According to one embodiment, an electrolytic cell includes: a housing for retaining an electrolytic solution; a diaphragm that partitions an interior of the housing into an anode-side cell and a cathode-side cell; an anode electrode that is provided in the anode-side cell and has most of a surface in contact with an anode-side gas phase; and a cathode electrode that is provided in the cathode-side cell and has most of a surface in contact with a cathode-side gas phase. According to the other embodiment, a hydrogen production apparatus according to the present embodiment includes: an electrolytic solution tank that retains an electrolytic solution; and a pump that supplies the electrolytic solution between the anode electrode and the cathode electrode from the electrolytic solution tank.

The present process invention in continuation to the U.S. Ser. No. 14/392,066 appertains to Advanced Combustion in post-combustion carbon capture, wherein the CO.sub.2-containing flue gas, said CO2-Stream, is cleaned from harmful constituents, recirculated, oxygenized and employed for combustion for the fossil fuels, referred to Flue Gas Oxy-Fueling in order to obtain a CO.sub.2-rich gas upstream to CO2-CC with significantly less gas flow rate subject to further processing. This continuation process patent also presents processing to prepare a CO.sub.2-rich CO2-Stream for the pre-combustion carbon capture downstream of gasification and gas cleaning process; or from the secondary CO2-Stream that stems from the cathodic syngas [CO/2H.sub.2] downstream of HPLTE-SG of patent parent, then downstream of the HP/IP-water shift converters in [CO.sub.2/3H.sub.2] composition, whereas the CO.sub.2-rich CO2-Stream from either pre-combustion process is routed to the CO2-CC for CO.sub.2 cooling and condensation section of the U.S. Ser. No. 14/392,066 to obtain liquid carbon dioxide for re-use as new fossil energy resource.

The present invention relates to an oxygen generator integrated with an ozone removal filter such that an ozone removal filter is provided in an oxygen discharge opening communicating with an oxygen discharge hole of a water electrolytic cell constituting an apparatus for producing oxygen by using mineral water among generally used water, for filtering ozone generated with oxygen during electrolysis of water and ozone compounds, in which ozone is combined with various organic and inorganic materials contained in mineral water, such as calcium (Ca), magnesium (Mg) and silicon (Si), and thus the oxygen generator allows only high purity oxygen to pass through and to be discharged through the oxygen discharge hole.

An interconnector-electrochemical reaction unit cell composite body including an electrochemical reaction unit cell, and an interconnector which has a first through hole defining a fuel gas flow channel and which is disposed on the side toward an anode of the electrochemical reaction unit cell. The interconnector includes a coating forming a first surface of the interconnector opposite the anode. The coating includes a first coating and a second coating a having reduction resistance higher than that of the first coating. The first coating forms a first surface region which is a portion of the first surface of the interconnector and which is located away from the first through hole. The second coating forms a second surface region which is a portion of the first surface of the interconnector, which surrounds the first through hole, and which is located between the first coating and the first through hole.

An electrolytic cell includes a housing, a first diaphragm, a first electrode, a second electrode, and a first discharge port. The housing held an electrolyte solution. The first diaphragm partitions the interior of the housing into a first cell and a second cell. The first electrode is provided inside the first cell. The first electrode includes a first surface facing the first diaphragm, a second surface different from the first surface, and a first hole. The second electrode is provided inside the second cell adjacent to the first diaphragm. The second electrode includes a third surface adjacent to the first diaphragm, a fourth surface different from the third surface, and a second hole. The first discharge port discharges the electrolyte solution from the second cell. The first cell is configured to supply the electrolyte solution supplied therein to the third surface side of the second cell.

Provided are electrochemical cells for hydrogen production and methods for hydrogen production. The electrochemical cell and methods use a mediator that may have a reversible redox potential lying outside the onset of the oxygen evolution reaction (OER) and the hydrogen evolution reaction (HER). Also, provided are systems for generating hydrogen and water from oxygen and generating water from oxygen and hydrogen.

Various embodiments may include a method of electrochemical production of synthesis gas comprising: reducing carbon dioxide to a first product gas including carbon monoxide in a carbon dioxide electrolysis cell; splitting water to generate a second product gas including hydrogen in a water electrolysis cell; delivering at least one catholyte from the group consisting of: a first catholyte from the carbon dioxide electrolysis cell and a second catholyte from the water electrolysis cell, into a gas scrubbing apparatus; and removing non-reduced carbon dioxide from the first product gas in the gas scrubbing apparatus using the at least one catholyte as an absorbent.

Certain configurations of a gas chromatography system comprising an internal gas generator are described. In some instances, the gas chromatography system may comprise an internal hydrogen generator to provide hydrogen gas to a chromatography column for separation of analyte species. In certain examples, the gas chromatography system can be operated without any external gas inputs.

An electrolyser arrangement with at least one electrolytic cell, having two electrodes, namely an anode and a cathode, each of the two electrodes being in contact with an electrode compartment for filling with a liquid electrolyte, the two electrode compartments being separated by a membrane and a conveying device being provided, one for each of the two electrodes, for conveying the electrolyte in each case in a circuit, a cathode circuit and an anode circuit, through the electrode compartment via at least one collection vessel per circuit and back into the electrode chamber. A device is provided outside the electrolytic cell, for conveying an auxiliary volume flow between the cathode circuit and the anode circuit.

A device includes a first electrode, a second electrode, and an electrolyte between the electrodes. The first electrode and the second electrode may comprise a metallic phase that does not contain a platinum group metal when the device is in use, and where the electrolyte is solid state and is oxide ion conducting.