An electrochemical reactor includes a plurality of plate-shaped members and a plurality of passages defined by the plurality of plate-shaped members. Each plate-shaped member includes a cell including an ion conducting solid electrolyte layer, an anode layer arranged on a surface of the solid electrolyte layer, and a cathode layer arranged on a surface of the solid electrolyte layer at an opposite side to the surface at which the anode layer is arranged. The plate-shaped members are configured so that, for all of the passages, both of an anode layer of at least one plate-shaped member among the plurality of plate-shaped members defining the passages and a cathode layer of at least one other plate-shaped member among the plurality of plate-shaped members defining the passages face the passages.

A carbon dioxide electrolytic device of an embodiment includes: an anode part including an anode which oxidizes water or hydroxide ions to produce oxygen; a cathode part including a cathode which reduces carbon dioxide to produce a carbon compound, a cathode solution flow path which supplies a cathode solution to the cathode, and a gas flow path which supplies carbon dioxide to the cathode; a separator which separates the anode part and the cathode part; and a differential pressure control unit which controls a differential pressure between a pressure of the cathode solution and a pressure of the carbon dioxide so as to adjust a production amount of the carbon dioxide produced by a reduction reaction in the cathode part.

Disclosed herein are doped perovskite oxides. The doped perovskite oxides may be used as a cathode material in an electrochemical cell to electrochemically generate ammonia from N.sub.2. The doped perovskite oxides may be combined with nitride compounds, for instance iron nitride, to further increase the efficiency of the ammonia production.

The present invention provides solid oxide cells such as fuel cells, electrolyzers, and sensors comprising an electrolyte having an interface between an yttria-stabilized zirconia material and a glass material, in some embodiments. Other embodiments add an interface between a platinum oxide material and the yttria-stabilized zirconia material in the electrolyte. Further embodiments of solid oxide cells have an ion-conducting species such as an ionic liquid or inorganic salt in contact with at least one electrode of the cell. Certain embodiments provide room temperature operation of solid oxide cells.

To provide a method whereby it is possible to efficiently produce an ion exchange membrane for alkali chloride electrolysis, which has high current efficiency and high alkali resistance at the time of electrolyzing an alkali chloride. This is a method for producing an ion exchange membrane 1 for alkali chloride electrolysis, having a layer (C) 12 containing a fluorinated polymer (A) having carboxylic acid type functional groups, by immersing an ion exchange membrane precursor film having a precursor layer (C) containing a fluorinated polymer (A) having groups convertible to carboxylic acid type functional groups, in an aqueous alkaline solution comprising an alkali metal hydroxide, a water-soluble organic solvent and water, and subjecting the groups convertible to carboxylic acid type functional groups to hydrolysis treatment to convert them to carboxylic acid type functional groups, wherein the concentration of the water-soluble organic solvent is from 1 to 60 mass % in the alkaline aqueous solution (100 mass %); the proportion of structural units having carboxylic acid type functional groups in the fluorinated polymer (A) is from 14.00 to 14.50 mol %; and the resistivity in the layer (C) 12 is from 3.010.sup.3 to 25.010.sup.3 .Math.cm.

Various embodiments include a method for producing a gas diffusion electrode comprising a metal M selected from Ag, Au, Cu and mixtures and/or alloys, the method comprising: providing a copper-, silver- and/or gold-containing starting material comprising at least one alkaline earth metal-copper, alkaline earth metal-silver and/or alkaline earth metal-gold phase, where the alkaline earth metal is selected from the group consisting of: Mg, Ca, Sr, and Ba; introducing the starting material into a solution having a pH of less than 5 and reacting to give a catalyst material; removing and washing the catalyst material; and processing the catalyst material to form a gas diffusion electrode.

An electrochemical device and method can include techniques involving bipolar membrane electrolysis to transform an input product into an output product. Some embodiments can include a gas-diffusion electrode as a cathode, a bipolar membrane configured to facilitate autodissociation, and an anode that can be configured as a liquid-electrolyte style electrode or a gas-diffusion electrode. In some embodiments the electrochemical device can be configured as a CO.sub.2 electrolyzer that is designed to utilize input product including carbon dioxide gas and water to generate output products that can include gaseous carbon monoxide or other reduction products of carbon dioxide and gaseous oxygen or the oxidation products of a depolarizer such as hydrogen, methane, or methanol. Embodiments can be utilized in the production of fuels or feedstocks for fuels and carbon-containing chemicals, in air purification systems, flue gas treatment devices, and other machines and facilities.

An electrochemical cell for wastewater treatment is disclosed comprising a catalyst coated membrane, an open pore mesh placed next to the catalyst coated membrane, on each side of the membrane, and a compression frame placed next to each of the open pore meshes. The open pore meshes and the compression frames are made of a conductive material. Each compression frame has compression arms spread within the area delimited by the perimeter of the frame to apply a uniform compression force across the anode and cathode active areas through fasteners which protrude through the compression arms, the open pore meshes and the catalyst coated membrane. A stack comprising at least one such electrochemical cell is immersed in a reactor tank containing the wastewater to be treated.

A combination of an electrochemical device for delivering reducing equivalents to a cell, and engineered metabolic pathways within the cell capable of utilizing the electrochemically provided reducing equivalents is disclosed. Such a combination allows the production of commodity chemicals by fermentation to proceed with increased carbon efficiency.

A fuel oxidation system including an inlet in fluid communication with an interior of a sealed container, and the sealed container is holding permeated gas released from a pressure vessel within the sealed container. Another inlet is in fluid communication with an environment surrounding the sealed container, and the environment includes oxygen gas (O.sub.2). An oxidation module is in fluid communication with the inlet and the other inlet, and the oxidation module is combining the permeated gas received by the inlet with the oxygen gas (O.sub.2) received by the other inlet to form a preferred substance.