The present disclosure discloses a spacer tube reverse osmosis (STRO) membrane and a preparation method thereof, which relates to the technical field of reverse osmosis membranes. The preparation method of the STRO membrane specifically comprises the following steps: S101: preparation of a zirconia sol; S102: preparation of a casting solution; S103: preparation of a polysulfone ultrafiltration membrane; S104: immersion; and S105: coating. In the preparation method of the present disclosure, an ionic liquid and high-pressure-resistant particles are introduced into an ultrafiltration layer, the ionic liquid is cross-linked with the ultrafiltration layer in the process of interfacial polymerization, and a layer of the ionic liquid is coated on a surface, so that a three-layer high-performance three-dimensional crosslinking system is formed via the ionic liquid. The ionic liquid is prevented from falling off and dispersing in an oil phase solution, and the pressure resistance and hydrophilic performance of the STRO membrane is greatly improved. The STRO membrane is more suitable for using in high-pressure and high-concentration environments. By combining the ionic liquid with the zirconia sol, the STRO membrane of the present disclosure has higher tensile strength and pressure resistance compared with the reverse osmosis membrane prepared by other modified additives. In addition, the flux and desalination rate of the STRO membrane are also improved compared with the conventional reverse osmosis membranes.

A nanoporous polymer membrane with vertically aligned pore channels can be synthesized through self-assembly of amphiphilic block copolymers on a supporting substrate. The pore surface chemistry can be functionalized for selective anion transport.

A carbon molecular sieve (CMS) membrane having improved separation characteristics for separating olefins from their corresponding paraffins is comprised of carbon with at most trace amounts of sulfur and a group 13 metal. The CMS membrane may be made by pyrolyzing a precursor polymer devoid of sulfur in which the precursor polymer has had a group 13 metal incorporated into it, wherein the metal is in a reduced state. The pyrolyzing for the precursor having the group 13 metal incorporated into it is performed in a nonoxidizing atmosphere and at a heating rate and temperature such that the metal in a reduced state (e.g., covalently bonded to carbon or nitrogen or in the metal state).

The invention relates to the providing of hydrophobic and hydrophilic polymer-based hollow fiber membranes containing a water-insoluble antioxidant; in particular, the invention relates to the providing of hollow fiber membranes for the extracorporeal treatment of blood, wherein the hollow fiber membranes have improved biocompatibility relative to treatment blood, in particular improved complement activation and lower platelet loss vis-à-vis treatment blood. At the same time, the elution of hydrophilic polymers from the lumen of the hollow fiber membrane is reduced.

The disclosure provides certain porous membranes comprised of cyclic polyolefin polymers, such as poly(norbornene)s. In one embodiment, a poly(norbornene) polymer is dissolved in tetrahydrofuran, cast into a film and subjected to solvent induced phase separation to provide a porous filter membrane (i.e., film).

A polysulfone-urethane copolymer is disclosed, which can be used as a membrane polymer, e.g., a matrix polymer, a pore forming agent, or both, while enhancing a membrane's blood compatibility. Methods are disclosed for forming the copolymer and incorporating the copolymer in membranes (e.g., spun hollow fibers, flat membranes) and other products.

A virus removal membrane includes cellulose, and a primary-side surface through which the protein-containing solution is to be applied and a secondary-side surface from which a permeate that has permeated the virus removal membrane is to be flowed, wherein a bubble point is 0.5 MPa or more and 1.0 MPa or less; and when a solution containing gold colloids having a diameter of 30 nm is applied through the primary-side surface to the virus removal membrane to allow the virus removal membrane to capture the gold colloids for measurement of brightness in a cross section of the virus removal membrane, a value obtained by dividing a standard deviation of a value of an area of a spectrum of variation in the brightness by an average of the value of the area of the spectrum of variation in the brightness is 0.01 or more and 0.30 or less.

The invention a solvent-resistant polymeric nanofiltration membrane and preparation method thereof. The method includes subjecting a diamine monomer and a dianhydride monomer to cyclization imidization in a first polar organic solvent at 160 to 230° C., to form a polyimide, wherein the diamine monomer includes a diamine monomer with a carboxyl group and a diamine monomer without a carboxyl group; dissolving the polyimide in a second polar organic solvent, to form a membrane-forming solution; performing phase inversion to obtain an intermediate membrane; treating the intermediate membrane with an organic solution of a metal salt, so that the metal ion is coordinated and cross-linked with the carboxyl group in the polyimide, to obtain a solvent-resistant polymeric nanofiltration membrane, wherein the metal salt is a divalent and/or a multi-valent metal salt. The invention also discloses use of the solvent-resistant polymeric nanofiltration membrane in the separation and/or purification of a compound.

Multi-block isoporous structures for non-aqueous and/or harsh chemical media having at least one of high separation specificity, chemical resistance, and antifouling properties, methods of manufacturing and use, for replacements or alternatives to existing separation membrane technologies.

Polymer-based membranes and methods for fabricating membranes are described. The methods include forming a casting solution featuring a polyvinylidene fluoride (PVDF)-based solvent and a polyvinylpyrrolidone (PVP)-based modifying agent, dispersing the casting solution to form a first element, generating a plurality of active sites on a surface of the first element, and forming a polymer-based membrane by exposing the surface of the first element to a fluorosilane composition to form a fluorosilane layer on the surface, where the fluorosilane composition includes a silane compound having at least one alkyl substituent that includes between 9 and 21 fluorine atoms.