The present invention is directed to surface-treated membranes comprising: (a) a porous substrate; and (b) a coating layer applied to the substrate. The coating layer is formed from a surface treatment composition comprising: (i) a first component comprising an organic solvent; and (ii) a second component comprising a fluorine-containing polymer and a solvent containing at least one C—F bond. The present invention is further drawn to a method of preparing a surface-treated filtration membrane, comprising: (a) contacting a porous substrate with a first component of a surface treatment composition, wherein the first component comprises an organic solvent; (b) subsequently contacting the porous substrate with a second component of the surface treatment composition, wherein the second component comprises a fluorine-containing polymer and a solvent containing at least one C—F bond; and (c) subjecting the porous substrate to a temperature of 25 to 90° C. for 1 to 180 minutes.

The present invention relates to a chemically modified anion exchange membrane and a method of preparing the same and, more particularly, an anion exchange membrane in which sulfonic acid groups in a perfluorinated sulfonic acid electrolyte membrane are substituted with anion conductive groups such as ammonium group, phosphonium group, imidazolium group, pyridinium group and sulfonium group, and a method of preparing an anion exchange membrane by chemically modifying sulfonic acid groups in a perfluorinated sulfonic acid electrolyte membrane.

A single piece-type bipolar film roll with a mesh cloth support and a manufacturing method therefor. The single piece-type bipolar film roll is supported by a high-strength ultra-high molecular weight polyethylene mesh cloth, one side of the single piece-type bipolar film roll is a cation exchange layer containing a benzenesulfonic acid group, the other side of the single piece-type bipolar roll is an anion exchange layer containing a benzyl dimethyl butyl ammonium quaternary amino group, and the middle is a water dissociation catalyst layer containing a benzyl methyl butyl amine tertiary amino group, and the three layers form the single piece-type bipolar film roll. By providing a wider protective film and a narrower spacing film, a dipping and absorbing film roll is polymerized to prepare a composite base film roll which is then subjected to continuous sulfonation to prepare a single-sided sulfonated composite positive film roll, and then the unreacted blank side is sequentially subjected to three-step chemical reactions such as complete chloromethylation, complete tertiary amination and incomplete methylation, so as to prepare a single piece-type bipolar film roll having a compact structure, a clear middle interface, a high mechanical strength and a stable quaternary amino group, and the product qualification rate is high; and the single piece-type bipolar film roll is suitable for a bipolar film electrodialysis engineering application of an organic material-containing system.

A system is described. The system includes a first region and a second region. The first region is configured to retain particles and has a first characteristic dimension. The second region is communicatively coupled with the first region such that the particles can travel between the first region and the second region. The second region has a second characteristic dimension of not larger than twice a characteristic length for the particles. The second region has a barrier that offers resistance to or interruption in particle movement.

M(SiF.sub.6)(pyz).sub.3 (M=Cu, Zn, Co, or Ni) has a pore size between a size of H.sub.2 and a size of CO.sub.2, and thus exhibits prominent screening performance for H.sub.2/CO.sub.2. A strong interaction between Cu(SiF.sub.6)(bpy).sub.2 and a CO.sub.2 molecule can hinder the transport of the CO.sub.2 molecule. The above two MOFs both can achieve the H.sub.2/CO.sub.2 separation. By preparing a dense MSiF.sub.6/polymer layer, MSiF.sub.6 is uniformly dispersed in the polymer and is fixed, and subsequently, MSiF.sub.6 is converted into M(SiF.sub.6)(pyz).sub.3 or Cu(SiF.sub.6)(bpy).sub.2 by interacting with an organic ligand. Through vapor-induced in-situ conversion, MOF particles can be well dispersed without interface defects between the MOF particles and the polymer. Even at a doping amount of 80%, the mechanical flexibility and stability of the MMM can still be retained.

The present invention relates to a purification/filtration system using reverse electro-osmotic flow through a composite or hybrid membrane element. The invention also relates to a process for purifying an electrolyte solution using such system. The invention further relates to a water purification system, a water desalination system and an implantable artificial kidney, comprising a reverse electro-osmotic filtration system according to the invention.

The present disclosure provides surface functionalized affinity membranes. The surface functionalized affinity membranes can provide increased binding capacity through improved coupling chemistries, ligand densities, spacer arm types, and spacer arm lengths. Methods of preparing the surface functionalized affinity membranes and methods of using the surface functionalized affinity membranes to isolate targets of interest, including nucleic acid molecules and proteins, from a sample are also provided.

A green energy generating system (e.g., thermal, solar, wind, kinetic) is integrated with a selective molecular separation (i.e., greenhouse gas capturing) system. The output of each system is utilized by the other to form a unitary system that produces green energy (i.e., electricity) while separating/capturing predetermined molecules (e.g., greenhouse gases) from the environment. The process includes providing kinetic energy fluid from an energy source; driving a turbine via the kinetic energy fluid; driving a generator via the turbine to generate electricity; supplying (i) the kinetic energy fluid exiting the turbine and/or (ii) electricity generated by the generator to a molecular separation unit; intaking the predetermined molecules into the separation unit and selectively separating at least one predetermined molecule from other molecules; and capturing the predetermined molecule via a desorption process using heat from thermal energy of (i) the kinetic energy fluid and/or (ii) an electrical heater powered by the electricity.

An article having a nanoporous membrane and a nanoporous graphene sheet layered on the nanoporous membrane. A method of: depositing a layer of a diblock copolymer onto a graphene sheet, and etching a minor phase of the diblock copolymer and a portion of the graphene in contact with the minor phase to form a nanoporous article having a nanoporous graphene sheet and a nanoporous layer of a polymer. A method of: depositing a hexaiodo-substituted macrocycle onto a substrate having a Ag(111) surface; coupling the macrocycle to form a nanoporous graphene sheet; layering the graphene sheet and substrate onto a nanoporous membrane with the graphene sheet in contact with the nanoporous membrane; and etching away the substrate.

In particles removal with extremely high filtration efficiency and the ability to block submicron airborne particles by a sieving mechanism is provided. This novel nanoporous filter advantageously combines extremely high transmittance for visible light and ultraviolet light, reusability after cleaning or disinfection by ultraviolet irradiation or simple washing, a customizable sieving pore size ranging from a few nanometers to 500 nanometers, and the ability to carry bactericidal, virucidal or other reagents or particles on the nano or micro scale.