Provided herein are methods of making asymmetric membranes comprising a first layer and a second layer. The methods include preparing a polymeric solution comprising one or more polymers, casting the polymeric solution to form a polymeric film, contacting the polymeric film with a solvent comprising a crosslinker under conditions to form a first layer on the top of the film, wherein the first layer is dense and solvent resistant, and contacting the polymeric film having the dense, solvent-resistant first layer with a non-solvent solution under conditions that form a porous second layer on the bottom of the film.

Disclosed is a self-wetting porous membrane comprising an aromatic hydrophobic polymer such as polysulfone and a wetting agent comprising a copolymer of formula A-B or A-B-A, wherein A is a hydrophilic segment comprising a polymerized monomer of the formula (I): CH.sub.2═C(R.sup.1)(R.sup.2), wherein R.sup.1 and R.sup.2 are as described herein, and B is an aromatic hydrophobic polymeric segment, wherein segments B and A are linked through an amidoalkylthio group. Also disclosed is a method of preparing a self-wetting membrane comprising casting a solution containing an aromatic hydrophobic polymer and the wetting agent, followed by subjecting the cast solution to phase inversion. The self-wetting porous membrane finds use in hemodialysis, microfiltration, and ultrafiltration.

Embodiments of the present disclosure provide for polystyrene-b-polyethylene oxide (PS-b-PEO) block copolymer nanoporous membranes, methods of making a PS-b-PEO block copolymer nanoporous membrane, methods of using PS-b-PEO block copolymer nanoporous membranes, and the like.

The present invention provides a carbon membrane for fluid separation with which a high-pressure fluid can be separated and purified and which has excellent pressure resistance and is less apt to be damaged. The present invention relates to a carbon membrane for fluid separation, including: a core layer which has a co-continuous porous structure; and a skin layer which has substantially no co-continuous porous structure and is formed around the core layer.

Methods of making blended, isoporous, asymmetric (graded) films (e.g. ultrafiltration membranes) comprising two or more chemically distinct block copolymers and blended, isoporous, asymmetric (graded) films (e.g. ultrafiltration membranes) comprising two or more chemically distinct block copolymers. The generation of blended membranes by mixing two chemically distinct block copolymers in the casting solution demonstrates a pathway to advanced asymmetric block copolymer derived films, which can be used as ultrafiltration membranes, in which different pore surface chemistries and associated functionalities can be integrated into a single membrane via standard membrane fabrication, i.e. without requiring laborious post-fabrication modification steps. The block copolymers may be diblock, triblock and/or multiblock mixes and some block copolymers in the mix may be functionally modified. Triblock copolymers comprising a reactive group (e.g., sulfhydryl group) terminated block and films comprising the triblock copolymers.

A method of preparing a membrane comprising the steps of: a) mixing together a membrane-forming polymer, a water-soluble polyetheramine, and a solvent, said mixture containing no component which will react chemically with the polyetheramine; and b) casting said mixture to form the polymer into a solid membrane.

The present invention relates to improved methods for the preparation of thin film composite membranes by interfacial polymerization, preferably (organic) solvent resistant thin film composite membranes. More in particular the method of the present invention allows for the preparation of thin film composite membranes wherein a thin film is deposited on a porous crosslinked support. Said method comprises the one step solidification, impregnation and crosslinking of the porous support through phase inversion by immersion of the cast membrane polymer film in an (aqueous) solvent comprising a polyfunctional monomers.

Membranes having first and second porous portions, wherein the first portion has a more open pore structure than the second portion, wherein the first porous portion includes channels prepared by removing introduced fibers, as well as methods of making and using the membranes, are disclosed.

Described herein is a crosslinked graphene and biopolymer (e.g. lignin) based composite membrane that provides selective resistance for gases while providing water vapor permeability. Methods for making such membranes, and methods of using the membranes for dehydrating mixtures, are also described.

The embodiments described herein relate to agarose ultrafiltration membrane composites and methods for making and using the same.