A preparation method of separation membrane is provided. First, a polyimide composition including a dissolvable polyimide, a crosslinking agent, and a solvent is provided. The dissolvable polyimide is represented by formula 1: ##STR00001## wherein B is a tetravalent organic group derived from a tetracarboxylic dianhydride containing aromatic group, A is a divalent organic group derived from a diamine containing aromatic group, A′ is a divalent organic group derived from a diamine containing aromatic group and carboxylic acid group, and 0.1≤X≤0.9. The crosslinking agent is an aziridine crosslinking agent, an isocyanate crosslinking agent, an epoxy crosslinking agent, a diamine crosslinking agent, or a triamine crosslinking agent. A crosslinking process is performed on the polyimide composition. The polyimide composition which has been subjected to the crosslinking process is coated on a substrate to form a polyimide membrane. A dry phase inversion process is performed on the polyimide membrane.

A composite, method of making the composite, and method of using the composite are disclosed. The composite comprises a macroporous scaffold comprising pores; and a polymer matrix positioned within the pores; wherein the polymer matrix comprises: a functional polymer particle; and a structural polymer. The method of using can comprise applications such as chromatography, catalysis, and sensing, among others.

A composite, method of making the composite, and method of using the composite are disclosed. The composite comprises a macroporous scaffold comprising pores; and a polymer matrix positioned within the pores; wherein the polymer matrix comprises: a functional polymer particle; and a structural polymer. The method of using can comprise applications such as chromatography, catalysis, and sensing, among others.

Membranes, methods of making the membranes, and methods of using the membranes are described herein. The membrane can comprise a support layer; and a selective polymer layer disposed on the support layer. The selective polymer layer can comprise a selective polymer matrix (e.g., hydrophilic polymer, an amine-containing polymer, a low molecular weight amino compound, a CO.sub.2-philic ether, or a combination thereof), and graphene oxide dispersed within the selective polymer matrix. The membranes can be used to separate carbon dioxide for hydrogen. Also provided are methods of purifying syngas using the membranes described herein.

Membranes, methods of making the membranes, and methods of using the membranes are described herein. The membrane can comprise a support layer; and a selective polymer layer disposed on the support layer. The selective polymer layer can comprise a selective polymer matrix (e.g., hydrophilic polymer, an amine-containing polymer, a low molecular weight amino compound, a CO.sub.2-philic ether, or a combination thereof), and graphene oxide dispersed within the selective polymer matrix. The membranes can be used to separate carbon dioxide for hydrogen. Also provided are methods of purifying syngas using the membranes described herein.

The present invention relates to a method of manufacturing a high-performance thin film composite (TFC) membrane through a solvent activation process. In the present invention, by using a mixed solvent of a good solvent and a poor solvent as an activating solvent, a conventional polysulfone-based support-based TFC membrane having high water permeance as well as excellent salt rejection may be manufactured.

The present invention relates to a thin-film composite (TFC) membrane composition comprising macrocycles. The invention also relates in part to a method of fabricating a TFC membrane and to a method of using the TFC membrane to separate a desired liquid or gas from a liquid or gas mixture.

The present invention relates to a thin-film composite (TFC) membrane composition comprising macrocycles. The invention also relates in part to a method of fabricating a TFC membrane and to a method of using the TFC membrane to separate a desired liquid or gas from a liquid or gas mixture.

A method for manufacturing a membrane, which includes at least the following steps of: preparing a mixture that contains at least an aqueous solution of a cationic polymer whose pH is between 5 and 8, the cationic polymer having positively-charged groups in this aqueous solution, and an aqueous solution of an anionic polymer, the anionic polymer having negatively-charged groups in this aqueous solution; stirring the mixture; leaving the mixture to mature to cause the ionic interaction between positively-charged groups of the cationic polymer and negatively-charged groups of the anionic polymer, until obtaining within the mixture a membrane in the form of a hydrogel; adding at least one crosslinking agent so as to crosslink the membrane; drying the crosslinked membrane obtained upon completion of the previous step. This membrane is used for the treatment of liquid or gaseous effluents, as well as an antimicrobial support or for heterogeneous catalysis.

A method for manufacturing a membrane, which includes at least the following steps of: preparing a mixture that contains at least an aqueous solution of a cationic polymer whose pH is between 5 and 8, the cationic polymer having positively-charged groups in this aqueous solution, and an aqueous solution of an anionic polymer, the anionic polymer having negatively-charged groups in this aqueous solution; stirring the mixture; leaving the mixture to mature to cause the ionic interaction between positively-charged groups of the cationic polymer and negatively-charged groups of the anionic polymer, until obtaining within the mixture a membrane in the form of a hydrogel; adding at least one crosslinking agent so as to crosslink the membrane; drying the crosslinked membrane obtained upon completion of the previous step. This membrane is used for the treatment of liquid or gaseous effluents, as well as an antimicrobial support or for heterogeneous catalysis.