Patent classifications
B01J35/004
NICKEL-BASED MOF FILM PHOTOCATALYST GROWN IN-SITU ON FOAMED NICKEL SURFACE, PREPARATION METHOD THEREFOR, AND APPLICATION THEREOF
A nickel-based MOF film photocatalyst grown in-situ on a foamed nickel surface, a preparation method therefor, and an application thereof. The nickel-based MOF film photocatalyst grown in-situ on a foamed nickel surface is prepared by first immersing foamed nickel in a diluted acid and performing ultrasonic processing, then cleaning the foamed nickel with deionized water, and drying the foamed nickel to obtain surface-activated foamed nickel; immersing the surface-activated nickel foam in a mixture of an imidazole compound, sodium formate, and a solvent and reacting at 100° C. to 180° C. to obtain an unactivated nickel-based MOFs film on the surface of the foamed nickel, and after cooling to room temperature, removing same and soaking in an organic solvent to activate, and then drying the obtained product. The film photocatalyst synthesized in-situ on the foamed nickel can increase the specific surface area of the material to facilitate the adsorption and diffusion of VOCs, and can expose more catalytic sites, so that the VOCs can be effectively degraded under the action of sunlight.
METHODS OF MAKING A THREE-DIMENSIONAL OBJECT
Provided herein is a method of making a three-dimensional object (31) by bottom-up additive manufacturing, which method may include: providing a carrier platform (14), a light source (13), and a light transmissive window (11) therebetween, the light transmissive window comprising a gas permeable member having a top surface and a bottom surface; depositing a liquid resin (21) on the window, the resin comprising a cyclic olefin monomer and a ring-opening metathesis polymerization (ROMP) photocatalyst; contacting a gas to said gas permeable member bottom surface; and exposing said resin to light from said light source while advancing aid carrier platform away from said window to form said three-dimensional object on said carrier platform. An apparatus useful for carrying out the method and a method useful for recycling the object are also provided.
PHOTOCATALYTICALLY ACTIVE AEROGEL CONCRETE
The invention relates to an aerogel concrete mixture containing a photocatalyst, a photocatalytically active high-performance aerogel concrete obtainable therefrom and a method for producing same.
Method for making photocatalytic structure
The disclosure relates to a method for making a photocatalytic structure, the method comprising: providing a carbon nanotube structure comprising a plurality of carbon nanotubes intersected with each other; a plurality of openings being defined by the plurality of carbon nanotubes; forming a photocatalytic active layer on the surface of the carbon nanotube structure; applying a metal layer pre-form on the surface of the photocatalytic active layer; and annealing the metal layer pre-form.
METHOD FOR PRODUCING AND DISCHARGING ULTRAPURE HYDROGEN PEROXIDE GAS INTO THE AMBIENT AIR, RELATED EQUIPMENT, SPECIAL POLYMER NANOCOMPOSITE, AND USES
Method for producing and discharging ultrapure hydrogen peroxide gas GPHU into the ambient air, said gas being substantially free of hygroscopic substances and substantially free of metals, primarily for use in bio-oxidative treatments via the blood stream by inhalation, for use in humans and animals. Said method comprises ultrapure hydrogen peroxide gas, alkaline nanostructured nanomaterial metal catalyst, special polymer nanocomposite material NPE and UV light. The ultrapure hydrogen peroxide gas is discharged into the ambient air naturally by the surface of the NPE. Equipment for producing and discharging ultrapure hydrogen peroxide gas into the ambient air is also disclosed.
NEAR-INFRARED PHOTOTHERMAL CATALYST AND PREPARATION METHOD AND USE THEREOF
The present disclosure provides a near-infrared (NIR) photothermal catalyst and a preparation method and use thereof. The method includes: mixing a graphene oxide (GO) dispersion and a dehydrating agent to obtain a GO solution; mixing the GO solution and branched polyethyleneimine (PEI) and then drying to obtain a GO-PEI carrier; and mixing the GO-PEI carrier with water and adjusting a pH value to be within a range of 2 to 4.5, adding dropwise a monosubstituted Keggin-type polyoxometalate (POM) aqueous solution, and conducting an ion replacement reaction to obtain the NIR photothermal catalyst, wherein a solute of the monosubstituted Keggin-type POM aqueous solution is K.sub.6SiW.sub.11Co(H.sub.2O)O.sub.39 or H.sub.4SiW.sub.11Ce(H.sub.2O).sub.4O.sub.39.
PROCESS AND CATALYST
A process for producing a gaseous product comprising hydrogen, said process comprising exposing a gaseous hydrocarbon to microwave radiation in the presence of a solid catalyst, wherein the catalyst comprises at least one metal species on a support, wherein the metal species is at least one a nickel species or a cobalt species; and a solid catalyst suitable for use in said process, and wherein the support comprises at least one of a carbonate or an alkaline earth metal oxide.
METHOD FOR PREPARING CORE-SHELL STRUCTURE PHOTOCATALYTIC MATERIAL BY PRECIPITATION AND SELF-ASSEMBLY PROCESS
A method for preparing a core-shell structure photocatalytic material includes: obtaining a titanyl sulfate solution by mixing and reacting sulfuric acid and metatitanic acid; obtaining a mixed solution by adding a porous material having a hydrophilic surface into the titanyl sulfate solution; adding an alkali into the mixed solution to obtain a precipitation product by reacting the alkali with the titanyl sulfate coated on the surface of the porous material; and filtering, washing, drying and calcining the precipitation product to obtaining a core-shell structure photocatalytic material with the porous material as a core and a mesoporous quantum titanium oxide as a shell.
TITANIUM DIOXIDE COATED SUBSTRATE WITH ADHESIVE
A device includes a flexible substrate having a length and width greater than a depth of the substrate. A photocatalytic titanium dioxide or silver photocatalytic titanium dioxide coating is supported by the substrate on a first surface defined by the length and width of the substrate. An adhesive is disposed on a second surface of the substrate opposite the first surface of the substrate.
CATALYST CARRIER STRUCTURE
The catalyst carrier structure of the present invention includes a central axis, and a plurality of fibers. The surface of each fiber is coated with a catalyst. The fibers are centered on the central axis, and are arranged around the central axis radially outward along the axial direction of the central axis. Each fiber is an independent and separate fiber set on the central axis.