The present invention relates to methods for improving carbon capture using entrained catalytic-particles within an amine solvent. The particles are functionalized and appended with a CO.sub.2 hydration catalyst to enhance the kinetics of CO.sub.2 hydration and improve overall mass transfer of CO.sub.2 from an acid gas.

An elemental sulfur recovery unit comprising a thermal unit configured to combust an acid gas feed comprising hydrogen sulfide, an oxygen source, and a fuel gas to create a reaction furnace outlet stream, comprising elemental sulfur, a waste heat boiler configured to capture heat from the reaction furnace outlet stream to create a waste heat boiler effluent, a condenser configured to condense the waste heat boiler effluent to produce a non-condensed gases stream and a condensed stream comprising elemental sulfur, a process gas reheater configured to generate a hot gases stream, a hydrogenation reactor configured to convert the hot gases stream to create a hydrogenation effluent comprising hydrogen sulfide, a process desuperheater configured to cool the hydrogenation effluent to generate a cooled effluent, and an absorber unit configured to absorb the hydrogen sulfide from the cooled effluent to produce a hydrogen sulfide recycle stream and a waste gas stream.

The present invention relates to methods for improving carbon capture by providing particles within an amine solvent. The particles provide for increased turbulence at the interface between the counter-flowing gas and solvent, which allows for increased amine and carbamate salt diffusion between the liquid film and bulk.

The gas separation device separates or captures a target gas component from a gas to be processed by: causing an absorbing liquid to flow down on a surface of a packing disposed inside a processing tank while supplying the gas to be processed containing the target gas component into the processing tank; bringing the absorbing liquid flowing down on the surface of the packing and the gas to be processed into gas-liquid contact; and thereby causing the absorbing liquid to absorb the target gas component contained in the gas to be processed. The packing includes at least one packing unit formed from multiple expanded metal plates, which are disposed vertically and arranged in parallel. Each expanded metal plate includes strands forming the openings which are arranged like stairs. Each strand is inclined to the vertical direction at an angle in a range from 48° to 73°.

An organic amine decarbonization solution includes: i) one or more organic amines serving as a carbon dioxide absorbent; and ii) an antioxidant. The antioxidant includes: a) one or more organometallic complexes of Formula [M.sub.x(L).sub.y]A.sub.n, wherein each M independently represents a central atom selected from the group consisting of transition metals, Group IVA metals and Group VA metals at a lower valence state; each L independently represents a bidentate or multidentate organic ligand with each ligating atom thereof being independently one of O, S, N and P; each A independently represents an uncoordinated counter-ion suitable for forming an outer sphere of a complex; x is 1, 2 or 3; y is 1, 2, 3, 4, 5, 6, 7 or 8; and n is 0, 1, 2, 3 or 4; and b) optionally one or more metal chelating agents.

A carbonic acid gas absorbing material on an embodiment includes a liquid carbonic acid gas absorbent and a solid carbonic acid gas absorbent. The liquid carbonic acid gas absorbent is a solution containing a first amine and a solvent. The solid carbonic acid gas absorbent is a second amine of any one among a polyamine, a base material and an amine fixed to the base material, or a polyamine, a base material, and an amine fixed to the base material.

A co-axial co-current contactor (CA-CCC) is described herein. The CA-CCC includes an outer annular support ring and an inner annular support ring configured to maintain the CA-CCC within an outer pipe and an inner pipe, respectively. The CA-CCC includes rich liquid flow channels located between the outer annular support ring and the inner annular support ring that are configured to allow a rich liquid stream to flow through the CA-CCC, and a central gas entry cone and gas flow channels configured to allow a gas stream to flow through the CA-CCC. The CA-CCC further includes radial blades configured to secure the central gas entry cone to the inner annular support ring and allow a lean liquid stream to flow into the central gas entry cone and the gas flow channels. The CA-CCC provides for efficient incorporation of liquid droplets formed from the lean liquid stream into the gas stream.

Disclosed are a carbon dioxide absorbent composition in which an N-alkylaminoalkanol; a polyhydroxyamine-based compound; and ethylenediamine and/or diethylenetriamine are mixed, a method for preparing the same, and a method and an apparatus for carbon dioxide absorption/separation using the same. Since the carbon dioxide absorbent according to the present disclosure has superior carbon dioxide absorption capacity and remarkably lower absorbent recycling temperature as compared to the existing absorbents such as monoethanolamine, etc., total energy consumption in the capturing process can be reduced greatly. In addition, since carbon dioxide is recovered at low recycling temperature, contamination by water or absorbent vapor may be prevented.

An aspect of the present invention is a gas treatment method including: an absorption step of bringing a gas to be treated, which contains carbon dioxide and a sulfur compound, into contact with an absorption liquid to be phase-separated by carbon dioxide absorption, to cause the absorption liquid to absorb the carbon dioxide and the sulfur compound; and a first release step of heating the absorption liquid brought into contact with the gas to be treated to a temperature equal to or higher than a temperature at which the carbon dioxide absorbed by the absorption liquid is released from the absorption liquid and lower than a temperature at which the sulfur compound absorbed by the absorption liquid is released from the absorption liquid, to release the carbon dioxide from the absorption liquid.

Disclosed is an adsorbent containing a metal oxide for adsorption of hydrogen sulfide in biogas, and a biogas purification system using the same.