B01D71/281

Cross-linked high stable anion exchange blend membranes with polyethyleneglycols as hydrophilic membrane phase
12083511 · 2024-09-10 ·

The invention relates to:anion exchange blend membranes consisting the following blend components:a halomethylated polymer (a polymer with (CH2)xCH2Hal groups, Hal=F, Cl, Br, I; x=0-12), which is quaternised with a tertiary or a n-alkylated/n-arylated imidazole, an N-alkylated/N-arylated benzimidazole or an N-alkylated/N-arylated pyrazol to form an anion exchanger polymer. - an inert matrix polymer in which the anion exchange polymer is embedded and which is optionally covalently crosslinked with the halomethylated precursor of the anion exchanger polymer,a polyethyleneglycol with epoxide or halomethyl terminal groups which are anchored by reacting with NH-groups of the base matrix polymer using convalent cross-linkingoptionally an acidic polymer which forms with the anion-exchanger polymer an ionic cross-linking (negative bound ions of the acidic polymer forming ionic cross-linking positions relative to the positive cations of the anion-exchanger polymer)optionally a sulphonated polymer (polymer with sulphate groups SO2Me, Me=any cation), which forms with the halomethyl groups of the halomethylated polymer convalent crosslinking bridges with sulfinate S-alkylation. The invention also relates to a method for producing said membranes, to the use of said membranes in electrochemical energy conversion processes (e.g. Redox-flow batteries and other flow batteries, PEM-electrolyses, membrane fuel cells), and in other membrane methods (e.g. electrodialysis, diffusion dialysis).

MEMBRANES FOR REMOVING METALLIC SPECIES FROM AMINES

The disclosure is directed to removal of metal contaminants from fluids, as well as ligand-modified filter materials useful for carrying out such methods. The filters and methods of this disclosure are particularly effective for removal of metals from liquid compositions comprising amines. Such liquid compositions with significantly reduced amounts of metals can be used in a microelectronic manufacturing process, such as liquids for removing photoresist or liquids used in etching. The ligand-modified filters, such as ligand-modified porous membranes, can be configured for use in a microelectronic manufacturing system, which can be utilized in the system as a point of use metal-removal feature for liquids entering the system.

Energy-Saving System And Method For Direct Air Capture With Precise Ion Control

Disclosed is an energy-saving system and method for direct air capture with precise ion control. The system includes an air conveying device, an air distribution device and a CO.sub.2 adsorption device with a moisture swing adsorbent with high CO.sub.2 adsorption capacity, where the air conveying device, the air distribution device and the CO.sub.2 adsorption device are connected in sequence, and the CO.sub.2 adsorption device is provided with a spray desorption device; a valence-state ion sieving device; a pH swing regeneration device; and a CO.sub.2 regeneration device. In accordance with the energy-saving system provided by the present disclosure, ultra-low concentration of CO.sub.2 in the air can be enriched to the concentration of 95% step by step for industrial application or biological application at room temperature and pressure by consuming the electricity which cannot be connected to a power grid.

ANIONIC MEMBRANES INCORPORATING FUNCTIONAL ADDITIVES
20240342699 · 2024-10-17 ·

An ultra-thin anion exchange membrane incorporates functional additives to provide improved water management. Without the functional additives the ultra-thin membrane may have high cross-over and not be effective for many applications. A composite anion exchange membrane includes a porous scaffold support such as a porous polymer. The anion exchange polymer may be coupled to the porous scaffold, such as by being imbibed into the pores of the porous scaffold. The functional additives may contribute to increase water production, water retention, back-diffusion and reduce the gas crossover. A functional additive may include a reactive species, including a catalyst that reacts with oxygen or hydrogen, a plasticizer, a hygroscopic material and/or a radical scavenger.

OXIDATION METHOD
20180118590 · 2018-05-03 · ·

Disclosed is a method of oxidizing a substrate comprising contacting the substrate, an oxidant, and a solid phase comprising a plurality of pendant groups having affinity for a substrate to be oxidised and an oxidation catalyst. Also disclosed is a solid phase and membrane for use in the method. Also disclosed is a method for preparing the solid phase, and system for oxidizing a substrate.

Method for creating a porous film through aqueous phase separation

The invention relates to a method for creating a porous film through aqueous phase separation, the method comprising: i) providing an aqueous solution comprising a responsive copolymer, and optionally a charged polymer, wherein at least one of the monomers in the responsive copolymer is a responsive monomer; ii) forming the aqueous solution into a thin layer and contacting the thin layer of aqueous solution with an aqueous coagulation solution in which the responsive copolymer is not soluble, or contacting the thin layer of aqueous solution with an aqueous coagulation solution in which a complex comprising the responsive copolymer and the charged polymer is not soluble; and iii) allowing solvent exchange between the aqueous solution and the aqueous coagulation solution to produce a porous film. The invention further relates to porous films or membranes thus obtained.

FLUOROPOLYMERS AND MEMBRANES COMPRISING FLUOROPOLYMERS (III)

Disclosed are fluoropolymers with low CWST values and porous membranes made from the fluoropolymers. The fluoropolymer is made up of polymerized monomeric units of the formula A-XCH.sub.2B, wherein A is C.sub.6F.sub.13(CH.sub.2).sub.2, X is O or S, and B is vinylphenyl, and the fluoropolymer has a weight average molecular weight (Mw) of at least 100 Kd and/or a glass transition temperature of at least 33 C. copolymer. The porous membranes are suitable for degassing a variety of fluids.

PROCESSES FOR REDUCING THE FOULING OF SURFACES

Process for reducing the fouling of a surface O, wherein an aqueous solution S of at least one polymer P comprising styrene and at least one ester E of (meth)acrylic acid and polyethylene oxide in a molar ratio of 0.05:1 to 50:1 is applied to said surface O.

ANIONIC ELECTROCHEMICAL COMPRESSOR AND REFRIGERATION SYSTEM EMPLOYING SAME
20180058729 · 2018-03-01 ·

An electrochemical compressor utilizes an anion conducting layer disposed between an anode and a cathode for transporting a working fluid. The working fluid may include carbon dioxide that is dissolved in water and is partially converted to carbonic acid that is equilibrium with bicarbonate anion. An electrical potential across the anode and cathode creates a pH gradient that drives the bicarbonate anion across the anion conducting layer to the cathode, wherein it is reformed into carbon dioxide. Therefore, carbon dioxide is pumped across the anion conducting layer. The compressor may be part of a refrigeration system that pumps the working fluid in a closed loop through a condenser and an evaporator.

ION-EXCHANGE MEMBRANE WITH MULTI-LAYERED SUPPORT SUBSTRATE

An ion-exchange membrane is disclosed here including ion-permeable layers impregnated with an ion-exchange material and arranged in an order from one face of the membrane to the opposite face of the membrane such that opposing layers in the supporting membrane substrate provide sufficiently identical physical properties to substantially avoid irregular expansion when in a salt solution. The ion-permeable layers including at least one non-woven layer and at least one reinforcing layer.