The present disclosure provides a rigid self-supporting MXene separation membrane and a preparation method and use thereof, belonging to the technical field of membranes. In the present disclosure, a MXene material is mixed with an aluminum salt powder to conduct one-step membrane formation by hot-pressing. The pressure forms the powder into a membrane and imparts rigidity, enabling a self-supporting structure; the heating breaks an ionic bond of an inorganic metal salt to reach a molten ionic state, and free metal cations react with active oxygen-containing functional groups on the surface of the MXene to form new chemical bonds (such as an AlO bond); such a chemical bond has higher energy, achieving a desirable anti-swelling effect to improve the membrane stability. The separation membrane further has excellent conductivity and hydrophilicity.

The present invention generally relates to a method of joining and sealing a vanadium based membrane to a metallic connection section. The invention is particularly applicable to joining a tubular vanadium or vanadium alloy membrane to a stainless steel body and it will be convenient to hereinafter disclose the invention in relation to that exemplary application. The present disclosure also includes methods of joining and sealing a vanadium based membrane to a metallic connection section.

Adsorptive membranes with sponge-like structures for direct recovery of lithium from geothermal brines and recycling of water from geothermal evaporation ponds are disclosed. The membrane surfaces are functionalized with task-specific chemicals capable of selective separation of lithium through host-guest complexation mechanism. The sponge-like structure provides high surface area resulting in an enhanced lithium adsorption capacity. The technology disclosed here aims to reduce the time required for lithium enrichment by evaporative concentration of geothermal brines and address the water loss problem thereof through enhanced solar-driven recycling of water.

The present disclosure discloses a preparation method of an organosilica/ceramic composite membrane with a gradient pore structure. The preparation method comprises: (1) selecting a porous ceramic material as a membrane support layer; (2) gradually replacing a solvent with water to prepare zirconium colloidal sols with different particle sizes, and successively coating the prepared zirconium colloidal sols onto a ceramic support from large to small so as to form a membrane transition layer with a gradient pore structure; and (3) catalytically synthesizing an organosilica polymeric sol using hydrochloric acid, coating the prepared organosilica sol onto the preheated transition layer through ultrasonic thermal spraying to undergo heat treatment, so as to prepare the organosilica/ceramic composite membrane with the gradient pore structure. According to the present disclosure, the transition layer with the gradient pore structure is prepared by using the zirconium colloidal sols with different particle sizes. An ultrathin defect-free organosilica separation layer is prepared through ultrasonic thermal spraying. As a result, the obtained organosilica/ceramic composite membrane can be applied to the fields of salt-containing dye wastewater treatment and polypeptide bioactive substance separation.

A composite palladium-based alloy material, a preparation method therefor, and a use thereof are provided. The composite palladium-based alloy material includes Pd and a group IB metal. In an XRD graph of the composite palladium-based alloy material, the full width at half maximum of at least one characteristic peak for 2 within the range of 5-90 is less than or equal to 0.1745. The composite palladium-based alloy material has a lower activation energy for hydrogen permeation, a higher hydrogen permeation efficiency, higher stability and carbon deposition resistance, and has a longer service life as a composite membrane (especially in hydrogen production via steam reforming).