A heterogeneous catalyst comprising a support and a noble metal, wherein said support comprises silicon, and wherein said catalyst comprises from 0.1 to 40 mol % titanium and from 0.1 to 10 mol % of at least one noble metal.

The present invention relates to the field of catalysts, and provides a porous layered transition metal dichalcogenide (TMD) and a preparation method and use thereof. The preparation method includes the following steps: (1) mixing silica microspheres, a transition metal salt and an elemental chalcogen, and pressing to obtain a tablet, the silica microspheres having a same or different particle diameters; and (2) sintering the tablet under hydrogen, and removing the silica microspheres to obtain the porous layered TMD. The porous layered TMD prepared by the method of the present invention has a high lattice edge exposure, which provides more active sites and higher catalytic activity, so the porous layered TMD can effectively catalyze the oxidation of alcohols to aldehydes or sulfides to sulfoxides under visible light irradiation.

The present disclosure provides an exhaust gas purification catalyst having an improved Rh activation, which comprises a substrate and a catalyst coat layer formed on the substrate, the catalyst coat layer having a two-layer structure, wherein the catalyst coat layer includes an upstream portion on an upstream side and a downstream portion on a downstream side in an exhaust gas flow direction, and a part or all of the upstream portion is formed on a part of the downstream portion, wherein the upstream portion contains Rh fine particles and Pt, wherein the Rh fine particles have an average particle size measured by a transmission electron microscope observation of 1.0 nm or more to 2.0 nm or less, and a standard deviation σ of the particle size of 0.8 nm or less, and wherein the downstream portion contains Rh.

The present invention relates to a molding catalyst and a method for producing the same, wherein the molding catalyst is used in the Deacon process for commercial production of chlorine using hydrogen chloride oxidation reaction, exhibits only a small reduction in catalytic activity even when exposed to harsh reaction conditions to thus be durable, and has superb mechanical strength to be suitable for use in a fixed bed catalytic reactor.

Disclosed is high conversion and high carbon yielding CARGEN catalyst and a method of preparing the same. The catalyst comprises transition metals that may be supported or unsupported. The preparation method involves mixing a metal material with or without a support in a standard ball milling apparatus to produce a fine and homogenous solid mixture of the transition metal oxide and support. The catalyst is used in the CARGEN system.

The present invention provides a catalyst for catalytic reduction of an industrial flue gas SO.sub.2 with CO to prepare sulfur, a method for preparing the same and use thereof. A CeO.sub.2 nanocarrier is prepared by using a hydrothermal method, La and Y are loaded as active components, pre-sulfurization is conducted with 6% of SO.sub.2 and 3% of CO, and finally, the catalyst is prepared. The catalyst has high reactivity and sulfur selectivity and strong stability. The by-product sulfur generated by the reaction is recovered with a solvent CS.sub.2, and the solvent CS.sub.2 is recovered by using a distillation process. The preparation method is low in cost, causes no secondary pollution and is high in sulfur recovery rate. The problem of low sulfur production in China at present is solved.

The invention relates to a novel catalyst for hydrogenation for hydrogenating at least one of dicarboxylic acid or its acid anhydride. The catalyst for hydrogenation according to a first embodiment is obtained by supporting at least one of palladium or platinum, and cobalt on a carrier, and subjecting the resulting carrier to a reduction treatment at 400 K or higher. The catalyst for hydrogenation according to a second embodiment is obtained by supporting at least one of palladium or platinum, and molybdenum on a carrier, and subjecting the resulting carrier to a reduction treatment at 500 K or higher.

Disclosed herein are modified zeolites and methods for making modified zeolites. In one or more embodiments disclosed herein, a modified zeolite may include a microporous framework including a plurality of micropores having diameters of less than or equal to 2 nm. The microporous framework includes at least silicon atoms and oxygen atoms. The modified zeolite may further include organometallic moieties each bonded to bridging oxygen atoms. The organometallic moieties include a hafnium atom. The hafnium atom is bonded to a bridging oxygen atom, and bridging oxygen atom bridges the hafnium atom of the organometallic moiety and a silicon atom of the microporous framework.

Methods and apparatuses for highly sensitive detection of analytes using redox reactions. A library of heat reactions of analytes of interest with a variety of catalysts at a variety of temperatures is prepared. An array of sensors with low thermal mass heating elements is prepared, depositing the same or different catalysts, such as metal oxide catalysts that have multiple oxidation states, on each heating element. The low thermal mass heating elements are preferably not in thermal contact with a substrate, or a low mass substrate is used. The array is exposed to a sample at various temperatures. The sign and magnitude of the heat effect of the redox reaction of compounds in the sample or their decomposition products with each catalyst is measured and compared with the library. The catalysts and temperatures are chosen so that the desired analytes have a unique pattern of heat effect signs and magnitudes when reacted with those catalysts at those temperatures. The resulting detector is highly selective and sensitive to the analytes of interest.

The present invention relates to a process for the dehydration of at least one oxygenated compound, preferably selected from saturated alcohols, unsaturated alcohols, diols, ethers, in the presence of at least one dehydration catalyst selected from cerium oxide (CeO.sub.2), aluminium oxide (γ-Al.sub.2O.sub.3), aluminium silicate, silica-aluminas (SiO.sub.2-Al.sub.2O.sub.3), aluminas, zeolites, sulfonated resins, ion-exchange resins, metal oxides (for example, lanthanum oxide, zirconium oxide, tungsten oxide, thallium oxide, magnesium oxide, zinc oxide); of at least one basic agent selected from ammonia (NH.sub.3), or from inorganic or organic compounds containing nitrogen capable of developing ammonia (NH.sub.3) during said dehydration process; and, optionally, of silica (SiO.sub.2), or of at least one catalyst for the dissociation of ammonia (NH.sub.3) selected from catalysts comprising silica (SiO.sub.2), preferably of silica (SiO.sub.2).