The present disclosure is directed to processes for the selective separation of carbon dioxide (CO.sub.2) from multi-component feedstreams containing CO.sub.2. The processes use a potassium-form MER framework type zeolite having a stick-like morphology. The potassium is present in the zeolite as K.sup.+ in extra-framework locations, and the zeolite is essentially free of an extra-framework cation other than potassium.

The present disclosure is directed to affinity chromatography devices including a fibrillated polymer membrane that contains inorganic particles having a spherical shape and a particle size distribution that has a D90/D10 less than or equal to 3. A blend or a combination of spherical inorganic particles may be utilized. A nominal particle size of the spherical inorganic particles is from about 5 microns to about 20 microns. An affinity ligand may be bonded to the spherical inorganic particles and/or to the fibrillated polymer membrane. Also, the affinity chromatography devices have a hydraulic permeability from about 100 (×10.sup.−12 cm.sup.2) to about 500 (×10.sup.−12 cm.sup.2). Additionally, the affinity chromatography devices have a cycling durability of at least 100 cycles without exceeding an pressure of 0.3 MPa. Manifolds containing multiple affinity chromatography devices in a parallel configuration and multiple manifolds in a parallel configuration are also disclosed.

A separation method includes a separation step of using a zeolite membrane composite to separate a branched diolefin from a branched hydrocarbon mixture containing the branched diolefin and at least one branched hydrocarbon in which the number of carbon-carbon double bonds is 1 or less and that is of an equivalent carbon number n to the branched diolefin. The zeolite membrane composite used in this step is a zeolite membrane composite that includes a porous support and a FAU-type zeolite membrane formed on at least one surface of the porous support, and in which the FAU-type zeolite membrane is a silylated FAU-type zeolite membrane including a silyl group at the surface thereof.

Carbon dioxide gas in a high-pressure gas to be treated is stably separated using a separation membrane. Upon separating carbon dioxide gas in a high-pressure gas to be treated using a separation membrane module including a separation membrane, a preliminary boosted gas is supplied to the separation membrane module before the supply of natural gas is started to boost a pressure on a primary side of the separation membrane to a preliminary pressure between a stand-by pressure and an operating pressure. Thus, when the supply of a high-pressure gas to be treated is started to increase the pressure of the separation membrane module to an operating pressure, an abrupt decrease in temperature of the gas to be treated can be suppressed.

A membrane heat treatment method includes a process of raising the temperature of a membrane to an intermediate heating temperature (step S21), a process of heating and keeping the membrane at the intermediate heating temperature (step S22), a process of raising the temperature of the membrane to a main heating temperature higher than the intermediate heating temperature (step S23), and the process of heating and keeping the membrane at the main heating temperature (step S24). A first recovery amount R1 that is a difference in permeability of the membrane between after step S22 and before step S21 is 50% or more and 95% or less of a second recovery amount R2 that is a difference in permeability of the membrane between after step S24 and before step S21.

A zeolite membrane complex includes a porous support and a zeolite membrane provided on the support and composed of RHO-type zeolite. In a case where a surface of the zeolite membrane is measured by an X-ray diffraction method, a peak intensity derived from a (310) plane of RHO-type zeolite is not higher than 0.4 times a peak intensity derived from a (110) plane thereof and a peak intensity derived from a (211) plane thereof is not higher than 0.3 times the peak intensity derived from the (110) plane.

The present disclosure is directed to a potassium-form MER framework type zeolite, a MER framework type zeolite having a stick-like morphology, wherein the potassium is present as K.sup.+ in extra-framework locations. The zeolite is essentially free of an extra-framework cation other than potassium.

The present invention discloses a new method for synthesizing a high-quality inorganic film by microwave heating, which relates to the field of preparation of inorganic materials. The method for synthesizing a high-quality inorganic film by microwave heating in the present invention allows a fine design and control of the temperature increase process during microwave heating, wherein the matrix and the synthesis solution is put into the microwave reactor at first, the temperature interval between the initial temperature and the target temperature of the synthesis solution is then divided into multiple sections, each of which sets a temperature increase rate, and then when the temperature reaches the target temperature after the designed temperature increase process, the synthesis solution reacts for a period of time at the target temperature, finally the high-quality inorganic film can be obtained after the treatment of washing and drying. The inorganic film prepared by the method of the present invention is dense and thin.

Provided is a zeolite membrane composite used for separation of a mixture, which has a high separation factor and is easily produced while maintaining a practically usable permeation flow rate. The zeolite membrane composite includes: a porous support; and an aluminosilicate zeolite membrane formed on a surface of the porous support and having a framework density of 10 or more and 17 or less. A Si/Al molar ratio of a surface of the zeolite membrane is 5 or more, and a ratio (A.sub.e/A.sub.0) of a developed membrane area A.sub.e in consideration of unevenness on the surface of the zeolite membrane to an apparent membrane area A.sub.0 not in consideration of the unevenness on the surface of the zeolite membrane is 2 or more and 20 or less.

Provided is a method for separating ammonia gas using zeolite membrane having excellent separation stability at a high temperature capable of separating ammonia gas from a mixed gas composed of multiple components including ammonia gas, hydrogen gas, and nitrogen gas to the permeation side with high selectivity and high permeability. Also provided is a method for separating ammonia by selectively permeating ammonia gas from a mixed gas containing at least ammonia gas, hydrogen gas, and nitrogen gas using a zeolite membrane, wherein the ammonia gas concentration in the mixed gas is 1.0% by volume or more.