A method of destroying a fluorocarbon compound includes regenerating an adsorbent to remove the fluorocarbon compound and to produce a regeneration fluid having a concentration of the fluorocarbon compound and directing the regeneration fluid to an electro-oxidation system. The method also includes applying a current to the electro-oxidation system to oxidize the fluorocarbon compound within the regeneration fluid and measuring a quantity of fluorides in the regeneration fluid to determine the progress of the removal of the fluorocarbon compound from the regeneration fluid.

In one aspect, separation media are described herein operable for removing one or more water contaminants, including NOM, fluorinated chemicals, and/or derivatives thereof. Briefly, a separation medium comprises a silica-containing granular support; and an oligomeric stationary phase forming a film on individual grains of the granular support. In some embodiments, the oligomeric stationary phase comprises oligomeric chains covalently bound to the individual grains.

Sorbent materials that are treated with ions, salts, oxides, hydroxides, or carbonates of calcium, magnesium, strontium, or barium are useful in removing perfluoroalkyl and polyfluoroalkyl substances (PFAS), perfluorooctanoic acid (PFOA), perfluorooctanesulfonic acid (PFOS), 2,3,3,3,-tetrafluoro-2-(heptafluoropropoxy)propanoate and heptafluoropropyl 1,2,2,2-tetrafluoroethyl ether, and similar compounds from liquids and gases are disclosed. The sorbent materials with the disclosed treatments offer improved performance as measured against untreated sorbent materials.

Methods, systems, and devices for PFAS destruction including providing water containing PFAS to a reactor vessel, irradiating the water with UV light under conditions to destroy at least a portion of the PFAS, passing the treated water through a selective membrane to form permeate and membrane reject comprising PFAS, providing the membrane reject back to the reactor vessel, providing additional water containing PFAS to the reactor vessel within the reactor vessel or before being provided to the reactor vessel, and irradiating the membrane reject and the additional water containing PFAS within the reactor vessel with UV light. The steps may be repeated a plurality of times such that PFAS that is not destroyed is recycled through the reactor vessel. Sensitizers may be added and may also be recycled in the membrane reject with the PFAS.

The present invention relates to the technical field of wastewater treatment, and discloses a method for enhanced bio-treatment of refractory organic pollutants with photo-excited holes as electron acceptors. The method comprises the following steps: 1) placing a composite semiconductor-coated carrier material into a reactor, introducing wastewater into the reactor inoculated with anaerobic sludge, and allowing the composite semiconductor-coated carrier material to be immersed in the wastewater, wherein the composite semiconductor-coated carrier material comprises a conductive carrier and composite semiconductor materials loaded on the conductive carrier; 2) carrying out habituated culture on the anaerobic sludge for a period of time, and loading a biological membrane on the surface of the composite semiconductor materials, to construct a photo-excited hole enhanced bioreactor; and 3) treating the refractory pollutants in the wastewater by utilizing the reactor under irradiation.

A method of moderating concentration of at least highly fluorinated alkyl materials (e.g., molecules) from a contaminated aqueous feed liquid containing an original composition of between 5 parts/trillion and 3000 parts/billion of the at least highly fluorinated materials per liter of water into an aqueous electronic separator having multiple chambers including a feed chamber having a liquid exit port from which a mediated aqueous contaminated feed liquid exits and a liquid input port into which the contaminated aqueous feed liquid enters the feed chamber; an anodic electrode chamber filled with an aqueous anodic liquid; and a cathodic electrode chamber filled with an aqueous cathodic liquid; wherein the feed chamber is between and adjacent to the anodic electrode chamber and the cathodic electrode chamber and the feed chamber is separated from each of the anodic electrode chamber and the cathodic electrode chamber by at least one semipermeable membrane.

A drop-in treatment apparatus, system, and method for treating PFAS-impacted liquids. The drop-in treatment apparatus may comprise a cartridge having a plurality openings; a mesh container disposed within the cartridge; a submersible pump coupled to the cartridge; and a power source electrically coupled to the submersible pump. The drop-in treatment apparatus may further comprise a prescribed mass of sorbent or resin filled within the mesh container, such that the prescribed mass of sorbent or resin may be disposed within the cartridge. The prescribed mass of sorbent or resin may be configured to remove PFAS compounds from a liquid and may be in the range of 0.1-50,000 milligrams per milliliter of liquid volume to be treated. The liquid is preferably stored within a drum container, and the drop-in treatment apparatus is preferably submerged into the liquid. The sorbent may be pyrogenic carbon, granular activated carbon, biochar, zeolite, aluminosilicates, and combinations thereof.

The present disclosure provides systems and methods for degrading per- and poly-fluoroalkyl substances (PFAS) using hydrated electrons generated in an ultraviolet (UV)/sulfite system. These systems and methods may be used, e.g., to remediate wastewater by destroying PFAS and co-contaminants such as chlorinated volatile organic compounds (CVOCs).

A treatment method and system using high-frequency ultrasound for treating a waste stream containing per- and polyfluoroalkyl substance (PFAS) is disclosed. The system has one or more reactors including one or more transducers configured to operating at one or more frequencies to destroy or mineralize the per- and polyfluoroalkyl substances (PFAS) in the waste stream using sonolysis.

An electrode apparatus and method remove a polarized molecule in a fluid. In another aspect, a non-uniform electric field is created between an anode and a cathode, the fluid flows within a gap between the cathode and the anode, and the polarized molecule is driven by an electrostatic force to and adsorbed on the anode without experiencing a chemical reaction.