The invention relates to Cu—Al—Mn shaped catalyst bodies in extruded form, and to a process for their preparation. The shaped catalyst body is suitable for the hydrogenation of organic compounds containing a carbonyl function, in particular for the hydrogenation of aldehydes, ketones and carboxylic acids and/or their esters. In particular, the shaped catalyst body is suitable for the hydrogenation of fatty acids or their esters, such as fatty acid methyl esters, to form the corresponding alcohols and dicarboxylic acid anhydrides, such as maleic anhydride, or esters of di-acids and di-alcohols, such as butane diol.

A honeycomb structure including a honeycomb having porous partition walls extending between inflow and outflow end faces to define cells, an outermost peripheral wall, and a pair of electrodes disposed on a side surface of the honeycomb. Each electrode is formed in a strip shape extending in a direction of the cells. In a cross section orthogonal to the extending direction of the cells, one electrode is disposed on a side opposed to the other electrode. The honeycomb has an outer peripheral region including the outer peripheral wall, a central region, and an intermediate region. An average electric resistivity A of a material constituted of the outer peripheral region, an average electric resistivity B of a material constituted of the central region and an average electric resistivity of C of a material constituted of the intermediate region satisfy the relationship: A≤B<C.

Disclosed herein are an activated carbon catalyst for hydrogen peroxide decomposition, a preparation method thereof and a hydrogen peroxide decomposition method using the same. The activated carbon catalyst for hydrogen peroxide decomposition, provided in an aspect of the present invention may be easily prepared through the carbonization and activation of an ion exchange resin, and safer and higher decomposition efficiency of hydrogen peroxide may be achieved than the conventional catalyst for hydrogen peroxide decomposition through the control of the manganese content and pore properties in the catalyst.

A metal oxide catalyst synthesized using supercritical carbon dioxide extraction is provided, wherein the metal oxide catalyst includes an active site containing at least one type of metal oxide and a support for loading the active site and the metal oxide is an oxide of a metal selected from the group consisting of transition metals (atomic number 21 to 29, 39 to 47, 72 to 79, or 104 to 108), lanthanide (atomic number 57 to 71), post-transition metals (atomic number 13, 30 to 31, 48 to 50, 80 to 84, and 112), and metalloids (atomic number 14, 32 to 33, 51 to 52, and 85) in the periodic table, and a combination thereof.

A method and catalyst for producing an alcohol, which method includes supplying water and a C2-C5 olefin to a reactor and performing hydration in a gas phase using a solid acid catalyst. The solid acid catalyst is one in which a heteropolyacid or a salt thereof is supported on a silica carrier. The silica carrier is obtained by kneading a fumed silica obtained by a combustion method, a silica gel obtained by a gel method, and a colloidal silica obtained by a sol-gel method or a water glass method; molding the resulting kneaded product; and calcining the resulting molded body.

The present invention provides an exhaust purification filter with which pressure loss can be reduced, the filter having high exhaust purification performance and granular-substance-filtering performance. The exhaust purification filter comprises a filter base material having a wall flow structure, and an exhaust purification catalyst supported on a dividing wall of the filter base material, the exhaust purification filter being such that: a median pore diameter (D50) of the filter base material according to a volumetric basis is 15 μm or greater; and the exhaust purification catalyst is unevenly supported on a high-density layer, in which the density of the exhaust purification catalyst is relatively high, and a low-density layer, in which the density of the exhaust purification catalyst is relatively low.

An improved process for the hydroconversion of micro carbon residue content of heavy hydrocarbon feedstocks by the use of a catalyst composition that is especially useful in the conversion of micro carbon residue of such feedstocks. The catalyst composition is a low surface area composition that further has a specifically define pore structure the combination of which provides for its enhance micro carbon residue conversion property.

A molded sintered body containing a mayenite type compound, an inorganic binder sintered material, and a transition metal, wherein a content of the inorganic binder sintered material is 3 to 30 parts by mass with respect to 100 parts by mass of the molded sintered body, and the molded sintered body has at least one pore peak in each of a pore diameter range of 2.5 to 20 nm and a pore diameter range of 20 to 350 nm. A method for producing the molded sintered body, including mixing a precursor of a mayenite type compound and a raw material of an inorganic binder sintered material to prepare a mixture; molding the mixture to prepare a molded body of the mixture; firing the molded body to prepare a fired product; and supporting a transition metal on the fired product to produce a molded sintered body.

A shaped catalyst body for producing ethylene oxide by gas-phase oxidation of ethylene, having a BET surface area in the range of 2 to 20 m2/g and comprising silver and a rhenium promotor deposited on a porous alpha-alumina catalyst support, characterized in that the support has a calcination history of at least 1460° C. The catalyst support has a high surface area and little ethylene oxide isomerization and/or decomposition activity. The invention further relates to a porous alpha-alumina catalyst support having a BET surface area of 1.7 to 10 m2/g, the porous alpha-alumina catalyst support being obtainable by a) preparing a precursor material comprising a transition alumina and/or an alumina hydrate; b) forming the precursor material into shaped bodies; and c) calcining the shaped bodies at a temperature of 1460° C. to 1700° C. to obtain the porous alpha-alumina support. The invention also relates to a process for producing ethylene oxide by gas-phase oxidation of ethylene, comprising reacting ethylene and oxygen in the presence of a shaped catalyst body as described above.

A process for producing a porous alpha-alumina catalyst support, comprising i) preparing a precursor material comprising, based on inorganic solids content, at least 50 wt.-% of a transition alumina having a loose bulk density of at most 600 g/L, a pore volume of at least 0.6 mL/g and a median pore diameter of at least 15 nm; and at most 30 wt.-% of an alumina hydrate; ii) forming the precursor material into shaped bodies; and iii) calcining the shaped bodies to obtain the porous alpha-alumina catalyst support. The catalyst support has a high overall pore volume, thus allowing for impregnation with a high amount of silver, while keeping its surface area sufficiently large so as to provide optimal dispersion of catalytically active species, in particular metal species. The invention further relates to a shaped catalyst body for producing ethylene oxide by gas-phase oxidation of ethylene, comprising at least 15 wt.-% of silver, relative to the total weight of the catalyst, deposited on a porous alpha-alumina catalyst support obtained in the process described above. The invention also relates to a process for preparing a shaped catalyst body as described above comprising impregnating a porous alpha-alumina catalyst support obtained in the process described above with a silver impregnation solution, preferably under reduced pressure; and optionally subjecting the impregnated porous alumina support to drying; and b) subjecting the impregnated porous alpha-alumina support to a heat treatment; wherein steps a) and b) are optionally repeated. The invention further relates to a process for producing ethylene oxide by gas-phase oxidation of ethylene, comprising reacting ethylene and oxygen in the presence of a shaped catalyst body as described above.