Metal-containing methacrylates incorporated into polymeric materials with antimicrobial capacity for biomedical applications, and more particularly for dental purposes, are provided. The incorporation of metal-containing methacrylates such as calcium methacrylate, tin methacrylate, copper methacrylate, silver methacrylate, in combination or alone, for potentializing antimicrobial effect of cements, in particular, to biomaterial compositions including metal containing methacrylates, such as calcium, tin, copper, silver, nickel, titanium and iron methacrylates, in the formulation of biomaterials for applications in human health provides advantages, particularly in dentistry, and allows for expressive antimicrobial activity to dental compositions, so as to be useful in dental prosthesis, operative dentistry, orthodontics, pediatric dentistry, implantodontics, and endodontics.

A method of smoothing teeth is disclosed that is based on surprising evidence achieved by practicing a method involving application of calcium powder or calcium containing composition to teeth, and maintaining it in contact with the teeth by application of an edible adherent wax containing material, that serves to maintain contact between the teeth and the calcium powder or calcium containing composition for at least one hour.

An object of the present invention is to provide a dental material, particularly, a dental prosthesis, having excellent properties such as hydrophilicity and antifouling properties. The dental prosthesis according to the present invention includes a monolayer film obtained by curing a composition including: a compound (I) having at least one hydrophilic group selected from anionic hydrophilic groups and cationic hydrophilic groups, and at least one functional group with a polymerizable carbon-carbon double bond; a compound (II) having two or more functional groups with a polymerizable carbon-carbon double bond (wherein the compound (II) has no anionic hydrophilic group nor cationic hydrophilic group); and a surfactant (III) having a hydrophilic moiety including an anionic hydrophilic group, a cationic hydrophilic group or two or more hydroxyl groups, and a hydrophobic moiety composed of an organic residue (wherein the surfactant has no polymerizable carbon-carbon double bond).

The invention includes a composition comprising a vinyl sulfone monomer, a thiol monomer, and optionally an isocyanate monomer. The invention further includes a composition comprising a composition comprising the tetra(2-mercapto)silane (SiTSH) monomer and at least one selected from the group consisting of (a) a Michael acceptor, optionally an isocyanate monomer, and optionally at least one catalyst selected from the group consisting of a base, nucleophile, photolabile base, photolabile nucleophile, and mixtures thereof; (b) an ene monomer, and optionally a polymerization photoinitiator. In certain embodiments, once the composition is polymerized, the polymerized system is suitable for use as a dental composite system. In other embodiments, the polymerized system is stable to acidic and basic conditions. In yet other embodiments, the polymerized system forms microparticles. The invention further includes a method of generating a dental polymeric material.

The present invention includes compositions comprising an alkyne-based substrate, an azide-based substrate, optionally a Cu(II) salt and optionally a photoinducible reducing agent. The present invention further includes a method of preparing composite materials that are suitable for use as dental implants using the compositions of the invention.

A part adapted for in vivo endosseous implantation made up of a material comprising a thermoplastic organic binder and a fiber charge. The fibers located in a surface layer of the part are mostly delaminated from the binder over all or part of their length. Also, a method for manufacturing such a part.

Dental composition comprising

(a) at least two di- or polyepoxides having 2 to 5 epoxide groups and having a molecular weight of from 200 to 700 Da, or a macromonomeric reaction product obtainable by reacting the diepoxide with a dicarboxylic acid in a molar ratio [diepoxide]/[dicarboxylic acid] of at least 2;
(b) one or more primary monoamines and/or disecondary diamines;
(c) optionally one or more aliphatic polyamines;
(d) a particulate filler,
wherein the molar ratio of epoxide groups in component (a) to the NH bonds in component (b) and (c) [epoxide.sub.(a)]/[NH.sub.(b),(c)] is in the range of from 0.9 to 1.1;
wherein the di- or polyepoxide having 2 to 5 epoxide groups is a compound of the following formula (I):

A(BZ.sub.m).sub.n(I)

wherein
A represents an n-valent organic moiety optionally having 1 to 10 heteroatoms selected from oxygen atoms and sulfur atoms; and
B represents an m+1-valent organic moiety,
Z is an epoxide group which may have a substituent,
m which are independent from each other represent an integer of at least 1; and
n is an integer of from 1 to 5;
wherein the m are selected so that 2 to 5 epoxide groups are present;
wherein the composition does not contain any 2,2-bis-(4-hydroxyphenyl)-propane, or 2,2-bis-(4-hydroxyphenyl)-methane.

To enable firm bonding to a member including a polyaryl ether ketone resin. A bonding method including: a bonding material applying step for applying, to the surface of a member including a polyaryl ether ketone resin, a bonding material including (A) a polymerizable monomer and (B) at least a portion of components for configuring a polymerization initiator, the content ratio of polymerizable monomers at least having two or more polymerizable functional groups in a (p2) molecule among all polymerizable monomers being 50% by mass or greater, and the content ratio of polymerizable monomers at least having one or more polymerizable functional groups and one or more functional groups capable of hydrogen bonding in a (p1h1) molecule being 5% by mass or greater; and a curing step for curing the bonding material. A bonding material and bonding kit using the bonding method.

A dental restorative composition is provided that includes a polymerizable resin, a substantially translucent structural filler, a nanofiller having a mean particle size less than 100 nm, and at least one rheology-modifying additive. In one embodiment, the structural filler has a refractive index substantially similar to that of the polymerizable resin, a coarse particle fraction, and a fine particle fraction having a mean particle size greater than 0.1 m and smaller than the mean particle size of the coarse particle fraction. The relative ratio of the coarse particle fraction to the fine particle fraction is in the range from about 12:1 to about 2:1 by volume, the particle size distribution of each fraction is essentially monomodal, and the D(90) of the fine particle fraction is less than or equal to the D(10) of the coarse particle fraction.

Methods and systems for using a curable material for endodontic processes are provided. The method comprises using an electroactive composition to cure and optionally un-cure the material. Using an electroactive composition allows for easy introduction of the material without unwanted complexity or side effects. It also allows for easy removal and replacement if desired.