Disclosed are methods and apparatuses for separating a wax product from a hydrocarbon feedstream by a) conducting a hydrocarbon feedstream to a membrane separation zone; b) retrieving at least one retentate product stream from the first side of the membrane element; c) retrieving at least one permeate product stream having a wax phase and an oil phase from a second side of the membrane element, wherein a pour point of the wax phase of the permeate product stream is higher than a pour point of the oil phase of permeate product stream; and d) separating a wax product from the wax phase of the permeate product stream.

Producing a dealcoholized beverage from its alcoholic beverage starting product and plant for implementing the method, which comprises the following steps: separating the beverage starting product into an alcoholic and aromatic permeate and into an aromatic and almost alcohol-free retentate in a permeation module by non-thermal permeation, dealcoholizing the permeate in a module intended for that task, and finally mixing the dealcoholized permeate with the almost alcohol-free retentate in a final-mixing module. Prior to the dealcoholizing, aroma compounds are removed from the aromatic and alcoholic permeate by cold adsorption in an aroma adsorber, resulting both in an aroma phase and in an aroma-free but alcoholic permeate which, however, has the alcohol removed from it by alcohol separation, resulting in an aqueous, largely dearomatized and dealcoholized permeate water phase. Final mixing of aroma phase, permeate water phase and retentate takes place in the final-mixing module to give a dealcoholized beverage.

The disclosure relates to a device for fermentation integrated with separation and purification of acetone, butanol, and ethanol (ABE) or butanol alone, including a medium tank (1), used for supplying a medium into a bioreactor; a bioreactor (2), connected with the medium tank (1), used for fermentation; a gas distributor (9), used for supplying gas bubble to the fermentation broth; a membrane separation unit (4), with gas communication to the bioreactor (2), used for receiving a gas with ABE or butanol from the bioreactor and separating ABE or butanol; a condensation unit (5), used for recovering ABE or butanol; a vacuum manometer (6) and a vacuum pump (8), used for supplying a force for driving ABE or butanol in a vapor form; and product tank (7), used for receiving a product.

A method of and apparatus for recovering an alcohol solvent from a liquid mixture of the solvent and plant oil and decarboxylating the plant oil may include, pressurizing the liquid mixture to a super-atmospheric pressure, recirculating the pressurized liquid mixture a plurality of times through at least one membrane separator to separate some of the solvent from the mixture to provide a concentrated mixture of the plant oil with less solvent, reducing the pressure of the liquid concentrated mixture to less than 15 psig, heating it at a pressure of less than 15 psig to a temperature sufficient to vaporize the solvent in the concentrated mixture, removing sufficient heat from the vaporized solvent to condense it to a liquid solvent at atmospheric pressure and temperature conditions, and heating the plant oil to a temperature desirably of at least 215° F. to decarboxylate the plant oil.

The present invention relates to an olefins-paraffins separation process in feed stream containing hydrocarbons with 2 to 4 carbon atoms by facilitated transport membrane specific to olefins, comprising the following step: a. feeding the feed stream containing hydrocarbons with 2 to 4 carbon atoms into distillation column and at least 1 stage of membrane unit connected to distillation column at the feed of distillation column and at least 1 stage of membrane unit connected to the side draw of distillation column; and b. separating a portion of feed stream that is passed from the membrane unit, at least 1 stream is the product stream that mostly comprising olefins and at least 1 stream that mostly comprising paraffins.

The present disclosure relates to the field of commercial scale production and processing of biosynthetic cannabinoids produced by growing genetically modified microalgae in a photo-bioreactor to a produce biosynthetic cannabinoids, separating a liquid nutrient medium from the genetically modified microalgae, and extracting the biosynthetic cannabinoids to produce an extracted biosynthetic cannabinoid, then distilling the extracted biosynthetic cannabinoid to produce the biosynthetic cannabinoid distillate. Biosynthetic cannabinoid distillates may be used foodstuffs, beverages, nanoemulsions, spray-dried water-soluble powders, cosmetics, or topicals.

Disclosed is a method of purifying a stream of crude hydrochlorofluoroolefin refrigerant produced by the reaction of 1,1,3,3 tetrachloropropene (R1230za) or 1,1,1,3,3-pentachloropropane (R240fa) with HF. The process includes a step of removing the cis-(Z) isomer by distillation of the crude refrigerant stream prior to a step of reacting the crude refrigerant stream with a base. The reaction with the base is a necessary step in production of the refrigerant and is done to remove HF and residual HCl from the crude refrigerant stream. Removal of the cis-(Z) isomer before the reaction with the base reduces the amount of toxic flammable trifluoropropyne (TFP) that is produced as a side-reaction during the reaction with the base. In addition, temperature control during the reaction with the base is less critical to minimizing the TFP production if the cis-(Z) isomer is first removed.

The present application pertains to methods for making metal oxides and/or citric acid. In one embodiment, the application pertains to a process for producing calcium oxide, magnesium oxide, or both from a material comprising calcium and magnesium. The process may include reacting a material comprising calcium carbonate and magnesium carbonate. Separating, concentrating, and calcining may lead to the production of oxides such as calcium oxide or magnesium oxide. In other embodiments the application pertains to methods for producing an alkaline-earth oxide and a carboxylic acid from an alkaline earth cation-carboxylic acid anion salt. Such processes may include, for example, reacting an alkaline-earth cation-carboxylic acid anion salt with aqueous sulfur dioxide to produce aqueous alkaline-earth-bisulfite and aqueous carboxylic acid solution. Other useful steps may include desorbing, separating, and/or calcining.

A mathematical model was developed to lead to the design of a novel membrane, which can operate in membrane distillation at a small trans-membrane temperature gradient, including at low feed water temperature range. The novel membrane design can be described as a super-hydrophobic nano-porous/micro-porous composite membrane. This membrane will significantly decrease the energy requirements of the MD process since it can operate at very low inlet feed temperatures.

The present disclosure provides processes and systems for ethanol production. In one embodiment, a first beer column receives a first portion of a feed mixture including ethanol and water to form a first beer column bottom stream and a first beer column vaporous overhead stream. A beer column receives a second portion of the feed mixture. A first portion of the first beer column bottom stream is forwarded to a first beer column reboiler. A second portion of the first beer column bottom stream is forwarded to a plurality of evaporators. A condensed portion of the first beer column vaporous overhead stream is forwarded to a stripper column. The stripper column forms a feed stream, which is contacted with a separation system, thereby forming a permeate and a retentate. The permeate is forwarded directly to at least one selected from the first beer column and the stripper column.