Described are membranes for separating olefins from a mixture that includes olefins and non-olefins. The membrane includes polymers and metal ions associated with the polymers. The metal ions mediate the transport of the olefins through the membrane by selectively and reversibly coupling with the olefins. The olefin/non-olefin selectivity of the membrane remains within at least 80% of its original selectivity after 200 hours of exposure of the membrane to a stream of hydrogen gas, 100 hours of exposure to a stream of acetylene gas, and 100 hours of exposure to a stream of hydrogen sulfide gas. Additional embodiments of the present disclosure pertain to methods of utilizing the membranes of the present disclosure to separate olefins from a mixture that includes olefins and non-olefins.

A method of producing a composite for acid gas separation by roll-to-roll process, including: a preparation step for preparing a coating liquid, containing a hydrophilic compound, an acid gas carrier and water, for formation of an acid gas separation facilitated transport membrane; a coating step for coating onto the support the coating liquid for formation at a liquid membrane thickness of 0.3 mm to 3.0 mm; a winding step for drying the coated liquid membrane in a drying oven to form the acid gas separation facilitated transport membrane, and winding around a winding roll the composite formed through formation of the acid gas separation facilitated transport membrane on the support, wherein humidity in a winding step unit in which the winding step is performed is measured to control the humidity to be 10% to 60%, and the winding step is performed under the controlled humidity conditions.

The further advancement of membrane separation processes requires the development of more selective membranes. In this study, membranes that take inspiration from biological systems and use multiple functionalities of unique chemical design to control solute transport through chemical factors in addition to steric factors are detailed. Specifically, copolymer materials tailor-made for the generation of nanofilters that possess a high density of well-defined pores lined by azido moieties allowed for the generation of chemically-patterned mosaic membranes in a rapid manner through the use of printing devices. By engineering the composition of the reactive ink solutions used for chemical functionalization, large areas of patterned membranes were generated in seconds rather than hours. Charge mosaic membranes were used as an example of this novel platform.

A separation membrane for blood processing, wherein the separation membrane for blood processing includes: a separation membrane containing polysulfone-based polymer and polyvinylpyrrolidone; and a coating film provided on at least a part of the surface of the separation membrane and containing a polymer material having a structure represented by the following general formula (1):

##STR00001##

wherein R.sup.1 is a hydrogen atom or a methyl group; R.sup.2 is a methyl group or an ethyl group; n is 2 to 6 and m is 1 to 3; P denotes the number of repetition; and a plurality of each of R.sup.1, R.sup.2, n, and m present in one molecule may be the same or different.

A spiral-wound acid gas separation membrane element (1) includes a wound body which includes a laminate and a perforated core (5), the laminate being wound around the perforated core tube (5) and including: a separation membrane (2), a feed-side channel component (3), and an element constituent layer (e.g., permeate-side channel component (4)). The separation membrane (2) is provided with a sealing section (25) present at both widthwise ends of the separation membrane (2). The sealing section (25) is sealed with an adhesive. This makes it possible not only to separate acid gas from mixed gas more efficiently as compared to a conventional spiral-wound acid gas separation membrane element but also to save energy.

A semi-porous composite membrane and a method of manufacturing the semi-porous composite membrane. The semi-porous composite membrane includes a base supporting substrate comprising ?-Al.sub.2O.sub.3, an outer layer comprising silica, and an intermediate layer comprising crystalline fibers of boehmite, and at least one of a secondary metal oxide and a synthetic polymer, wherein the intermediate layer is disposed between the base supporting substrate and the outer layer. The crystalline fibers of boehmite are a length of 5-150 nm. The semi-porous composite membrane may be employed in membrane reactors.

A composite membrane for selectively separating (e.g., pervaporating) a first fluid (e.g., first liquid such as a high octane compound) from a mixture comprising the first fluid (e.g., first liquid such as a high octane compound) and a second fluid (e.g., second liquid such as gasoline). The composite membrane includes a porous substrate comprising opposite first and second major surfaces, and a plurality of pores. A pore-filling polymer is disposed in at least some of the pores so as to form a layer having a thickness within the porous substrate. The composite membrane further includes at least one of: (a) an ionic liquid mixed with the pore-filling polymer; or (b) an amorphous fluorochemical film disposed on the composite membrane.

Preparing forming coating liquid for an acid gas separation facilitated transport membrane which includes a hydrophilic compound, an acid gas carrier, and water, coating the forming coating liquid, using a layered film layered in the order of a hydrophilic porous film, a hydrophobic porous film, and an auxiliary support film as a porous support, on a surface of the hydrophilic porous film of the layered film with a liquid film thickness of 0.3 mm to 1.0 mm and drying the coated liquid to form a first acid gas separation facilitated transport membrane, and further coating the forming coating liquid for the acid gas separation facilitated transport membrane on the surface of the hydrophilic porous film with the previously formed acid gas separation facilitated transport membrane and drying the coated liquid to form a next acid gas separation facilitated transport membrane.

The disclosure relates to processes, related polyacid polymers, and related articles for functionalizing a porous membrane by contacting the membrane with a polyacid polymer at low pH to stably adsorb a polyacid layer on the membrane pore surface, in particular polyacid polymers including repeating units with a pendent metal-binding ligand or star polyacid polymers. The resulting functionalized membrane is characterized by a high density of free acid groups, resulting in a higher specific capacity for its intended application. The process allows functionalization of porous membranes in a very simple, one-step process, for example without a need to derivatize an adsorbed polyacid layer to impart metal-binding ligand functionality thereto. Such functional membranes may find multiple uses, including rapid, selective binding of proteins for their purification or immobilization.

A semi-porous composite membrane and a method of manufacturing the semi-porous composite membrane. The semi-porous composite membrane includes a base supporting substrate comprising ?-Al.sub.2O.sub.3, an outer layer comprising silica, and an intermediate layer comprising crystalline fibers of boehmite, and at least one of a secondary metal oxide and a synthetic polymer, wherein the intermediate layer is disposed between the base supporting substrate and the outer layer. The crystalline fibers of boehmite are a length of 5-150 nm. The semi-porous composite membrane may be employed in membrane reactors.