An improved process for deacidizing a gaseous mixture with reduced overall energy costs is described. The process involves contacting the gaseous mixture with at least one of a vaporizing compound, a vaporized compound, a vaporizing solution of compound and a vaporized solution of compound, and forming a liquid or solid reaction product that can be easily separated from the gaseous mixture.

Provided is a gas separation apparatus advantageous in suppression of increase in pressure loss and achievement of reduced size and weight, thereby reducing costs. The gas separation apparatus causes an absorbent to flow down along the surface of a packing arranged in a treatment chamber, and supplies to the treatment chamber a gas to be treated which contains a target gas component, and then causes the gas to be treated and the absorbent flowing down along the surface of the packing to come into gas-liquid contact. Thus the target gas component contained in the gas to be treated is absorbed into the absorbent and separated or recovered from the gas to be treated. The packing has at least one packing unit configured by a plurality of expanded metal plates standing vertically and being aligned.

The present invention relates to an aqueous alkanolamine solution for the removal of hydrogen sulfide from gaseous mixtures containing hydrogen sulfide. The aqueous alkanolamine solution comprises (i) an amino compound with the formula:
R.sup.1R.sup.2NCH.sub.2CH(OH)CH.sub.2OH
wherein R.sup.1 and R.sup.2 independently represent lower alkyl groups of 1 to 3 carbon atoms, (ii) piperazine, and (iii) optionally a physical solvent, wherein said solution does not contain a strong acid. Further, the present invention relates to a process for removing hydrogen sulfide from a gaseous mixture containing hydrogen sulfide, and additionally other acid gases, if present, for example carbon dioxide, comprising the step of contacting the gaseous mixture contain hydrogen sulfide with the aqueous alkanolamine solution, preferably wherein the temperature of the aqueous alkanolamine solution is equal to or greater than 140 F. Examples of the gaseous mixtures include natural gas, synthesis gas, tail gas, and refinery gas.

A process for absorbing carbon dioxide from a gas stream containing carbon dioxide, including the steps of contacting the gas stream with an aqueous composition including a substituted heteroaromatic compound having a six-membered heteroaromatic ring with from 1 to 3 nitrogen atoms in the heteroaromatic ring and at least one substituent wherein at least one of the substituents is of formula R.sup.1NH.sub.2 wherein R.sup.1 is selected from C1 to C6 alkylene and ethers of formula R.sup.2OR.sup.3 wherein R.sub.2 and R.sub.3 are C.sub.1 to C.sub.3 alkylene

A system and a process for capturing Carbon Dioxide (CO.sub.2) from flue gases are disclosed. The process comprises feeding a flue gas comprising CO.sub.2 to at least one Rotary Packed Bed (RPB) absorber rotating circularly. A solvent may be provided through an inner radius of the RPB absorber. The solvent may move towards an outer radius of the RPB absorber. The solvent may react with the flue gas in a counter-current flow. The process further includes passing the flue gas through at least one of a water wash and an acid wash to remove traces of the solvent present in the flue gas. Finally, the solvent reacted with the CO.sub.2 may be thermally regenerated for re-utilizing the solvent back in the process.

A process for producing a material that absorbs carbon dioxide from atmospheric air, comprising: using a material that has a core and terminal primary amine end groups; and epoxy end capping of the terminal primary amine end groups to give secondary amine end groups.

An improved method for the removal of non-targeted components from a non-targeted component containing gas stream, the method includes the steps of: (i) contacting the non-targeted component containing gas stream with a fluid solvent stream; (ii) passing the product of step i) through a co-current phase separation step to produce both a non-targeted component containing solvent stream and a partially purified gas stream; (iii) passing the partially purified gas stream product of step ii) through a mass transfer step to produce a wet gas product; and (iv) passing the wet gas product of step iii) through a final co-current phase separation step to produce a purified gas stream, wherein the method is performed in a subsea location.

An apparatus removes acidic gases from a gas stream. The apparatus remove acid gas from a gas stream in a manner that generates a product gas stream at a higher temperature while consuming less energy than the existing technology. The apparatus enables the positive gas temperature differential to be maintained by manipulating the absorber column operating conditions and/or the solvent chemistry to increase the amount of absorption and reaction in the absorber.

Methods of reducing the water content of a wet gas are presented. In one case, the method includes exposing the gas to an amine-terminated branched polymer solvent to remove a substantial portion of the water from the wet gas, exposing the diluted solvent to carbon dioxide to phase separate the solvent from the water, and regenerating the solvent for reuse by desorbing the carbon dioxide by the application of heat. In another case, the method includes exposing the gas to a cloud-point glycol solvent to remove a substantial portion of the water from the wet gas, heating the diluted solvent to above a cloud point temperature for the solvent so as to create a phase separation of the solvent from the water so as to regenerate the solvent for reuse, and directing the regenerated solvent to a new supply of wet gas for water reduction.

A method for treating sulfur-containing exhaust gases is provided, comprising the following steps: step i): mixing the sulfur-containing exhaust gases, air, and a hydrocarbon fuel, and controlling a reaction between the air and the hydrocarbon fuel therein, to obtain a procedure gas stream comprising the sulfur-containing exhaust gases, hydrogen, and carbon oxides; step ii): controlling a hydrogenation reaction between the hydrogen contained in the procedure gas stream and a sulfur-containing substance in the sulfur-containing exhaust gases, to obtain hydrogenated tail gases containing hydrogen sulfide; and step iii): absorbing the hydrogen sulfide contained in the hydrogenated tail gases with an absorbing agent to obtain purified tail gases.