An object of the present invention is to provide a mixture of cyclophosphazenes suitably substituted with phenoxy having a polymerizable functional group, such as allyl, on the phenyl ring and a production method for the mixture. The invention relates to a mixture of cyclophosphazene compounds that each contain a plurality of constituent units linked to each other, each constituent unit being represented by formula (I):

##STR00001##

wherein R.sup.1 and R.sup.2 are identical or different and represent C.sub.1-4 alkyl or the like, the mixture containing cyclophosphazene compounds in which 3, 4, and 5 constituent units represented by formula (I) are linked, wherein the cyclophosphazene compound containing 3 linked constituent units is cyclophosphazene compound (I-A) with a specific structure, compound (I-A) includes cyclophosphazene compounds (I-A2) and (I-A3) having a specific structure, and compounds (I-A2) and (I-A3) are present in an amount of 80 wt % or more in total in cyclophosphazene compound (I-A).

The present invention relates to new dendrimers with thiophosphoramidate units and derivatives, their preparation method and their use.

Provided is a manufacturing method for an amino-substituted phosphazene compound, including: reacting a fluorinated phosphazene compound and an amine compound in presence of a catalyst consisting of a compound consisting of a specific element M below and an oxygen atom as constituent elements; and obtaining an amino-substituted phosphazene compound by substitution reaction between a fluorine atom of the fluorinated phosphazene compound and an amino group of the amine compound. Specific element M: At least one selected from magnesium, titanium, zirconium, vanadium, lithium, calcium, aluminum, manganese, molybdenum, silicon, or boron.

Provided are a phosphazene compound, a method for preparing a phosphazene compound and a method for producing a polymer with a phosphazene compound as a catalyst. The compound of formula (I) or a solvate thereof, where A is a six- or eight-membered ring consisting of repeated PN, and B is at least one of unsubstituted or substituted C.sub.1-6 alkylamino, unsubstituted or substituted C.sub.1-6 cycloalkylamino, unsubstituted or substituted arylamino,

##STR00001##

or halogen, and B is attached to A at phosphorus in PN, where R is unsubstituted or substituted C.sub.1-6 alkyl, unsubstituted or substituted C.sub.1-6 cycloalkyl, unsubstituted or substituted aryl, or unsubstituted or substituted benzyl, or R forms C.sub.1-6 heterocycloalkyl together with N attached thereto.

##STR00002##

An object of the present invention is to provide a mixture of cyclophosphazenes suitably substituted with phenoxy having a polymerizable functional group, such as allyl, on the phenyl ring and a production method for the mixture. The invention relates to a mixture of cyclophosphazene compounds that each contain a plurality of constituent units linked to each other, each constituent unit being represented by formula (I): ##STR00001##
wherein R.sup.1 and R.sup.2 are identical or different and represent C.sub.1-4 alkyl or the like, the mixture containing cyclophosphazene compounds in which 3, 4, and 5 constituent units represented by formula (I) are linked, wherein the cyclophosphazene compound containing 3 linked constituent units is cyclophosphazene compound (I-A) with a specific structure, compound (I-A) includes cyclophosphazene compounds (I-A2) and (I-A3) having a specific structure, and compounds (I-A2) and (I-A3) are present in an amount of 80 wt % or more in total in cyclophosphazene compound (I-A).

Disclosed herein are cyclopolyphosphazenes of formula I:

##STR00001##

methods for the preparation thereof and uses thereof in adjuvant compositions.

The present invention relates to a phosphazene compound and a composite metal laminate. The phosphazene compound with a partial structure of carboxylic esters has a structure as shown in Formula (I). The present invention obtains a phosphazene compound with a partial structure of carboxylic esters using an M group having specific components. The cured products of the phosphazene compound have good flame retardancy, heat resistance, mechanical properties, flame retardancy, and low dielectric constant, and are a low dielectric flame retardant material having great economic properties and being environmental friendly.

The present invention relates to a phosphazene compound and a prepreg and a composite metal laminate. The phosphazene compound has a structure as shown in Formula (I). The present invention obtains a phosphazene compound using an M group having specific components. The composite metal laminates prepared by the epoxy resin composition comprising the phosphazene compound have low dielectric properties, good heat resistance and mechanical properties and is a low dielectric material also having great economic properties and being environmental friendly.

The present invention relates to n-dopants for doping organic electron transport materials, wherein the n-dopants have at least one aminophosphazene group of formula 1 having 4 nitrogen atoms bonded to a phosphorus atom. ##STR00001##

Provided is a polyphosphazene produced by a cyclic phosphazene of formula (1)

##STR00001##

wherein k is a natural number between 1 and 10, with a bis-hydroxy-terminated phosphonate of formula (2) HOR.sup.2[OP(O)(R.sup.1)OR.sup.2].sub.aOH (2), wherein R.sup.1 represents C.sub.1- to C.sub.20-alkyl, C.sub.2-C.sub.20 alkylene, C.sub.5-C.sub.20 cycloalkyl or C.sub.6-C.sub.20 aryl, R.sup.2 represents C.sub.1- to C.sub.20-alkyl, phenyl or a bisphenyl, and n represents 1-10, in the presence of a base. Also provided is a process for producing the polyphosphazene, a moulding compound comprising the polyphosphazene and a thermoplastic polymer.