B01J35/0066

EXHAUST GAS TREATMENT SYSTEM COMPRISING A MULTIFUNCTIONAL CATALYST
20230219039 · 2023-07-13 ·

The present invention relates to an exhaust gas treatment system for treating exhaust gas from a lean burn combustion engine, wherein said exhaust gas comprises hydrocarbons and NOx, the exhaust gas treatment system comprising: (i) a means for injecting hydrocarbons into an exhaust gas stream; (ii) a diesel oxidation catalyst (DOC) comprising a substrate and a catalyst coating provided on the substrate, wherein the catalyst coating comprises one or more platinum group metals, wherein the one or more platinum group metals comprise platinum; (iii) a means for injecting a nitrogenous reducing agent into an exhaust gas stream; and (iv) a multifunctional catalyst (MFC) comprising an oxidation catalyst, and a selective catalytic reduction (SCR) catalyst for the selective catalytic reduction of NOx, wherein the MFC comprises a substrate and a catalyst coating provided on the substrate, wherein the catalyst coating comprises the oxidation catalyst and the SCR catalyst, wherein the oxidation catalyst comprises one or more platinum group metals, wherein the one or more platinum group metals comprise palladium and/or platinum, and wherein the SCR catalyst comprises a zeolitic material loaded with copper and/or iron; wherein the means for injecting hydrocarbons, the DOC, the means for injecting a nitrogenous reducing agent, and the MFC are located in sequential order in a conduit for exhaust gas, wherein the means for injecting hydrocarbons into an exhaust gas stream is located upstream of the DOC, wherein the DOC is located upstream of the MFC, and wherein the means for injecting a nitrogenous reducing agent into the exhaust gas stream is located between the DOC and the MFC. Furthermore, the present invention relates to a method for the treatment of exhaust gas using the exhaust gas treatment system according to the present invention, and to a method for the preparation of an exhaust gas treatment system according to the present invention.

AMMONIA SYNTHESIS CATALYST AND METHOD FOR MANUFACTURING AMMONIA

Provided is a catalyst that is free from catalyst deactivation caused by reaction of the support and exhibits good catalytic activity in an ammonia synthesis reaction in a low-temperature, low-pressure process. The present invention relates to an ammonia synthesis catalyst having a structure in which at least one of ruthenium or an oxide of ruthenium is loaded on a titanium suboxide support represented by the composition formula TiOx where x represents a number satisfying 1.5<x<2.0.

CATALYST STRUCTURE FOR SYNTHESIS GAS PRODUCTION, SYNTHESIS GAS PRODUCTION APPARATUS, AND METHOD FOR PRODUCING CATALYST STRUCTURE FOR SYNTHESIS GAS PRODUCTION

A catalyst structure for synthesis gas production of a synthesis gas that contains carbon monoxide and hydrogen, the catalyst structure being provided with a carrier that has a porous structure, while being configured from a zeolite type compound; first catalyst particles that contain one or more iron group elements which are selected from the group consisting of nickel (Ni), iron (Fe) and cobalt (Co); and second catalyst particles that contain one or more platinum group elements which are selected from the group consisting of platinum (Pt), palladium (Pd), rhodium (Rh) and ruthenium (Ru). The catalyst structure for synthesis gas production has passages in communication with each other within the carrier. The first catalyst particles are present at least in the passages of the carrier; and the second catalyst particles are present at least either inside the carrier or on the outer surface of the carrier.

Structured catalyst for oxidation for exhaust gas purification, method for producing same, automobile exhaust gas treatment device, catalytic molding, and gas purification method

The structured catalyst for oxidation for exhaust gas purification includes a support having a porous structure constituted by a zeolite-type compound, and at least one type of oxidation catalyst that is present in the support and selected from the group consisting of metal and metal oxide, the support having channels that communicate with each other, and the oxidation catalyst being present in at least the channels of the support.

HIGHLY CHLORINE- AND WATER-RESISTANT CATALYST, PREPARATION METHOD THEREFOR AND USE THEREOF

A preparation method for a highly chlorine- and water-resistant catalyst is provided. A mixture of at least one of SnO.sub.2, GeO.sub.2, and MoO.sub.2 with CeO.sub.2 is used as a catalyst support, face-centered cubic ruthenium oxide is used as an active component, and the catalyst with excellent chlorine- and water-resistance is prepared through selective adsorption regulation, which can realize safe and efficient purification of chlorine-containing organic waste gas at temperatures below 250° C.

Acid-resistant catalyst supports and catalysts

A process for preparing a catalyst comprises coating substantial internal surfaces of porous inorganic powders with titanium oxide to form titanium oxide-coated inorganic powders. After the coating, an extrudate comprising the titanium oxide-coated inorganic powders is formed and calcined to form a catalyst support. Then, the catalyst support is impregnated with a solution containing one or more salts of metal selected from the group consisting of molybdenum, cobalt, and nickel.

Method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst

A method for preparing methyl methacrylate from methacrolein and methanol. The process comprises contacting in a reactor a mixture comprising methacrolein, methanol and oxygen with a heterogeneous catalyst comprising a support and a noble metal, wherein said catalyst has an average diameter of at least 200 microns, liquid and gaseous reactants flow downward in the reactor and wherein the continuous phase in the reactor is a gas which has no more than 7.5 mol % oxygen at reactor inlets.

PALLADIUM FIXING AND LOW FRESH OXYGEN STORAGE CAPACITY USING TANNIC ACID AS A COMPLEXING AND REDUCING AGENT
20220401926 · 2022-12-22 ·

A method of manufacturing a catalyst article, the method comprising: providing a complex of a polyphenol and a PGM, the polyphenol comprising an ester functional group, the PGM comprising palladium; providing a support material; applying the complex to the support material to form a loaded support material; disposing the loaded support material on a substrate; and heating the loaded support material to form nanoparticles of the PGM on the support material.

Bifunctional Metal Oxides And Paraffin Isomerization Therewith

Tungstated zirconium catalysts for paraffin isomerization may comprise: a mixed metal oxide that is at least partially crystalline and comprises tungsten, zirconium, and a variable oxidation state metal selected from Fe, Mn, Co, Cu, Ce, Ni, and any combination thereof. The mixed metal oxide comprises about 5 wt. % to about 25 wt. % tungsten, about 40 wt. % to about 70 wt. % zirconium, and about 0.01 wt. % to about 5 wt. % variable oxidation state metal, each based on a total mass of the mixed metal oxide. The mixed metal oxide has a total surface area of about 50 m.sup.2/g or greater as measured according to ISO 9277, and at least one of the following: an ammonia uptake of about 0.05 to about 0.3 mmol/g as measured by temperature programmed adsorption/desorption, or a collidine uptake of about 100 μmol/g or greater as measured gravimetrically.

TWC ACTIVITY USING RHODIUM/PLATINUM AND TANNIC ACID AS A COMPLEXING AND REDUCING AGENT
20220401925 · 2022-12-22 ·

A method of manufacturing a catalyst article, the method comprising: providing a complex of a polyphenol and a PGM, the PGM comprising rhodium and/or platinum, the polyphenol comprising an ester functional group; providing a support material; applying the complex to the support material to form a loaded support material; disposing the loaded support material on a substrate; and heating the loaded support material to form nanoparticles of the PGM on the support material.