The disclosure provides an apparatus, as well as associated systems and methods for removing acid gas components from gas streams. The disclosure provides a rotating packed bed (RPB)-based absorber with a non-aqueous liquid solvent contained therein for treatment of the gas streams, wherein the non-aqueous liquid solvent captures acid components from the gas stream. Various advantages, e.g., with respect to spatial considerations and associated expenses can be realized using the apparatus, systems, and methods described herein.

A solvent composition for carbon capture according to a preferred embodiment comprises at least two of the following: diethylaminoethanol (DEAE), hexamethylenediamine (HMDA), and polyethylenimine (PEI). Another embodiment includes a method of performing carbon capture using the carbon capture solvent compositions described herein. Another embodiment provides an apparatus for performing carbon capture using the carbon capture compositions described herein and/or the carbon capture methods described herein.

An absorbent liquid which absorbs at least one of CO.sub.2 and H.sub.2S from a gas, including a secondary linear monoamine; a tertiary linear monoamine or a sterically hindered primary monoamine; and a secondary cyclic diamine, wherein a concentration of each of the secondary linear monoamine, the tertiary linear monoamine or the sterically hindered primary monoamine; and the secondary cyclic diamine is less than 30% by weight.

The concerns a process for producing formic acid, (a) a carbon capture step in which a source of carbon dioxide is contacted with an amine solution in an amine scrubber, to obtain an ammonium bicarbonate solution, where the carbon capture uses a chilled amine solution having a temperature in the range of 0-20 ° C.; (b) inducing crystallization in the ammonium bicarbonate solution to obtain a concentrated ammonium bicarbonate solution; (c) subjecting the concentrated ammonium bicarbonate solution to a hydrogenation step to obtain an ammonium formate; and (d) heating the ammonium formate to a temperature in the range of 50-150 ° C., to obtain a gaseous product containing the amine and a liquid product stream containing formic acid. The application further concerns a system for performing the process.

A method and apparatus for continuously treating acid gases including recovering absorbent chemicals by introducing streams leaving a regenerator and/or leaving an absorber into a static mixing zone wherein supplemental washing water is added to recover absorbent chemicals. Improvements to the prior art methods are provided where one or more absorbent chemical recovery units are included to increase the amount of recovered absorbent chemicals exiting the regenerator and/or exiting the absorber are increased and/or maximized. Absorbent chemical recovery units can include mixing units where liquid is added to the stream of sour gas and absorbent chemical to mix with and absorb the absorbent chemical from the stream.

A system and process for selectively separating H.sub.2S from a gas mixture which also comprises CO.sub.2 is disclosed. A water recycle stream is fed to the absorber in order to create a higher concentration absorbent above the recycle feed and having a greater H.sub.2S selectivity at lower acid gas loadings, and a more dilute absorbent below the recycle feed and having a greater H.sub.2S selectivity at higher acid gas loadings. Also disclosed is a system and process for selectively separating H.sub.2S by utilizing two different absorbents, one absorbent for the upper section of the absorber, tailored to have a greater H.sub.2S selectivity at lower acid gas loadings, and a second absorbent for the lower section of the absorber, tailored to have a greater H.sub.2S selectivity at higher acid gas loadings.

This disclosure relates to a process for removing acid gases from a gas stream enriched in acid gases, wherein: (a) the gas stream enriched in acid gases is contacted in an absorption zone with an absorption medium, wherein the absorption medium is an aqueous medium comprising an amine, to form a gas stream depleted in acid gases which comprises an entrained amine and an absorption medium enriched in acid gases; and (b) treating the gas stream depleted in acid gases which comprises an entrained amine in a first scrubbing zone with a first scrubbing medium, wherein the first scrubbing medium is an aqueous medium comprising an amine, the amount of amine comprised by the scrubbing medium being about 0.1 to about 50.0 wt. %, wherein the aqueous medium is saturated with carbon dioxide such that at least 75 wt. % of the amine, based on the total amount of amine comprised by the aqueous medium, is in its carbamate or carbonate form, to form a gas stream depleted in acid gases and in amine and a first scrubbing medium enriched in amine.

The present invention relates to an apparatus and method for recovering carbon dioxide (hereinafter also referred to as “CO.sub.2”) contained in a combustion exhaust gas, and more specifically relates to: an apparatus and method for reactively absorbing CO.sub.2 contained in a combustion exhaust gas into an amine compound-containing absorption liquid; an apparatus and method for desorbing CO.sub.2 contained in an amine compound-containing absorption liquid from the amine compound-containing absorption liquid; an apparatus and method for evaporating and separating impurities from the amine compound-containing absorption liquid containing the impurities; an apparatus and method for performing a pretreatment such as desulfurization, dust removal, and cooling on a combustion exhaust gas; and a carbon dioxide-recovering apparatus and method utilizing the above apparatuses and methods.

A process for removing hydrogen sulfide and carbon dioxide from a fluid stream comprises a) an absorption step in which the fluid stream is contacted with an absorbent comprising an aqueous solution (i) of an amine of the general formula (I)

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in which R.sub.1, R.sub.2 and R.sub.3 are each independently selected from C.sub.1-4-alkyl and C.sub.1-4-hydroxyalkyl; each R.sub.4 is independently selected from hydrogen, C.sub.1-4-alkyl and C.sub.1-4-hydroxyalkyl; each R.sub.5 is independently selected from hydrogen, C.sub.1-4-alkyl and C.sub.1-4-hydroxyalkyl; X is OH or NH(CR.sub.1R.sub.2R.sub.3); m is 2, 3, 4 or 5; n is 2, 3, 4 or 5; and o is 0 or 1; and optionally (ii) at least one tertiary amine, where the molar ratio of (i) to (ii) is greater than 0.05; wherein at least 90% of the hydrogen sulfide is removed from the fluid stream and selectivity for hydrogen sulfide over carbon dioxide is not greater than 8, wherein a CO.sub.2- and H.sub.2S-laden absorbent is obtained; b) a regeneration step in which at least a substream of the CO.sub.2- and H.sub.2S-laden absorbent is regenerated and a regenerated absorbent is obtained; and c) a recycling step in which at least a substream of the regenerated absorbent is recycled into the absorption step a). The process allows a high level of hydrogen sulfide removal with a simultaneously high coabsorption of carbon dioxide.

The invention relates to methods and systems for determining operating and/or dimensioning parameters of a gas treatment plant including at least one gas treatment unit as well as methods and systems for generating a request to initiate the determination of operating and/or dimensioning parameters of a gas treatment plant. The invention further relates to a computer program and non-volatile or non-transitory storage medium with the computer program, which when executed on one or more processors, performs one or more of the methods.