A negative-carbon footprint concrete composition includes CO.sub.2-sequestering aggregate that sequesters carbon dioxide (CO.sub.2) from a CO.sub.2 containing gas and cementitious material. The negative-carbon footprint concrete composition has a negative carbon footprint relative to an ordinary concrete composition.

The concerns a process for producing formic acid, (a) a carbon capture step in which a source of carbon dioxide is contacted with an amine solution in an amine scrubber, to obtain an ammonium bicarbonate solution, where the carbon capture uses a chilled amine solution having a temperature in the range of 0-20 ° C.; (b) inducing crystallization in the ammonium bicarbonate solution to obtain a concentrated ammonium bicarbonate solution; (c) subjecting the concentrated ammonium bicarbonate solution to a hydrogenation step to obtain an ammonium formate; and (d) heating the ammonium formate to a temperature in the range of 50-150 ° C., to obtain a gaseous product containing the amine and a liquid product stream containing formic acid. The application further concerns a system for performing the process.

A method for reducing the concentration of amines in a wash liquid stream exiting a wash section in an acid gas scrubbing process includes introducing the wash liquid stream exiting the wash section of the acid gas scrubbing process to an adsorbent material, wherein the wash liquid stream has a first concentration of amines. The wash liquid stream having the first concentration of amines is flowed through the adsorbent material, and the adsorbent material retains at least a portion of the amines thereby providing a wash liquid stream having a second, reduced concentration of amines. The wash stream with reduced concentration of amines is recycled back to the wash section to remove amines more effectively from the acid gas being scrubbed. The adsorbent material can be regenerated for reuse. Amine recovered from the regenerated adsorbent material can be recycled to the process for reuse.

A method of forming a concrete product includes directly capturing CO.sub.2 from a gas source, the capturing comprising contacting the gas source with an absorption solution having a solvent and a solute, wherein the solvent and/or the solute are capable of reacting with CO.sub.2 to form an anionic compound, adjusting the pH of the absorption solution electrochemically to less than about 7 to release the CO.sub.2 as a concentrated vapor containing CO.sub.2, collecting the concentrated vapor containing CO.sub.2, regenerating the solvent and/or the solute, and optionally collecting the regenerated solvent and/or solute; flowing the concentrated vapor containing CO.sub.2 through a gas processing unit to adjust at least one of a temperature, a relative humidity, or a flow rate of the concentrated vapor containing CO.sub.2; and contacting the concentrated vapor containing CO.sub.2 with a concrete component.

The present disclosure relates to a processes and systems for producing fuels from biomass with high carbon conversion efficiency. The processes and systems described herein provide a highly efficient process for producing hydrocarbons from biomass with very low Green House Gas (GHG) emissions using a specific combination of components, process flows, and recycle streams. The processes and systems described herein provide a carbon conversion efficiency greater than 95% with little to no GHG in the flue gas due to the novel arrangement of components and utilizes renewable energy to provide energy to some components. The system reuses water and carbon dioxide produced in the process flows and recycles naphtha and tail gas streams to other units in the system for additional conversion to syngas to produce hydrocarbon-based fuels.

A membrane modification method for improving liquid membrane separation of carbon dioxide (CO.sub.2) includes grafting an organic substance containing an amine group on a porous membrane material, and loading water into pore channels of the porous membrane material to prepare a supported liquid membrane for a gas mixture separation experiment of CO.sub.2. In the method, the amine group is introduced through chemical grafting to make the water being alkaline when used as membrane liquid. Compared with an alkaline solution as the membrane liquid, the method can avoid the loss of active alkaline substances and increase the permeation flux of CO.sub.2.

A spacesuit contaminant removal system includes at least one membrane separator and a liquid sorbent circuit. The at least one membrane separator is configured to receive a spent air stream from a ventilation system of a spacesuit and absorb a contaminant from the spent air stream into a liquid sorbent. The at least one membrane separator is configured to discharge a clean air stream to the ventilation system and discharge the contaminant in a contaminant stream to a space environment using a vacuum of the space environment. The liquid sorbent circuit is configured to circulate the liquid sorbent through the at least one membrane separator.

A carbon dioxide recovery apparatus is disclosed including a flue gas cooling unit that brings flue gas cooling water into contact with a flue gas to cool the flue gas, a circulation channel through which the flue gas cooling water and condensed water are returned to the flue gas cooling unit, an absorption unit including a carbon dioxide absorbing section, and a flue gas washing section that brings the flue gas including carbon dioxide absorbed in the carbon dioxide absorbing section into contact with flue gas washing water and washes the flue gas, a regeneration unit that removes carbon dioxide from the absorbent including carbon dioxide absorbed in the absorption unit, a supply channel through which circulating water is guided, and a discharge channel through which the circulating water circulating through the flue gas cooling unit and the circulation channel is discharged to outside of a system.

A method for decreasing the SFFC of a steam reforming plant, including establishing a base operating mode. Then modifying the base operating mode by introducing the shift gas stream into a solvent based, non-cryogenic separator prior to introduction into the pressure swing adsorption and introducing the compressed hydrogen depleted off-gas stream in a membrane separation unit, wherein the membrane is configured to produce the hydrogen enriched permeate stream at a suitable pressure to allow the hydrogen enriched permeate stream to be combined with carbon dioxide lean shift gas stream, prior to introduction into the pressure swing adsorption unit without requiring additional compression. Thereby establishing a modified operating mode. Wherein said pressure swing adsorption unit has a modified overall hydrogen recovery. Wherein said modified operating mode has a modified hydrogen production, a modified hydrogen production unit firing duty, a modified SCO2e, and a modified SFFC.

A method for decreasing the SFFC of a steam reforming plant, including establishing a base operating mode. Then modifying the base operating mode by introducing the shift gas stream into a solvent based, non-cryogenic separator prior to introduction into the pressure swing adsorption and introducing the compressed hydrogen depleted off-gas stream in a membrane separation unit, wherein the membrane is configured to produce the hydrogen enriched permeate stream at a suitable pressure to allow the hydrogen enriched permeate stream to be combined with carbon dioxide lean shift gas stream, prior to introduction into the pressure swing adsorption unit without requiring additional compression. Thereby establishing a modified operating mode. Wherein said pressure swing adsorption unit has a modified overall hydrogen recovery. Wherein said modified operating mode has a modified hydrogen production, a modified hydrogen production unit firing duty, a modified SCO2e, and a modified SFFC.