A method reducing carbon dioxide to one or more organic products may include steps (A) to (E). Step (A) may introduce an anolyte to a first compartment of an electrochemical cell. The first compartment may include an anode. Step (B) may introduce a catholyte and carbon dioxide to a second compartment of the electrochemical cell. Step (C) may oxidize an indium cathode to produce an oxidized indium cathode. Step (D) may introduce the oxidized indium cathode to the second compartment. Step (E) may apply an electrical potential between the anode and the oxidized indium cathode sufficient for the oxidized indium cathode to reduce the carbon dioxide to a reduced product.

Embodiments relate to systems and methods for gas delivery for personal medical consumption having safety features. A hydrogen or oxygen gas delivery system herein can include electrolytic cores performing electrolysis-based reactions, and obtain free hydrogen (H2) gas for collection and delivery to a user. In aspects, the electrolytic core(s) can be scaled to produce a sufficient amount of hydrogen (H2) or oxygen (O2) gas so that the user can ingest that gas directly, without a need for storage. The system can be portable, and configured with a delivery tube for transmitting hydrogen or oxygen gas to a user. While safety risks are generally minimal, the system can be configured with sensors to detect fault conditions or hazards such as combustion or overpressure, which can only be caused by deliberate user action to expose gaseous products to flame or spark, and even then would not be likely to trigger violent combustion.

To provide a production method whereby an ion exchange membrane for alkali chloride electrolysis can be obtained which has high current efficiency, little variation in current efficiency and high alkaline resistance. This is a method for producing an ion exchange membrane 1 having a layer (C) 12 containing a fluorinated polymer (A) having carboxylic acid type functional groups, by immersing an ion exchange membrane precursor film having a precursor layer (C) containing a fluorinated polymer (A) having groups convertible to carboxylic acid type functional groups, in an aqueous alkaline solution comprising an alkali metal hydroxide, a water-soluble organic solvent and water, and converting the groups convertible to carboxylic acid type functional groups to carboxylic acid functional groups, wherein the concentration of the water-soluble organic solvent is from 1 to 60 mass % in the aqueous alkaline solution (100 mass %); the temperature of the aqueous alkaline solution is at least 40 C. and less than 80 C.; and the proportion of structural units having carboxylic acid type functional groups in the fluorinated polymer (A) is from 13.0 to 14.50 mol % in all structural units (100 mol %) in the fluorinated polymer (A).

Various embodiments herein relate to methods and apparatus for electroplating material onto a semiconductor substrate. The apparatus includes an ionically resistive element that separates the plating chamber into a cross flow manifold (above the ionically resistive element) and an ionically resistive element manifold (below the ionically resistive element). Electrolyte is delivered to the cross flow manifold, where it shears over the surface of the substrate, and to the ionically resistive element manifold, where it passes through through-holes in the ionically resistive element to impinge upon the substrate as it enters the cross flow manifold. In certain embodiments, the flow of electrolyte into the cross flow manifold (e.g., through a side inlet) and the flow of electrolyte into the ionically resistive element manifold are actively controlled, e.g., using a three-way valve. In these or other cases, the ionically resistive element may include electrolyte jets.

Disclosed herein is a method for selectively reducing, using electrical energy, CO.sub.2 to carbon monoxide or formic acid, a catalyst for use in the method, and an electrochemical reduction system. The method for producing carbon monoxide or formic acid by electrochemically reducing carbon dioxide of the present invention includes (a) reacting carbon dioxide with a metal complex represented by formula (1), and (b) applying a voltage to a reaction product of the carbon dioxide and the metal complex represented by formula (1):

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An arrangement for the electrolysis of carbon dioxide, includes: an electrolytic cell having an anode and a cathode, wherein the anode and cathode are connected to a voltage supply, wherein the cathode is configured as a gas diffusion electrode to which a gas compartment is attached on a first side and a cathode compartment is attached on a second side; an electrolyte circuit connecting to the electrolytic cell; and a gas supply for supplying carbon dioxide-containing gas into the gas compartment, wherein one or more channels are arranged in the gas compartment, wherein the channels are at least partially in contact with the gas diffusion electrode and are configured for transporting electrolyte fluid passing through the gas diffusion electrode to a lateral region of the gas compartment.

Electrochemically reacting C-1 compounds including carbon dioxide, formic acid, formaldehyde, methanol, carbon monoxide in the presence of at least one lanthanide and/or at least one actinide. Reducing carbon dioxide or reacting C-1 compounds such as HCOOH (formic acid), HCHO (formaldehyde), CH.sub.3OH (methanol), or CO (carbon monoxide) with use of an electrochemical device, wherein the device comprises at least one cathode, and at least one anode, and at least one electrolyte between the cathode and the anode, wherein the electrolyte comprises at least one lanthanide and/or actinide compound. The electrode can be modified with a film such as an ionically conducting or ionically permeable film, optionally comprising a magnetic material. Polar organic solvent such as acetonitrile can be used. Electrocatalysis and/or reaction mediation is observed. Devices can be adapted to carry out the methods. The device can be part of a fuel cell, a battery, an electrolyzer, or an electrosynthetic device.

A hydrogen molecule remixing device includes a base, a first gas and water channelling disc, an anode, a cathode, an ion membrane, a second gas and water channelling disc, a cover, a cationic water outlet connector and a connector. In practice, the source water is electrolyzed in the anode cavities of the anode to form oxygen molecules, ozone and anionic water, and electrolyzed in the cathode cavities of the cathode to form hydrogen molecules and cationic water. The hydrogen molecules are carried by the cationic water into the collecting and guiding chambers of the second gas and water channelling disc, so that the hydrogen molecules and the cationic water produce a blending reaction, and more hydrogen molecules are dissolved into the cationic water.

Compositions comprising hydrogenated and dehydrogenated graphite comprising a plurality of flakes. At least one flake in ten has a size in excess of ten square micrometers. For example, the flakes can have an average thickness of 10 atomic layers or less.

According to one embodiment, an electrolytic cell includes: a housing for retaining an electrolytic solution; a diaphragm that partitions an interior of the housing into an anode-side cell and a cathode-side cell; an anode electrode that is provided in the anode-side cell and has most of a surface in contact with an anode-side gas phase; and a cathode electrode that is provided in the cathode-side cell and has most of a surface in contact with a cathode-side gas phase. According to the other embodiment, a hydrogen production apparatus according to the present embodiment includes: an electrolytic solution tank that retains an electrolytic solution; and a pump that supplies the electrolytic solution between the anode electrode and the cathode electrode from the electrolytic solution tank.