Patent classifications
B01J35/1033
EXHAUST GAS PURIFICATION FILTER
An exhaust gas purification filter is used so as to support a NO.sub.X purification catalyst. The exhaust gas purification filter includes a honeycomb structure portion and a plug portion. The honeycomb structure portion includes a partition wall and cells. Numerous pores are formed in the partition wall. The cells are partitioned by the partition walls and form a flow path for an exhaust gas. The plug portion alternately seals an inflow end surface or an outflow end surface for the exhaust gas in the cells. The partition wall has a gas permeability coefficient that is equal to or greater than 0.35×10.sup.−12 m.sup.2, a pore volume ratio of pore diameters of 9 μm or less that is equal to or less than 25%, and an average pore diameter that is equal to or greater than 12 μm.
EXHAUST GAS PURIFYING FILTER
Provided is an exhaust gas purifying filter used with a HC purifying catalyst supported thereon. Numerous pores are formed in partitions of the exhaust gas purifying filter. In a cross-section of the partition, pores are open at a passage surface, having an open end of which the opening diameter is 50 μm or larger. In the cross-section of the partitions, the partitions include a narrow part where a pore diameter is 5 μm or more and the pore diameter becomes a minimum in a region. In the cross-section of the partitions, the region is positioned between a pair of virtual lines L.sub.1 and L.sub.2 extending from opposing sides of the opening end to a passage surface positioned opposite to the opening end along the wall thickness direction X, Z. The pore diameter at the narrow part is 6% or more and less than or equal to 20% of the opening diameter.
Process And Catalyst For The Catalytic Hydrogenation Of Organic Carbonyl Compounds
Process for the catalytic hydrogenation of organic carbonyl compounds containing at least one functional group belonging to the group of aldehydes, ketones, esters and carboxylic acids, whereby said at least one functional group is converted to an alcohol by contacting said carbonyl compound with hydrogen and a hydrogenation catalyst at elevated temperature and pressure as well as a catalyst therefore and a process for producing said catalyst.
Production of hydrothermally stable CHA zeolites
A method of producing hydrothermally stable chabazite (CHA) zeolites is disclosed. The disclosed method is based on the use of reaction mixtures that (1) are essentially void of alkali metal cations and (2) contain the N,N,N-trimethyl-1-adamantyl ammonium (TMAda+) organic as the sole OSDA. The disclosed method results in a higher crystalline CHA zeolite that exhibits hydrothermal stability. There is also disclosed a zeolite material having a CHA-type framework structure made by the disclosed method. A method of selective catalytic reduction of NOx in exhaust gas using the material described herein is also disclosed.
HONEYCOMB FILTER
A honeycomb filter includes a pillar-shaped honeycomb structure body having a porous partition wall disposed to surround a plurality of cells and a plugging portion, wherein the partition wall is composed of a material containing cordierite as a main component thereof, porosity of the partition wall measured by a mercury press-in method is 60 to 68%, an average pore diameter of the partition wall measured by a mercury press-in method is 19 to 26 μm, and in a pore diameter distribution indicating a cumulative pore volume of the partition wall measured by a mercury press-in method, with a pore diameter (μm) on an abscissa axis and a log differential pore volume (cm.sup.3/g) on an ordinate axis, a first peak including a maximum value of the log differential pore volume has a pore diameter value of 18 μm or less, the pore diameter value corresponding to a ⅓ value width of the maximum value.
Process for the commercial production of high-quality catalyst materials
The present invention describes an improved process for the commercial scale production of high-quality catalyst materials. These improved processes allow for production of catalysts that have very consistent batch to batch property and performance variations. In addition these improved processes allow for minimal production losses (by dramatically reducing the production of fines or small materials as part of the production process). The improved process involves multiple steps and uses calcining ovens that allow for precisely control temperature increases where the catalyst is homogenously heated. The calcining gas is released into a separate heating chamber, which contains the recirculation fan and the heat source. Catalysts that may be produced using this improved process include but are not limited to catlaysts that promote CO hydrogenation, reforming catalysts, Fischer Tropsch Catalysts, Greyrock GreyCat™ catalysts, catalysts that homologate methanol, catalysts that promote hydrogenation of carbon compounds, and other catalysts used in industry.
Zeolite adsorbent in the form of low-tortuosity agglomerates
Provided is a zeolite-based adsorbent in the form of agglomerates, where the adsorbent having a tortuosity factor, calculated from the pore distribution determined by mercury intrusion porosimetry, of greater than 1 and less than 3. The adsorbent also has a porosity as determined by mercury intrusion porosimetry of between 25% and 35%. The adsorbent is useful in the field of separations in particular in a process for separating para-xylene from aromatic hydrocarbon isomer fractions containing 8 carbon atoms.
METHOD FOR ISOMERISING DEHYDRATION OF A NON-LINEAR PRIMARY MONOALCOHOL ON A QUADRILOBED IRON ZEOLITE CATALYST
A method for isomeris ng dehydration in the presence of a specific catalyst, to produce at least one alkene, carried out on a feedstock containing a non-linear primary monoalcohol, where the catalyst includes a zeolite having a series of 8MR channels and a binder having certain pore volume, which catalyst is multilobe-shaped and has characteristics including certain average mesopore volume Vm, and mesopores having a certain diameter, an average certain macropore volume VM, the macropores having a certain diameter, and certain average micropore volume V, the micropores having a certain diameter, and the catalyst has a certain exposed geometric area.
Dehydrogenation catalyst
The present invention relates to a dehydrogenation catalyst in which a platinum-group metal, an assistant metal, and an alkali metal or alkaline earth metal component are supported on a carrier, wherein the molar ratio of platinum to the assistant metal is 0.5 to 1.49, and the catalyst has an acidity amount of 20 to 150 mol KOH/g catalyst when it is titrated with KOH. The dehydrogenation catalyst according to the present invention may prevent coke formation from increasing rapidly when the hydrogen/hydrocarbon ratio in a dehydrogenation reaction is reduced, thereby increasing the productivity of the process. Accordingly, it makes it possible to operate the process under a condition in which the hydrogen/hydrocarbon ratio in a dehydrogenation reaction is reduced, thereby improving the economy of the process.
KIT AND METHODS FOR ASSESSING THE ADSORBENT PROPERTIES OF THE SURFACE OF A MATERIAL
The present invention relates to a kit and a method for assessing the electrostatic component of the surface of a material of interest by assessing the capacity to adsorb cationic or anionic molecules on the surface of the material of interest, and a method for assessing the lyophobic component of the surface of a material of interest by characterizing the adsorption and desorption of molecules without elementary charge from the surface of the material of interest.