A hydrogen permeation membrane is provided that can include a carbon-based material (C) and a ceramic material (BZCYT) mixed together. The carbon-based material can include graphene, graphite, carbon nanotubes, or a combination thereof. The ceramic material can have the formula BaZr.sub.1-x-y-zCe.sub.xY.sub.yT.sub.zO.sub.3-?, where 0?x?0.5, 0?y?0.5, 0?z?0.5, (x+y+z)>0; 0???0.5, and T is Yb, Sc, Ti, Nb, Ta, Mo, Mn, Fe, Co, Ni, Cu, Zn, Ga, In, or a combination thereof. In addition, the BZYCT can be present in the C-BZCYT mixture in an amount ranging from about 40% by volume to about 80% by volume. Further, a method of forming such a membrane is also provided. A method is also provided for extracting hydrogen from a feed stream.

Zeolite membrane sheets for separation of mixtures containing water are provided, as well as methods for making the same. Thin, but robust, zeolite membrane sheets having an inter-grown zeolite crystal film directly on a thin, less than 200 micron thick, porous support sheet free of any surface pores with a size above 10 microns. The zeolite membrane film thickness is less than about 10 microns above the support surface and less than about 5 microns below the support surface. Methods of preparing the membrane are disclosed which include coating of the support sheet surface with a seed coating solution containing the parent zeolite crystals with mean particle sizes from about 0.5 to 2.0 microns at loading of 0.05-0.5 mg/cm2 and subsequent growth of the seeded sheet in a growth reactor loaded with a growth solution over a temperature range of about 45? C. to about 120? C.

A method for manufacturing a porous membrane includes: mixing silicon carbide powders and a coagulant to form a first mixture; adding a sintering aid to the first mixture to form a second mixture; compressing the second mixture; and sintering the compressed second mixture. More particularly, the coagulant is in an amount of 1% to 3% by weight of the silicon carbide powders and the sintering aid is in an amount of 10% by weight of the first mixture.

The present invention relates to a method of controlling a defect structure in an MFI zeolite membrane and a method of separating xylene isomers using the MFI zeolite membrane produced by the method, and more particularly, to a method of controlling a defect structure in an MFI zeolite membrane that improves the performance of separating a xylene isomer by reducing the amount and size of defects formed in the MFI membrane structure when removing organic-structure-directing agents in the membrane through calcination at a low temperature using ozone.

A method for fabrication of an hydrogen-permeable membrane, comprising forming an alloy of a target composition and structure from powders by mechanically alloying; and forming a membrane from the alloy of the target composition and structure.

A method is described of producing a catalyst-containing composite oxygen ion membrane and a catalyst-containing composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln.sub.1?xA.sub.x).sub.wCr.sub.1?yB.sub.yO.sub.3?? and a doped zirconia. Adding certain catalyst metals into the fuel oxidation layer not only enhances the initial oxygen flux, but also reduces the degradation rate of the oxygen flux over long-term operation. One of the possible reasons for the improved flux and stability is that the addition of the catalyst metal reduces the chemical reaction between the (Ln.sub.1?xA.sub.x).sub.wCr.sub.1?yB.sub.yO.sub.3?? and the zirconia phases during membrane fabrication and operation, as indicated by the X-ray diffraction results.

A low-cost and easy-to-fabricate mixed e.sup.? and CO.sub.3.sup.2? conducting membrane for advanced high-flux and selective electrochemical CO.sub.2 separation from flue gas is provided. The membrane includes a CO.sub.3.sup.2?-conducting molten carbonate phase and an e.sup.?-conducting lithiated Ni-oxide interphase that can be formed in situ during operation. The membrane exhibits a CO.sub.2 flux density greater than 0.8 mL/(minute.Math.cm.sup.2) at 850? C. with a selectivity ranging from about 100 to about 500 and excellent stability for up to about 450 hours. Further, the self-formed interphase Li.sub.0.4Ni.sub.1.6O.sub.2 is highly electron conducting and can provide electrons to the co-reduction of CO.sub.2 and O.sub.2 into CO.sub.3.sup.2?. Such a membrane is an alternative to the conventional size-sieving inorganic and dissolution-diffusion organic counterparts for CO.sub.2 capture from flue gas.

A porous support includes a base body, a supporting layer, and a topmost layer. The supporting layer is disposed between the base body and the topmost layer, and makes contact with the topmost layer. A ratio of a porosity of the topmost layer to a porosity of the supporting layer is greater than or equal to 1.08. A ratio of a thickness of the topmost layer to a thickness of the supporting layer is less than or equal to 0.9.

A method of powder bed-based additive manufacturing of an intricate structure is specified, wherein the structure has a predetermined porosity, wherein a multitude of parallel irradiation vectors is chosen for selective irradiation of a powder layer for the production of the structure, wherein melt pathways generated by the parallel irradiation vectors are free of overlaps and wherein the parallel irradiation vectors also run parallel to the structure to be formed thereby. Additionally specified are a computer program product and a corresponding porous functional structure.

A layered device is provided. The device includes a ceramic composite substrate layer and a hydrogen permeable layer. The ceramic composite substrate layer includes a metal oxide phase and ceramic proton conducting oxide phase. The substrate layer is dense upon sintering and has contiguous porosity upon reduction in reducing atmosphere. The hydrogen permeable layer includes a single metal, metal alloys or layers of different metals.