A working fluid that includes a fluorinated olefin compound represented by the following general formula (I): ##STR00001##

A method of fighting a fire, the method includes aerating a firefighting foam composition to form an aerated firefighting foam; administering the aerated firefighting foam to a fire or applying the aerated firefighting foam to a surface of a volatile flammable liquid; wherein the firefighting foam composition includes a surfactant component comprising an anionic surfactant, a zwitterionic surfactant, optionally a nonionic surfactant, or a mixture of any two or more thereof; an aliphatic alcohol-based component comprising at least two compounds selected from C.sub.8-C.sub.14-aliphatic alcohols and ethoxylates of C.sub.10-C.sub.14-aliphatic alcohols having an average of no more than about 6 ethylene oxide units; and at least about 30 wt. % water.

A firefighting composition for use in onboard firefighting systems of heavy industrial equipment, such as heavy vehicles and other types of heavy equipment used in construction, forestry, mining, and other similar industries, includes aqueous liquids that include (a) a sodium and/or potassium salt of an organic acid; (b) one or more of an alkylpolyglycoside surfactant, an alkyl sulfate anionic surfactant, an alkyliminodialkylcarboxylate surfactant and a zwitterionic surfactant; (c) an acetylenic diol derivative surfactant and/or a siloxane-based surfactant; and (d) alkylene glycol and/or glycerol.

A method of proportioning a finished foam at or near a hazard comprising proportioning and delivering a first finished foam to the hazard, determining if the first finished foam extinguishes or suppresses the hazard, if not, selecting an amount of a fluorinated additive, and proportioning a foam solution including the selected amount of the fluorinated additive to form a fluorinated finished foam. A foam injection system is also disclosed.

An environmentally-clean aqueous-based fire extinguishing biochemical liquid concentrate to be mixed with a proportioned quantity of water, to produce a fire extinguishing water stream that produces good immediate extinguishing effects when applied to extinguish a burning or smoldering fire, and good long-term fire inhibiting effects when being proactively applied to protect combustible surfaces against the threat of fire. The environmentally-clean aqueous-based fire extinguishing biochemical liquid concentrate includes: a dispersing agent realized in the form of a quantity of water, for dispersing potassium ions dissolved in water; a fire inhibiting agent in the form of at least one alkali metal salt of a nonpolymeric saturated carboxylic acid, specifically potassium citrate, for providing potassium ions dispersed in the quantity of water when the potassium citrate is dissolved in the quantity of water; and a dispersing agent in the form of triethyl citrate, an ester of citric acid, for dispersing the potassium ions in the quantity of water, and lowering the surface tension of the liquid solution formed when the potassium citrate is dissolved in the quantity of water, forming of a fire extinguishing liquid solution, for mixing with a proportioned amount of water, to produce a fire extinguishing water stream having good immediate extinguishing effects when applied to extinguish a burning or smoldering fire, and good long-term fire inhibiting effects when applied proactively to protect combustible surfaces against the threat of fire ignition and flame spread of an incident fire.

Poly-perfluoroalkyl substituted polyethyleneimine compositions are provided that act as foam stabilizers and film formers when used in fire-fighting foam concentrates. The polyethylene compositions are soluble in water, but have only low solubility in polar solvents. When aqueous film forming foam generated from these concentrates is applied to burning polar solvent the polyethyleneimine compositions precipitate at the polar solvent/foam interface and inhibit the collapse and destruction of the foam.

It has been discovered that low molecular weight poly(ethyleneglycol) (PEG) can be used in place of diethylene glycol monobutyl ether (DGME) in fire foam concentrates without compromising the desirable properties provided by DGME. Surprisingly it has been found that lower molecular weight PEG with a weight average molecular weight Mw of 400 or less provides comparable performance to DGME with considerably lower toxicity. Use of this PEG permits preparation of fire foam concentrates that exclude DGME completely and that are less toxic than conventional DGME-containing concentrates.

A foam stabilizing composition includes a) colloidal silica and b) a siloxane cationic surfactant. The siloxane cationic surfactant includes a cationic moiety having the formula Z.sup.1-D.sup.1-N(Y).sub.a(R).sub.2-a, where Z.sup.1 is a siloxane moiety, D.sup.1 is a divalent linking group, R is H or an unsubstituted hydrocarbyl group having from 1 to 4 carbon atoms, subscript a is 1 or 2, and each Y has formula -D-NR.sup.1.sub.3+, where D is a divalent linking group and each R.sup.1 is independently an unsubstituted hydrocarbyl group having from 1 to 4 carbon atoms. A firefighting includes the foam stabilizing composition and water. Methods of making and using the same are also provided.

A fire-fighting composition and method of manufacture of the same has been disclosed herewith. The composition comprises a natural gum, glycol ether, sodium lauryl sulfate, other anionic surfactant(s), non-ionic surfactant(s), and many other propriety components. The resultant composition passed in-house testsmeasuring cylinder test, torch test and hot heptane test. The composition does not contain any fluorinated surfactant or compounds. When diluted at 3% concentration, the solution produces satisfactory quantity of foam under pressure to extinguish fire.

The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises a fluoroolefin and at least one other component. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents.