B01J35/026

Silica-Alumina Composite Materials for Hydroprocessing Applications

A silica-alumina based composite material for making hydroprocessing catalysts, is disclosed. The silica-alumina composite material generally comprises at least two silica-aluminas, the first being a modified first silica-alumina, and the second being a second silica-alumina that is unmodified or modified. The first silica-alumina is modified to comprise silica and alumina domains and a silica-alumina interphase. The second silica-alumina may also be modified at the same time or separately to comprise silica and alumina domains and a silica-alumina interphase. The first silica-alumina and the second silica-alumina differ in one or more physical and/or chemical characteristics, e.g., the ratio of silica to alumina, surface area, pore size, pore volume, silica domain size, or alumina domain size. The invention can be used for making catalyst base materials and catalysts useful for upgrading hydrocarbon feedstocks to produce fuels, lubricants, chemicals and other hydrocarbonaceous compositions.

COVALENT ORGANIC FRAMEWORKS AND APPLICATIONS THEREOF IN CHEMICAL REACTIONS
20230001397 · 2023-01-05 ·

organic frameworks that include catalytic components incorporated throughout the framework. These covalent organic frameworks have unique structural and physical properties, which lend these frameworks to be versatile and useful in a number of different applications and uses and chemical reactions. In one, the covalent organic frameworks include a plurality of fused aromatic groups or polyaromatic groups and ligands, where catalytic components such as transition metal catalysts are coordinated by the ligand to the frameworks.

CATALYTIC GASIFICATION PROCESS, CATALYST, USE OF THE CATALYST AND PROCESS FOR PREPARING THE CATALYST

The present invention relates to a catalyst to be applied to the process of gasification of coke or coal, individually or in mixture, and to the process of preparing said catalyst, which is useful in obtaining higher levels of hydrogen and carbon monoxide, which allows the conversion of coke into by-products of higher added value (hydrogen-rich syngas). The present invention also addresses to a process for converting petroleum coke by using a catalyst according to the present invention.

TABLETED ALPHA-ALUMINA CATALYST SUPPORT

A tableted catalyst support, characterized by an alpha-alumina content of at least 85 wt.-%, a pore volume of at least 0.40 mL/g, as determined by mercury porosimetry, and a BET surface area of 0.5 to 5.0 m.sup.2/g. The tableted catalyst support is an alpha-alumina catalyst support obtained with high geometrical precision and displaying a high overall pore volume, thus allowing for impregnation with a high amount of silver, while exhibiting a surface area sufficiently large so as to provide optimal dispersion of catalytically active species, in particular metal species. The invention further provides a process for producing a tableted alpha-alumina catalyst support, which comprises i) forming a free-flowing feed mixture comprising, based on inorganic solids content, at least 50 wt.-% of a transition alumina; ii) tableting the free-flowing feed mixture to obtain a compacted body; and iii) heat treating the compacted body at a temperature of at least 1100° C., preferably at least 1300° C., more preferably at least 1400° C., in particular at least 1450° C., to obtain the tableted alpha-alumina catalyst support. The invention moreover relates to a compacted body obtained by tableting a free-flowing feed mixture which comprises, based on inorganic solids content, at least 50 wt.-% of a transition alumina having a loose bulk density of at most 600 g/L, a pore volume of at least 0.6 mL/g, as determined, and a median pore diameter of at least 15 nm. The invention moreover relates to a shaped catalyst body for producing ethylene oxide by gas-phase oxidation of ethylene, comprising at least 15 wt.-% of silver, relative to the total weight of the catalyst, deposited on the tableted alpha-alumina catalyst support. The invention moreover relates to a process for producing ethylene oxide by gas-phase oxidation of ethylene, comprising reacting ethylene and oxygen in the presence of the shaped catalyst body.

Method for in-situ generation of nanoflower-like manganese dioxide catalyst on filter material
11565241 · 2023-01-31 · ·

A method for in-situ generation of nanoflower-like manganese dioxide catalyst on filter material is provided. The method comprises: immersing a filter material in a solution containing sodium lauryl sulfate and nitric acid; first modifying the surface of the filter material by using the sodium lauryl sulfate so that a charge layer is wound around the surface of the filter material and tightly absorbs H.sup.+ in an acid solution; and then adding potassium permanganate as an oxidant to react with H.sup.30 on the surface of the filter material to generate nano flower-like manganese dioxide in situ on the surface of the filter material, so as to obtain a composite filter material having a denitration function.

Gold nanoparticle superlattice embedded in porous silica and method for manufacturing same

The present invention relates to a catalyst composition comprising a gold nanoparticle superlattice embedded in hierarchical porous silica and a method for manufacturing the same. The catalyst composition comprising a gold nanoparticle superlattice embedded in hierarchical porous silica according to the present invention comprises micropores and mesopores in the superlattice, so that these pores are channelized to allow the rapid access of reactants to surfaces of gold nanoparticles, and the catalyst composition is very structurally stable and has excellent catalytic activity, and thus has an effect of exhibiting a CO conversion rate of 100% at room temperature.

COMPOSITE SOLID BASE CATALYST, MANUFACTURING METHOD THEREOF AND MANUFACTURING METHOD OF GLYCIDOL

A composite solid base catalyst, a manufacturing method thereof and a manufacturing method of glycidol are provided. The composite solid base catalyst includes an aluminum carrier and a plurality of calcium particles. The plurality of calcium particles are supported by the aluminum carrier. Beta basic sites of the composite solid base catalyst are 0.58 mmol/g-3.89 mmol/g.

CATALYST STRUCTURE HAVING A CORE-SHELL STRUCTURE WITH A CONTROLLED SURFACE MORPHOLOGY AND PREPARATION METHOD THEREOF
20230234031 · 2023-07-27 ·

The present invention provides a catalyst structure having a core-shell structure comprising a core comprising a metal and a shell formed on the core, wherein the shell comprises a metal hydroxide crystal or a metal oxide crystal formed uniformly in shape and size perpendicular to the surface of the metal, wherein the metal hydroxide crystal or the metal oxide crystal have a 2D structure or a 1D structure, and preparation method thereof.

CATALYTIC POROUS POLYMER FOR SELECTIVE CAPTURE AND REDUCTION OF CARBON DIOXIDE
20230234042 · 2023-07-27 ·

A catalytic carbon capture material is provided. The catalytic carbon capture material includes a microporous polymer including a Tröger's base moiety, and a transition metal is coordinated within the microporous polymer. The catalytic carbon capture material selectively captures carbon dioxide (CO.sub.2) and also is a catalyst that simultaneously converts the captured carbon dioxide into one or more carbon dioxide-based products. A method of making the catalytic carbon capture material and a method of selective carbon dioxide capture and conversion are also provided.

METHOD FOR MANUFACTURING A PHOTOCATALYTIC DEVICE, PHOTOCATALYTIC DEVICE, PHOTOCATALYTIC COMPOSITION AND GAS DEPOLLUTING APPARATUS
20230025309 · 2023-01-26 ·

The invention refers to a method for manufacturing a catalytic device, with the steps: a) providing a first catalyst having photocatalytic activity, a second catalyst, which is a different molecule than the first catalyst, and an adsorbent, each in a powdered state, b) mingling the first catalyst, the second catalyst and the adsorbent to form a catalytic composition and suspending them in a suspension liquid to form a slurry, and c) repeatedly coating the slurry onto a solid grid-like carrier having a plurality of through holes, configured to allow a gas to flow through the carrier, and evaporating the suspension liquid.