyst component and a microporous catalyst component comprising 8-MR pore openings less than or equal to 5.1 A and a cage defining ring size less than or equal to 7.45 A, where a C2/C3 carbon molar ratio of the product stream is greater than or equal to 0.7.

The invention relates to a method for producing a metal-foam body, comprising the steps of (a) providing a metal-foam body A, which consists of nickel, cobalt, copper, or alloys or combinations thereof, (b) applying an aluminum-containing material MP to metal-foam body A so as to obtain metal-foam body AX, (c) thermally treating of metal-foam body AX, with the exclusion of oxygen, to achieve the formation of an alloy between the metallic components of metal-foam body A and the aluminum-containing material MP so as to obtain metal-foam body B, wherein the duration of the thermal treatment is chosen in dependence on the temperature of the thermal treatment and the temperature of the thermal treatment is chosen in dependence on the thickness of the metal-foam body AX. The invention also relates to the metal-foam bodies obtainable by the methods according to the invention and to the use thereof as catalysts for chemical transformations.

The invention relates to a method for producing a metal-foam body, comprising the steps of (a) providing a metal-foam body A, which consists of nickel, cobalt, copper, or alloys or combinations thereof, (b) applying an aluminum-containing material MP to metal-foam body A so as to obtain metal-foam body AX, (c) thermally treating of metal-foam body AX, with the exclusion of oxygen, to achieve the formation of an alloy between the metallic components of metal-foam body A and the aluminum-containing material MP so as to obtain metal-foam body B, wherein the duration of the thermal treatment is chosen in dependence on the temperature of the thermal treatment and the temperature of the thermal treatment is chosen in dependence on the thickness of the metal-foam body AX. The invention also relates to the metal-foam bodies obtainable by the methods according to the invention and to the use thereof as catalysts for chemical transformations.

The invention provides for a method to prepare an alumina catalyst support comprising bismuth for emission control applications, to an alumina catalyst support prepared according to the method of the invention and to an alumina catalyst support comprising bismuth and having a specific crystallinity value that leads to improved technical effects.

The present invention provides a catalyst, comprising molybdenum; one or more first elements selected from a Group V, VI, VII, VIII, IX, X, and XI metal (e.g., silver, cobalt, nickel, copper, rhodium, ruthenium, iridium, palladium, niobium, and manganese); one or more second elements selected from sulfur, carbon, oxygen, phosphorus, nitrogen, and selenium; and optionally, one or more Group IA metals, wherein the molybdenum is present in an amount of 10-50 wt. % of the total amount of the one or more first elements, the molybdenum, the one or more second elements, and the Group IA metal, and methods of using said catalyst in the production of ethanol from carbon dioxide.

The present invention provides a catalyst, comprising molybdenum; one or more first elements selected from a Group V, VI, VII, VIII, IX, X, and XI metal (e.g., silver, cobalt, nickel, copper, rhodium, ruthenium, iridium, palladium, niobium, and manganese); one or more second elements selected from sulfur, carbon, oxygen, phosphorus, nitrogen, and selenium; and optionally, one or more Group IA metals, wherein the molybdenum is present in an amount of 10-50 wt. % of the total amount of the one or more first elements, the molybdenum, the one or more second elements, and the Group IA metal, and methods of using said catalyst in the production of ethanol from carbon dioxide.

A silica-alumina based composite material for making hydroprocessing catalysts, is disclosed. The silica-alumina composite material generally comprises at least two silica-aluminas, the first being a modified first silica-alumina, and the second being a second silica-alumina that is unmodified or modified. The first silica-alumina is modified to comprise silica and alumina domains and a silica-alumina interphase. The second silica-alumina may also be modified at the same time or separately to comprise silica and alumina domains and a silica-alumina interphase. The first silica-alumina and the second silica-alumina differ in one or more physical and/or chemical characteristics, e.g., the ratio of silica to alumina, surface area, pore size, pore volume, silica domain size, or alumina domain size. The invention can be used for making catalyst base materials and catalysts useful for upgrading hydrocarbon feedstocks to produce fuels, lubricants, chemicals and other hydrocarbonaceous compositions.