A method for catalytic vapor phase oxidation of methanol to formaldehyde may include: passing a feed stream comprising methanol and oxygen through a layered catalyst bed having a first layer comprising a first silver catalyst particles and a second layer comprising a second silver catalyst particles that are different than the first silver catalyst particles, wherein the feed stream passes through the first layer before the second layer, wherein the first silver catalyst particles has a greater reaction activity for converting methanol and oxygen to formaldehyde; and reacting the methanol and the oxygen in the presence of the catalysts to produce a product stream comprising formaldehyde.

A multilayer supported oxidative coupling of methane (OCM) catalyst composition (support, first single oxide layer, one or more mixed oxide layers, optional second single oxide layer) characterized by formula A.sub.aZ.sub.bE.sub.cD.sub.dO.sub.x/support; A is alkaline earth metal; Z is first rare earth element; E is second rare earth element; D is redox agent/third rare earth element; the first, second, third rare earth element are not the same; a=1.0; b=0.1-10.0; c=0.1-10.0; d=0-10.0; x balances oxidation states; first single oxide layer (Z.sub.b1O.sub.x1, b1=0.1-10.0; x1 balances oxidation states) contacts support and one or more mixed oxide layers; one or more mixed oxide layers (A.sub.a2Z.sub.b2E.sub.c2D.sub.d2O.sub.x2, a2=1.0; b2=0.1-10.0; c2=0.1-10.0; d2=0-10.0; x2 balances oxidation states; A.sub.aZ.sub.bE.sub.cD.sub.dO.sub.x and A.sub.a2Z.sub.b2E.sub.c2D.sub.d2O.sub.x2 are different) contacts first single oxide layer and optionally second single oxide layer, and second single oxide layer (AO), when present, contacts one or more mixed oxide layers and optionally first single oxide layer.

An object of the present invention is to provide a catalyst capable of improving the selectivity of unsaturated aldehydes and unsaturated carboxylic acids, and a catalyst containing molybdenum, antimony, bismuth, and iron, wherein an atom ratio of the antimony to the molybdenum on a surface of the catalyst is greater than an atom ratio of the antimony to the molybdenum in the entire catalyst is provided.

There is provided an exhaust gas purification device that shows a high HC removal performance under a condition in which a rich air-fuel mixture is introduced. The exhaust gas purification device includes a substrate, a first catalyst layer, and a second catalyst layer. The substrate includes an upstream end and a downstream end. The first catalyst layer is disposed on a surface of the partition wall in an upstream region including the upstream end of the substrate. The second catalyst layer is disposed inside the partition wall in a downstream region including the downstream end of the substrate. The first catalyst layer contains a first metal catalyst and alumina-zirconia composite oxide. The second catalyst layer contains a second metal catalyst.

The present invention relates to a diesel oxidation catalyst comprising a substrate and a wash-coat comprising a first layer and a second layer, wherein the substrate has a substrate length, a front end and a rear end, the washcoat comprising the first layer comprising a first metal oxide and comprising a platinum group metal supported on a metal oxide support material; the second layer comprising a second metal oxide and comprising one or more of an oxidic compound of vanadium, an oxidic compound of tungsten and a zeolitic material comprising one or more of Fe and Cu; wherein the first layer is at least partially disposed directly on the substrate, or is at least partially disposed directly on an intermediate layer which is disposed directly on the substrate over the entire length of the substrate, on x % of the length of the substrate from the front end of the substrate, and wherein the second layer is at least partially disposed directly on the substrate, or is at least partially disposed directly on the intermediate layer which is disposed directly on the substrate over the entire length of the substrate, on y % of the length of the substrate from the rear end of the substrate, wherein x is in the range of from 25 to 75 and y is in the range of from 25 to 75 and wherein x+y is in the range of from 95 to 105, wherein the intermediate layer comprises alumina.

The present invention relates to a process for conveniently preparing a supported cobalt-containing Fischer-Tropsch synthesis catalyst having improved activity and selectivity for C.sub.5+ hydrocarbons. In one aspect, the present invention provides a process for preparing a supported cobalt-containing Fischer-Tropsch synthesis catalyst, said process comprising the steps of: (a) impregnating a support material with: i) a cobalt-containing compound and ii) acetic acid, or a manganese salt of acetic acid, in a single impregnation step to form an impregnated support material; and (b) drying and calcining the impregnated support material; wherein the support material impregnated in step (a) has not previously been modified with a source of metal other than cobalt; and wherein when the cobalt-containing compound is cobalt hydroxide, a manganese salt of acetic acid is not used in step (a) of the process.

A modified Y-type molecular sieve has a modifying metal content of about 0.5-6.3 wt % calculated on the basis of an oxide of the modifying metal and a sodium content of no more than about 0.5 wt % calculated on the basis of sodium oxide. The modifying metal is magnesium and/or calcium. The modified Y-type molecular sieve has a proportion of non-framework aluminum content to the total aluminum content of no more than about 20%, a total pore volume of about 0.33-0.39 ml/g, a proportion of the pore volume of secondary pores having a pore size of 2-100 nm to the total pore volume of about 10-25%, a lattice constant of about 2.440-2.455 nm, a lattice collapse temperature of not lower than about 1040° C., and a ratio of B acid to L acid in the total acid content of no less than about 2.30.

Methods of producing an isomerization catalyst include preparing a catalyst precursor solution, hydrothermally treating the catalyst precursor solution to produce a magnesium oxide precipitant, and calcining the magnesium oxide precipitant to produce the isomerization catalyst. The catalyst precursor solution includes at least a magnesium precursor, a hydrolyzing agent, and polyethylene glycol. Methods of producing propene from a butene-containing feedstock with the isomerization catalyst and a metathesis catalyst are also disclosed.

The present invention relates to a diesel oxidation catalyst comprising a carrier body having a length L extending between a first end face and a second end face, and differently composed material zones A and B arranged on the carrier body, wherein material zone A comprises platinum and palladium applied to a cerium-titanium mixed oxide, and material zone B comprises platinum and palladium applied to a carrier oxide B.

The present disclosure relates to an FCC catalyst composition and a process for its preparation. The FCC catalyst composition comprises Y type zeolite, silicon oxide, alumina, at least one clay, at least one rare earth metal, and at least one metal oxide. The FCC catalyst composition of the present disclosure provides improved yields of high value gasoline such as propylene and LPG and reduces yields of low value hydrocarbons such as CSO and LCO.