Processes and systems are provided to compress vapors produced in distillation and recover the heat of condensation through vapor compression and to derive mechanical, thermal, and electrical energy from a combined heat and power system, while maintaining the plant's original ability to operate. The plant's existing distillation system, steam generation, and electrical demand determine the design basis for the retrofit system that is targeted at an optimized combination of energy usage, energy cost, and environmental impact. Vapor compression (by mechanical vapor recompression and/or thermal vapor recompression) minimizes the total energy usage. Optionally, combined heat and power provides a means of converting energy between fuel, electricity, and thermal energy in a manner that best complements plant requirements and energy economics and minimizes inefficiencies and energy losses.

The present disclosure relates to systems and methods for separation of sulfurous material(s) from a multi-component feed stream. The systems and methods can comprise contacting the multi-component feed stream with a solvent in a contacting column so that at least a portion of the sulfurous material(s) is transferred from the multi-component feed stream to the solvent. A stream of a substantially purified gas can thus be provided along with a liquid stream comprising at least a majority of the sulfurous material. In particular, the solvent can comprise liquid carbon dioxide, which can be particularly beneficial for removing sulfurous materials from multi-component feed streams.

An apparatus and process heat a process stream taken from a separator vessel by heat exchange with a hydroprocessed effluent stream and return the heated process stream to the separator vessel. We have found the significant heater duty reduction is provided particularly for a hydroprocessing unit. A spiral tube heat exchange can achieve heating of an already hot process stream by heat exchange with a hot effluent stream.

A differential heating system along the length of a distillation column in a continuous-feed vacuum distillation system is proposed. By means of separately controlled heating units along the length of the distillation column, the temperature of the distillation column wall and therefore of the feed material in contact with the wall may be precisely modulated along the length of the column to optimize the distillate output. This contrasts with conventional practice in which the distillation column receives heat from a heat source of more or less uniform temperature along its entire length. Various features of the differential heating system that enhance its effectiveness are also claimed.

A method and systems are provided for controlling degradation in a reboiler using a hydrophobic coating. A reboiler is provided that includes a steam shell and a plurality of tubes. The reboiler includes a low surface-energy coating on a surface of the plurality of tubes.

A process and apparatus reboil a propylene splitter bottoms by heat exchange and/or a deethanizer bottoms stream with a compressed propylene splitter overhead stream. Use of single splitter compressor and operation of the propane-propylene splitter column at lower pressure are enabled, whereas conventionally two splitter compressors and higher splitter pressure were necessary to provide a propylene product stream and a propane recycle stream of equivalent quality.

A method to continuously monitor for tube leakage in a shell and tube thermosiphon reboiler for heating feedstock in a fractionating column includes: determining the column is in service by continuously monitoring an input flow of the feedstock into the column; determining the reboiler is inactive by continuously monitoring an output valve of tube-side heating fluid from the reboiler; determining the reboiler is losing the heating fluid by continuously monitoring an output flow of the heating fluid from the reboiler; determining the reboiler is heat exchanging by continuously monitoring a temperature difference between input and output flows of shell-side bottoms fluid with the column; and determining the tube leakage in the reboiler is taking place when the column is determined to be in service, the reboiler is determined to be inactive, the reboiler is determined to be losing the heating fluid, and the reboiler is determined to be heat exchanging.

System and method for producing 1-butene are disclosed. The method includes dehydrogenating butane to form a mixture comprising butene isomers. 1-butene is separated from the mixture using a system that includes a membrane. The system also includes an isomerizing unit for isomerizing cis-2-butene and trans-2-butene to form additional 1-butene.

An isomerization method consists of a deisobutanizer column receives feed comprising n-butane. The deisobutanizer column delivers its bottoms a portion to a reboiler and another portion along with hydrogen is routed to a isomerization reactor and the reactor effluent is returned to the column. A stabilizer which is integrated with the column, an overhead stream used as a reflux and bottoms containing an iso-butane-rich stream that is the iso-butane product stream. The column overhead effluent is routed to separator, which splits the hydrocarbons and effluent, where the hydrocarbons are routed to deisobutanizer column and effluent recycled to stabilizer, where the stabilizer separates the reactor effluent into product streams contains an iso-butane product stream, a n-butane product stream, and a lighter hydrocarbon product stream.

The present disclosure relates to systems and methods for separation of sulfurous material(s) from a multi-component feed stream. The systems and methods can comprise contacting the multi-component feed stream with a solvent in a contacting column so that at least a portion of the sulfurous material(s) is transferred from the multi-component feed stream to the solvent. A stream of a substantially purified gas can thus be provided along with a liquid stream comprising at least a majority of the sulfurous material. In particular, the solvent can comprise liquid carbon dioxide, which can be particularly beneficial for removing sulfurous materials from multi-component feed streams.