A coating layer containing a silicone compound is formed on an inner surface of a hollow fiber membrane for manufacturing an oxygenator having a plurality of porous hollow fiber membranes for gas exchange. The method includes dissolving a silicone compound in an organic solvent having a surface tension of less than 70 dyn/cm to prepare a coating solution; and bringing an inner surface of the hollow fiber membranes into contact with the coating solution while bringing an outer surface of the hollow fiber membranes into contact with water to form a coating layer containing a silicone compound on the inner surface.

Embodiments disclosed herein generally relate to a microporous separator with a pore geometry that creates a low or no tortuosity architecture. In one embodiment, a battery cell may comprise of an anode layer, a cathode layer, and a separator layer positioned between the cathode layer and the anode layer. The separator layer may be comprised of one or more block copolymers. The block copolymers that make up the separator layer may be materials that self-align into a vertical nanostructure. The vertical nanostructures may allow ions within the battery cell to flow in a vertical path between the cathode and anode. This vertical path my create a low or no tortuosity environment within the battery cell.

This application is directed to new and/or improved MD and/or TD stretched and optionally calendered membranes, separators, base films, microporous membranes, battery separators including said separator, base film or membrane, batteries including said separator, and/or methods for making and/or using such membranes, separators, base films, microporous membranes, battery separators and/or batteries. For example, new and/or improved methods for making microporous membranes, and battery separators including the same, that have a better balance of desirable properties than prior microporous membranes and battery separators. The methods disclosed herein comprise the following steps: 1.) obtaining a non-porous membrane precursor; 2.) forming a porous biaxially-stretched membrane precursor from the non-porous membrane precursor; 3.) performing at least one of (a) calendering, (b) an additional machine direction (MD) stretching, (c) an additional transverse direction (TD) stretching, and (d) a pore-filling on the porous biaxially stretched precursor to form the final microporous membrane. The microporous membranes or battery separators described herein may have the following desirable balance of properties, prior to application of any coating: a TD tensile strength greater than 200 or 250 kg/cm2, a puncture strength greater than 200, 250, 300, or 400 gf, and a JIS Gurley greater than 20 or 50 s.

In at least one embodiment, a microporous membrane having a moderate to high water vapor permeability and high liquid water penetration resistance is disclosed. The microporous membrane may be used in building applications, including as or as part of a building wrap, a rain screen, a roofing underlayment, a flashing, a sound proofing material, or an insulation material. The microporous membrane may include at least one thermoplastic polymer, at least one filler, and at least one processing oil. The microporous membrane may be flat or may have ribs. The microporous membrane may include at least one scrim component. A method for forming the microporous membrane is also disclosed.

A crosslinked polyolefin separator and a method of making the same are disclosed herein. In some embodiments, a crosslinked polyolefin separator includes inorganic particles and a crosslinked polyolefin having Si—O—Si crosslinking bonds, wherein the inorganic particles are chemically bound to silicon (Si) atoms of the Si—O—Si crosslinking bonds by oxygen (O) atoms. The crosslinked polyolefin separator has low resistance, high air permeability and improved heat resistance.

In accordance with at least selected embodiments, a battery separator or separator membrane comprises one or more co-extruded multi-microlayer membranes optionally laminated or adhered to another polymer membrane. The separators described herein may provide improved strength, for example, improved puncture strength, particularly at a certain thickness, and may exhibit improved shutdown and/or a reduced propensity to split.

Disclosed herein is an improved membrane, separator and/or method for forming a multilayer microporous membrane for use in an improved battery separator, particularly a battery separator for a lithium ion secondary battery. Also disclosed herein is the multilayer microporous membrane formed by this method, which has properties that compete with or exceed those of wet process, coated or uncoated, membranes that are also useable in battery separators. Also disclosed are battery separators comprising the multilayer microporous membrane and batteries, vehicles, or devices comprising the separators. The method may comprise at least the following steps: (1) forming a stretched first non-porous precursor film that has pores due to the stretching of a first non-porous precursor film; (2) separately forming a second stretched non-porous precursor film that has pores due to the stretching of a second non-porous precursor film; and then (3) laminating the stretched first non-porous precursor and the stretched second non-porous precursor.

A metal-organic framework material separation membrane and a preparation method for the metal-organic framework material separation membrane are provided. The metal-organic framework material separation membrane has a base membrane and a metal-organic framework material functional layer. The metal-organic framework material functional layer comprises has an inter-embedded polyhedron structure. The preparation metal-organic framework material separation membrane includes the steps of: (1) preparing a solution containing a first organic solvent, an organic ligand, a metal compound, and an auxiliary agent; (2) subjecting a base membrane to a pretreatment, involving introducing, on the surface of the base membrane, metal atoms from the metal compound of step (1); and (3) mixing the pretreated base membrane of step (2) with the solution of step (1) to obtain a first mixture, and then heating the first mixture for reaction, so as to prepare a metal-organic framework material separation membrane.

A polyolefin composite porous membrane includes a first layer and a second layer. The first layer contains a polypropylene (A), a first high-density polyethylene (B) having a melting point of 130 C. or higher, and a second high-density polyethylene (C) having a melting point of 120 C. or higher and lower than 130 C. The second layer contains a polyethylene (D). The first layer and the second layer are integrally laminated with each other.

This application relates to a separator for a rechargeable battery. The separator includes a porous substrate and a coating layer on at least one surface of the porous substrate. The coating layer includes a binder including a fluorine-based binder and a (meth)acryl-based binder, and a filler. The fluorine-based binder includes a first structural unit derived from vinylidene fluoride and a second structural unit derived from at least one monomer of hexafluoropropylene, chlorotrifluoroethylene, trifluoroethylene, ethylene tetrafluoride, and ethylene monomers, and the second structural unit is included in an amount of 10 wt % or less with respect to the fluorine-based binder. The fluorine-based binder includes a first fluorine-based binder having a weight average molecular weight of 800,000 to 1,500,000 and a second fluorine-based binder having a weight average molecular weight of less than or equal to 600,000. The (meth)acryl-based binder has pencil hardness of 5H or higher.