The invention relates to a spinning nozzle (10) for the extrusion of a hollow fiber from one or more spinning masses and an apparatus comprising a spinning nozzle (10) as well as method for extruding a hollow fiber by means of a spinning nozzle (10), wherein the spinning nozzle (10) has an inlet port (12, 13, 14) for each spinning mass to be extruded for introducing the spinning mass into the spinning nozzle (14), an outlet port for the exit of spinning mass along an outlet axis (A), and at least one spinning mass flow channel for guiding at least one spinning mass to be extruded from the inlet port (12, 13, 14) to the outlet port, wherein at least one spinning mass flow channel comprises a flow manipulation section having an inlet and an outlet, which comprises a flow-guiding structure (18, 19, 20) for influencing a spinning mass flowing through the spinning mass flow channel, wherein the flow-guiding structure (18, 19, 20) is thereby designed to influence spinning mass flow such that the spinning mass flowing through the spinning mass flow channel at least partially flows through said spinning mass flow channel along at least two different flow paths, wherein the flow paths running through the spinning mass flow channel exhibit a substantially identical path length between the inlet of the flow manipulation section and the outlet port of the spinning mass flow channel.

The present invention addresses the problem of providing: a composite hollow-fiber membrane having high permeability and high membrane strength; and a production method therefor. The present invention pertains to a composite hollow-fiber membrane that at least has a layer (A) and a layer (B), wherein the layer (A) contains a thermoplastic resin, the layer (A) is provided with a co-continuous structure comprising voids and a phase containing the thermoplastic resin, the co-continuous structure has a structural cycle of 1-1000 nm, and the hole area rate H.sub.A of the layer (A) and the hole area rate H.sub.B of the layer (B) fulfill the relation: H.sub.A<H.sub.B.

A nanofiltration membrane comprising a selective layer comprising or consisting of poly(amide-imide) cross-linked with polyallylamine is provided. A method of manufacturing a nanofiltration membrane and use of a nanofiltration membrane in a water softening process that is carried out at a low pressure of less than about 2 bar are also provided.

Asymmetric hollow fiber membranes, membrane contactors, and related production and use methods. The asymmetric hollow fiber membranes include a porous substrate having a multiplicity of pores, the porous substrate including at least a first semi-crystalline thermoplastic polyolefin copolymer derived by polymerizing at most 3 wt. % of linear or branched alpha olefin monomers with at least 97 wt. % of 4-methyl-1-pentene monomer. The asymmetric hollow fiber membranes also include a skin layer overlaying the porous substrate, the skin layer including a second semi-crystalline thermoplastic polyolefin copolymer derived by polymerizing at least 2 wt. % of linear or branched alpha olefin monomers with at most 98 wt. % of 4-methyl-1-pentene monomer. The skin layer is less porous than the porous substrate and forms an outer surface of the asymmetric hollow fiber membrane, while the porous substrate forms an inner surface of the hollow fiber membrane. The skin layer is preferably nonporous.

The invention relates to a method for manufacturing a hollow fiber membrane bundle from a plurality of polysulfone and PVP-based hollow fiber membranes which encompasses the providing of a spinning solution comprising a polysulfone-based material, in particular polysulfone, a vinylpyrrolidone-based polymer, in particular polyvinylpyrrolidone, an aprotic solvent, in particular dimethylacetamide, providing a coagulant liquid comprising water and an aprotic solvent, in particular dimethylacetamide, co-extruding the spinning solution and the coagulant liquid through a concentric annular spinneret into a hollow strand, whereby the cavity of the strand is filled with coagulant liquid, conducting the strand through a precipitation gap, introducing the strand into a precipitating bath comprised substantially of water so as to obtain a hollow fiber membrane, conducting the hollow fiber membranes through at least one rinsing bath and drying the hollow fiber membrane obtained, arranging the resulting hollow fiber membranes into a hollow fiber membrane bundle, and treating the hollow fiber membrane bundle with water vapor.

A co-extrusion die is configured to produce a multilayer extrusion comprising component layers of an electrochemical cell. The die comprises a plurality of inlet ports configured to receive a plurality of pressurized fluids comprising at least a first metallic ink, a second metallic ink, and a polymeric ink. A plurality of channels are configured to separately transport and shape the plurality of fluids from the plurality of inlet ports to a merge section, such that the plurality of fluids flow together in the merge section to form the multilayer extrusion comprising a polymeric membrane layer disposed between and in contact with a first metallic layer and a second metallic layer. A thickness of each layer within the merge section is controllable by adjustment of a pressure of the plurality of pressurized fluids. An outlet port is configured to output the multilayer extrusion onto a substrate.

Disclosed herein are asymmetric multilayer carbon molecular sieve (CMS) hollow fiber membranes and processes for preparing the membranes. The processes include simultaneously extruding a core dope containing a polymer and suitable nanoparticles, a sheath dope, and a bore fluid, followed by pyrolysis of the extruded fiber.

The present invention is directed towards a method for the preparation of macroporous or mesoporous polymer films in hollow fiber geometry. The method according to the present invention reliably produces macroporous or mesoporous homopolymer or copolymer films in hollow fiber geometry having an ordered porous structure. Preferably, the pores are isoporous. The method involves the purging or casting a polyol adjacent to a film forming polymer solution of at least one homopolymer or at least one copolymer in a suitable solvent while polyol diffuses in and then condenses out of the film forming solution before the solution is immersed into a coagulation bath. The methods also require the presence of a carrier solution or carrier substrate during spinning or casting. The method makes macroporous or mesoporous film formation possible with a single step processing method.

The present invention relates to high performance, crosslinked hollow-fibre membranes and a new process for manufacturing the same.

Hollow fiber membranes, membrane contactors, and related production and use methods. The membranes include a substrate having a multiplicity of pores and a skin layer overlaying the porous substrate. The porous substrate includes a first semi-crystalline thermoplastic polyolefin (co)polymer resin and a nucleating agent in an amount effective to achieve nucleation. The skin layer includes a second semi-crystalline thermoplastic polyolefin (co)polymer resin derived by polymerizing at most 98 wt. % of 4-methyl-1-pentene monomer with at least 2 wt. % of linear or branched alpha olefin monomers. Preferably, the first thermoplastic polyolefin (co)polymer is different from the second thermoplastic polyolefin (co)polymer. The skin layer is less porous than the porous substrate and forms an outer surface of the hollow fiber with the porous substrate forming an inner surface. The hollow fibers are formed by co-extruding the porous substrate resin and the skin layer resin through an annular die.