Multiblock polymer materials, methods of preparing, and using to separate proteins, nucleic acids, other biological or other biomolecules, compounds, or solutes, with high fluxes through electrostatic interactions where the self-assembled block polymer materials contain at least one of macro, meso, or micro pores, and at least some of the pores are isoporous, and at least one polymer block contains stationary electrostatic charge, or reactive functional groups to provide large surface areas that are charged in isoporous structure.

Multiblock polymer materials, methods of preparing, and using to separate proteins, nucleic acids, other biological or other biomolecules, compounds, or solutes, with high fluxes through electrostatic interactions where the self-assembled block polymer materials contain at least one of macro, meso, or micro pores, and at least some of the pores are isoporous, and at least one polymer block contains stationary electrostatic charge, or reactive functional groups to provide large surface areas that are charged in isoporous structure.

Compositions of and methods for producing a modified polyimide-containing compound with an alkyl or acyl group, one method including selecting and preparing a polyimide-containing compound to undergo a Friedel-Crafts alkylation or acylation reaction; carrying out the Friedel-Crafts alkylation or acylation reaction on the polyimide-containing compound to bond an alkyl group or acyl group to a reactive site on an aromatic compound of the polyimide-containing compound; cleaving the polyimide-containing compound to produce modified monomers comprising the alkyl group or the acyl group; and using the modified monomers in a reaction to produce the modified polyimide-containing compound, wherein the alkyl group or the acyl group is present in the modified polyimide-containing compound.

This invention integrates a membrane with a steam reformer such that a membrane is placed between a raw biogas feed, and a steam reformer to supply a retentate of purified methane feed to the steam reformer and the permeate as fuel to the steam reformer,

A gas-separation membrane obtainable from curing a composition comprising one or more curable monomers at least 30 wt % of which are monomer(s) comprising oxyethylene groups, oxypropylene groups and at least two polymerizable groups.

A gas-separation membrane obtainable from curing a composition comprising one or more curable monomers at least 30 wt % of which are monomer(s) comprising oxyethylene groups, oxypropylene groups and at least two polymerizable groups.

A method for forming an isoporous graded film comprising multiblock copolymers and isoporous graded films. The films have a surface layer and a bulk layer. The surface layer can have at least 1×10.sup.14 pores/m.sup.2 and a pore size distribution (d.sub.max/d.sub.min)) of less than 3. The bulk layer has an asymmetric structure. The films can be used in filtration applications.

A method for forming an isoporous graded film comprising multiblock copolymers and isoporous graded films. The films have a surface layer and a bulk layer. The surface layer can have at least 1×10.sup.14 pores/m.sup.2 and a pore size distribution (d.sub.max/d.sub.min)) of less than 3. The bulk layer has an asymmetric structure. The films can be used in filtration applications.

A porous membrane includes a triblock copolymer of the formula ABC. B is a hydrogenated vinyl aromatic block present in a range from 30 to 90 weight percent, based on the total weight of the copolymer and has a T.sub.g of ≥110° C. C is a rubbery block present in a range from 10 to 70 weight percent, based on the total weight of the copolymer and has a T.sub.g≤25° C. A is substantially incompatible with both the B and C blocks and is derived from ring-opening polymerization. B+C is present in a range from 70 to 95 weight percent, based on the total weight of the copolymer.

A porous membrane includes a triblock copolymer of the formula ABC. B is a hydrogenated vinyl aromatic block present in a range from 30 to 90 weight percent, based on the total weight of the copolymer and has a T.sub.g of ≥110° C. C is a rubbery block present in a range from 10 to 70 weight percent, based on the total weight of the copolymer and has a T.sub.g≤25° C. A is substantially incompatible with both the B and C blocks and is derived from ring-opening polymerization. B+C is present in a range from 70 to 95 weight percent, based on the total weight of the copolymer.