A system and a method for the recovery of carbon dioxide from a gas containing it. The system of the invention includes: pressurizing means for pressurizing the gas, an absorption tank for absorbing into water the carbon dioxide contained in a gas pressurized with the pressurizing means, a desorption tank for desorbing from water the carbon dioxide absorbed in water, means for circulating water from the absorption tank into the desorption tank and from the desorption tank back into the absorption tank, and recovering means for the recovery of carbon dioxide capable of being desorbed from the water. The system's absorption tank houses an agitator with a function of enabling water to circulate in the absorption tank by ejecting it into an air space of the absorption tank and by spreading in the absorption tank's air space over an area as extensive as possible.

Plant and process for separation of sulfur-containing components, H.sub.2S, COS and mercaptans from methanol which is used as absorbent within the Rectisol process by hot regeneration of the methanol laden in the absorption and an additional step for separation of the mercaptans from the methanol by stripping.

The invention provides methods and systems for reducing cost and energy consumption of gas purification processes that use physical or chemical absorbents. These methods and system provide a novel approach to vaporize process energy wastes including thermodynamic inefficiencies and waste heat by optimally integrating ejector technology into gas purification processes. These methods and systems use single-phase and/or two-phase ejectors as alternatives to mechanical compressors or pumps for recirculating fluid between vessels or as part of the cooling system associated to the gas purification processes.

The invention relates to an absorber column and to the use thereof for separation of unwanted, especially acidic, gas constituents, for example carbon dioxide and hydrogen sulfide, from a crude synthesis gas by absorption with an absorbent, especially under low load states of the absorber column in relation to the synthesis gas velocity. According to the invention, a defined concentration of carbon dioxide in the clean synthesis gas is established by mixing at least a portion of the absorbent regenerated by flash regeneration with the absorbent regenerated by means of hot regeneration prior to the recycling thereof into the absorber column.

Processes and equipment for purification of a sour hydrocarbon mixture or a gas mixture including hydrocarbons and sour gas, at least including the steps of directing the gas mixture to contact an absorbent liquid having affinity for sour gas, providing a purified off-gas mixture, directing the purified off-gas mixture to contact a liquid hydrocarbon mixture, providing an enriched liquid hydrocarbon mixture, with the associated benefit of such a process having a high recovery of hydrocarbons from the gas mixture to the enriched liquid hydrocarbon mixture, while being efficient in removing hydrogen sulfide from the gas mixture. The gas mixture to be purified may either be a natural gas, a fuel gas or an intermediate gas stream, e.g. from naphtha, kerosene, diesel or condensate hydrotreatment or hydrocracking, and it may also include further constituents, typically hydrogen.

A vapor/smoke capturing trap system featuring a smoke chamber trap for precipitating the smoke dispersed in the chamber. The chamber includes a bottom pool for containing a reservoir of a liquid solvent, and a gas filled portion in which a lower smog portion contains fog-sized droplets of the liquid solvent and into which the smoke is introduced, and an upper clear portion in which the concentration of the smoke and the droplets is decreased, respective of their concentration in the smog portion. A fog-condenser, disposed between the smog portion and the clear portion, precipitates the fog droplets of the smog portion into the pool. A fine mist generator streams a jet of fog-sized droplets of the liquid solvent mixed with smoke toward a concentration of the smoke at the smog portion. A closed loop gas circulator withdraws gas from the clear portion and recirculates the gas under pressure through the fine mist generator into the smog portion. Fresh smoke is introduced into the gas circulator via a smoke conveying conduit. A complementary smoke capturing method includes filling the reservoir, streaming the jet of fog-sized droplets toward a concentration of smoke dispersed within the lower smog portion of the gas filled portion, precipitating droplets, in the smog portion, into the pool by a fog-condenser disposed between the lower smog portion and the upper clear portion of the gas filled portion, recirculating under pressure, in a closed loop gas circulator, gas withdrawn from the clear portion into the smog portion through the fine mist generator, and conducting fresh smoke via smoke conveying conduit into the gas circulator.

Embodiments of the invention are directed to methods, processes, and systems for safely and reliably purifying hydrogen from a gas mixture containing hydrogen and oxygen.

The present process invention in continuation to the U.S. Ser. No. 14/392,066 appertains to Advanced Combustion in post-combustion carbon capture, wherein the CO.sub.2-containing flue gas, said CO2-Stream, is cleaned from harmful constituents, recirculated, oxygenized and employed for combustion for the fossil fuels, referred to Flue Gas Oxy-Fueling in order to obtain a CO.sub.2-rich gas upstream to CO2-CC with significantly less gas flow rate subject to further processing. This continuation process patent also presents processing to prepare a CO.sub.2-rich CO2-Stream for the pre-combustion carbon capture downstream of gasification and gas cleaning process; or from the secondary CO2-Stream that stems from the cathodic syngas [CO/2H.sub.2] downstream of HPLTE-SG of patent parent, then downstream of the HP/IP-water shift converters in [CO.sub.2/3H.sub.2] composition, whereas the CO.sub.2-rich CO2-Stream from either pre-combustion process is routed to the CO2-CC for CO.sub.2 cooling and condensation section of the U.S. Ser. No. 14/392,066 to obtain liquid carbon dioxide for re-use as new fossil energy resource.

Process and apparatus are disclosed for capturing and converting an ozone-depleting alkyl halide fumigant from a fumigant/air mixed stream (14) by absorbing it into a metal hydroxide-alcohol buffer solution (26) in an absorber/scrubber (12) to produce a fumigant-free air stream. The captured alkyl halide in aqueous alcohol solution can actively react with the metal hydroxide in alcohol solution to produce a value-added product, such as a precipitate metal halide, and another alcohol that further enhances absorption. The absorbing solution is well-mixed with make-up alcohol and alkali streams to maintain the concentration of the metal hydroxide in the desired buffer solution range. The solid precipitate metal halide is separated from the liquid stream, and the metal hydroxide-containing mixed alcohol stream is recycled to the absorber/scrubber (12).

The disclosure provides seven integrated methods for the chemical sequestration of carbon dioxide (CO.sub.2), nitric oxide (NO), nitrogen dioxide (NO.sub.2) (collectively NO.sub.x, where x=1, 2) and sulfur dioxide (SO.sub.2) using closed loop technology. The methods recycle process reagents and mass balance consumable reagents that can be made using electrochemical separation of sodium chloride (NaCl) or potassium chloride (KCl). The technology applies to marine and terrestrial exhaust gas sources for CO.sub.2, NOx and SO.sub.2. The integrated technology combines compatible and green processes that capture and/or convert CO.sub.2, NOx and SO.sub.2 into compounds that enhance the environment, many with commercial value.